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Journal Articles

Synthesis of new perovskite-type oxyfluorides, BaInO$$_{2}$$F and comparison of the structure among perovskite-type oxyfluorides

Katsumata, Tetsuhiro*; Suzuki, Ryo*; Sato, Naoto*; Suzuki, Shumpei*; Nakashima, Mamoru*; Inaguma, Yoshiyuki*; Mori, Daisuke*; Aimi, Akihisa*; Yoneda, Yasuhiro

Journal of Solid State Chemistry, 279, p.120919_1 - 120919_8, 2019/11

 Times Cited Count:8 Percentile:47.78(Chemistry, Inorganic & Nuclear)

Journal Articles

Relation between the structure and tolerance factor for perovskite-type oxyfluorides

Katsumata, Tetsuhiro*; Inaguma, Nobuyuki*; Mori, Daisuke*; Aimi, Akihisa*; Yoneda, Yasuhiro

Seramikkusu, 54(9), p.629 - 632, 2019/09

Crystal structure analysis of ABO$$_3$$ perovskite-type oxyfluoride were performed by using high-energy synchrotron X-ray measurement. The effect of tolerance factor appeared in the local structure. The average structure of perovskite-type oxyfluoride found to be a cubic structure in the traditional crystal structure analysis.

Journal Articles

Synthesis, structural transformation, thermal stability, valence state, and magnetic and electronic properties of PbNiO$$_{3}$$ with perovskite- and LiNbO$$_{3}$$-type structures

Inaguma, Yoshiyuki*; Tanaka, Kie*; Tsuchiya, Takeshi*; Mori, Daisuke*; Katsumata, Tetsuhiro*; Oba, Tomonori*; Hiraki, Koichi*; Takahashi, Toshihiro*; Saito, Hiroyuki

Journal of the American Chemical Society, 133(42), p.16920 - 16929, 2011/09

 Times Cited Count:84 Percentile:85.78(Chemistry, Multidisciplinary)

Oral presentation

Local structure of perovskite-type oxyfluorides, BaFeO$$_2$$F and BaInO$$_2$$F

Katsumata, Tetsuhiro*; Inaguma, Yoshiyuki*; Aimi, Akihisa*; Yoneda, Yasuhiro

no journal, , 

The search for novel materials requires the search for compounds with compositional flexibility. Mixed anion compounds such as perovskite oxyfluorides are promising materials. In these compounds, the relationship between structure and tolerance factor t is interesting. In this study, perovskite oxyfluorides with various t, BaInO$$_2$$F (t=0.97), BaScO$$_2$$F (t=0.99) and BaFeO$$_2$$F, were synthesized and their local and average structures were investigated by X-ray diffraction and pair distribution (PDF) methods, respectively. Furthermore, the relationship between the structure and the tolerance factor t was discussed.

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