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Journal Articles

Sm valence determination of Sm-based intermetallics using $$^{149}$$Sm M$"{o}$ssbauer and Sm L$$_{rm III}$$-edge X-ray absorption spectroscopies

Tsutsui, Satoshi; Higashinaka, Ryuji*; Nakamura, Raito*; Fujiwara, Kosuke*; Nakamura, Jin*; Kobayashi, Yoshio*; Ito, Takashi; Yoda, Yoshitaka*; Kato, Kazuo*; Nitta, Kiyofumi*; et al.

Hyperfine Interactions, 242(1), p.32_1 - 32_10, 2021/12

https://doi.org/10.1007/s10751-021-01759-x
 Times Cited Count：1 Percentile：84.42(Physics, Atomic, Molecular & Chemical)

Journal Articles

Characterization and storage of radioactive zeolite waste

Yamagishi, Isao; Nagaishi, Ryuji; Kato, Chiaki; Morita, Keisuke; Terada, Atsuhiko; Kamiji, Yu; Hino, Ryutaro; Sato, Hiroyuki; Nishihara, Kenji; Tsubata, Yasuhiro; et al.

Journal of Nuclear Science and Technology, 51(7-8), p.1044 - 1053, 2014/07

https://doi.org/10.1080/00223131.2014.924446
 Times Cited Count：19 Percentile：78.38(Nuclear Science & Technology)

For safe storage of zeolite wastes generated by treatment of radioactive saline water at the Fukushima Daiichi Nuclear Power Station, properties of the Herschelite adsorbent were studied and its adsorption vessel was evaluated for hydrogen production and corrosion. Hydrogen production depends on its water level and dissolved species because hydrogen is oxidized by radicals in water. It is possible to evaluate hydrogen production rate in Herschelite submerged in seawater or pure water by taking into account of the depth effect of the water. The reference vessel of decay heat 504 W with or without residual pure water was evaluated for the hydrogen concentration by thermal hydraulic analysis using obtained fundamental properties. Maximum hydrogen concentration was below the lower explosive limit (4 %). The steady-state corrosion potential of a stainless steel 316L increased with absorbed dose rate but its increase was repressed by the presence of Herschelite. At 750 Gy/h and $$<$$60$$^{circ}$$C which were values evaluated at the bottom of the vessel of 504 W, the localized corrosion of SUS316L contacted with Herschelite would not immediately occur under 20,000 ppm of Cl$$^{-}$$ concentration.

Journal Articles

Safe storage of zeolite adsorbents used for treatment of accident-generated water at Fukushima Daiichi Power Station

Yamagishi, Isao; Nagaishi, Ryuji; Terada, Atsuhiko; Kamiji, Yu; Kato, Chiaki; Morita, Keisuke; Nishihara, Kenji; Tsubata, Yasuhiro; Ji, W.*; Fukushima, Hisashi*; et al.

IAEA-CN-211 (Internet), 5 Pages, 2013/01

http://www-pub.iaea.org/iaeameetings/IEM4/29Jan/Yamagishi.pdf

Since the accident at Fukushima Daiichi Nuclear Power Station, a large amount of radioactive contaminated water has been generated to cool damaged reactor cores. Adsorption of cesium with zeolite-like media was employed for treatment of this contaminated saline water. As spent zeolite media are highly radioactive, their safe storage is a pressing issue. Japan Atomic Energy Agency has extensively conducted R&D on the management of secondary wastes produced by the operation of the treatment system. Subjects on the safe storage of spent zeolites include the analysis of their characteristics and the evaluation of effectiveness of the present safety measures in consideration of decay heat emission and hydrogen generation by water radiolysis as well as durability of vessels exposed to saline. Preliminary results obtained are described in the present paper.

Journal Articles

Pulse radiolysis study of ion-species effects on the solvated electron in alkylammonium ionic liquids

Kondo, Takafumi*; Asano, Akira*; Yang, J.*; Norizawa, Kimihiro*; Takahashi, Kenji*; Taguchi, Mitsumasa; Nagaishi, Ryuji; Kato, Ryuji*; Yoshida, Yoichi*

Radiation Physics and Chemistry, 78(12), p.1157 - 1160, 2009/12

https://doi.org/10.1016/j.radphyschem.2009.07.004
 Times Cited Count：28 Percentile：85.84(Chemistry, Physical)

Spectrum and kinetic behavior of solvated electrons (e$$_{sol}$$$$^{-}$$) in alkyl ammonium ionic liquids (ILs), ${it i.e.}$ DEMMA-TFSI, DEMMA-BF4, TMPA-TFSI, PP13-TFSI, P13-TFSI and P14-TFSI were investigated by pulse radiolysis method. The e$$_{sol}$$$$^{-}$$ in the ILs have same absorption peak at 1100 nm with a molar absorption coefficient of 1.5-2.3$$times$$10$$^{4}$$ dm$$^{3}$$mol$$^{-1}$$cm$$^{-1}$$. The reaction rate constant of e$$_{sol}$$$$^{-}$$ with Pyrene (Py) was 1.5-3.5$$times$$10$$^{8}$$ dm$$^{3}$$mol$$^{-1}$$s$$^{-1}$$. These values were about one order of magnitude higher than that of diffusion controlled limit, which was calculated from measured viscosity. The dry electron (e$$_{dry}$$$$^{-}$$) reacts with Py, and its rate constant in DEMMA-TFSI was 7.9$$times$$10$$^{11}$$ dm$$^{3}$$mol$$^{-1}$$s$$^{-1}$$, three orders of magnitude higher than that of the e$$_{sol}$$$$^{-}$$ reactions.

Journal Articles

Picosecond pulse radiolysis; Dynamics of solvated electrons in ionic liquid and geminate ion recombination in liquid alkanes

Yang, J.*; Kondo, Takafumi*; Norizawa, Kimihiro*; Nagaishi, Ryuji; Taguchi, Mitsumasa; Takahashi, Kenji*; Kato, Ryuji*; Anishchik, S. V.*; Yoshida, Yoichi*; Tagawa, Seiichi*

Radiation Physics and Chemistry, 77(10-12), p.1233 - 1238, 2008/10

https://doi.org/10.1016/j.radphyschem.2008.05.031
 Times Cited Count：25 Percentile：82.53(Chemistry, Physical)

First observation of picosecond dynamics in ionic liquid of DEMMA-TFSI in radiation chemistry was reported. It is found that the electron produced by ionization is solvated to full solvation in ionic liquid with a rate constant of 3.9$$times$$10$$^{10}$$ s$$^{-1}$$. The yield of solvated electrons in picosecond time region is 1.2$$times$$10$$^{-7}$$ mol J$$^{-1}$$. The dry electron in ionic liquid reacts rapidly with biphenyl and pyrene with a rate constant of 3.8 to 7.9$$times$$10$$^{11}$$ L mol$$^{-1}$$ s$$^{-1}$$. The geminate ion recombination in n-dodecane and n-hexane was also observed by monitoring the transient absorptions at 523 nm.

Journal Articles

Electron photodetachment from iodide in ionic liquids through charge-transfer-to-solvent band excitation

Kato, Ryuji*; Yoshida, Yoichi*; Katsumura, Yosuke; Takahashi, Kenji*

Journal of Physical Chemistry B, 111(18), p.4770 - 4774, 2007/05

https://doi.org/10.1021/jp067107e
 Times Cited Count：54 Percentile：76.97(Chemistry, Physical)

Journal Articles

Luminescence study on preferential solvation of europium (III) in water/non-aqueous solvent mixtres

Kimura, Takaumi; Nagaishi, Ryuji; Kato, Yoshiharu; Yoshida, Zenko

Journal of Alloys and Compounds, 323-324(1-4), p.164 - 168, 2001/07

https://doi.org/10.1016/S0925-8388(01)01121-5
 Times Cited Count：50 Percentile：87.64(Chemistry, Physical)

no abstracts in English

Journal Articles

Luminescence study on solvation of americium(III), curium(III) and several lanthanide(III) ions in nonaqueous and binary mixed solvents

Kimura, Takaumi; Nagaishi, Ryuji; Kato, Yoshiharu; Yoshida, Zenko

Radiochimica Acta, 89(3), p.125 - 130, 2001/05

https://doi.org/10.1524/ract.2001.89.3.125
 Times Cited Count：66 Percentile：96.81(Chemistry, Inorganic & Nuclear)

no abstracts in English

Oral presentation

Solvated electrons in ionic liquids

Takahashi, Kenji*; Hiejima, Yusuke*; Kato, Ryuji*; Nagaishi, Ryuji; Taguchi, Mitsumasa; Kojima, Takuji; Kondo, Takafumi*; Yang, J.*; Yoshida, Yoichi*

no journal, , 

Solvated electrons were studied using the pulse radiolysis and photo ionization methods. The Vis-NIR spectra and reactivity of the solvated electrons in ionic liquids are discussed.

Oral presentation

Water effects on the solvated electron in ammonium ionic liquids

Kondo, Takafumi*; Yang, J.*; Yoshida, Yoichi*; Nagaishi, Ryuji; Taguchi, Mitsumasa; Takahashi, Kenji*; Kato, Ryuji*

no journal, , 

The effect of the coexistence water on the solvated electrons in ammonium ionic liquids was studied by the electron pulse radiolysis method. The optical absorption band of the solvation electron decreased by coexistence of water, and new absorption band like a hydrated electron were generated in the medium wavelength region between solvated electron and hydrated electron. Furthermore, if quantity of water increase in the hydrophilic ionic liquid, it was found that the spectrum changed into the hydrated electron.

Oral presentation

Femtosecond pulse radiolysis study of the reaction between solvated electron or presolvated electron in ionic liquids with scavengers

Kondo, Takafumi*; Yang, J.*; Yoshida, Yoichi*; Nagaishi, Ryuji; Taguchi, Mitsumasa; Takahashi, Kenji*; Kato, Ryuji*

no journal, , 

no abstracts in English

Oral presentation

Consideration for long-term storage of a spent zeolite adsorption vessel, 8; External heating type drying test of zeolite packed in small SUS vessel

Yamagishi, Isao; Kato, Chiaki; Nagaishi, Ryuji; Arisaka, Makoto; Uruga, Kazuyoshi*; Tsukada, Takeshi*

no journal, , 

no abstracts in English

12 (Records 1-12 displayed on this page)
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