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Fujihara, Hiro*; Toda, Hiroyuki*; Ebihara, Kenichi; Kobayashi, Masakazu*; Mayama, Tsuyoshi*; Hirayama, Kyosuke*; Shimizu, Kazuyuki*; Takeuchi, Akihisa*; Uesugi, Masayuki*
International Journal of Plasticity, 174, p.103897_1 - 103897_22, 2024/03
Times Cited Count:0Hydrogen(H) embrittlement in high-strength aluminum(Al) alloys is a crucial problem. H accumulation at the interface of precipitates in Al alloy is considered to cause embrittlement. However, there is no quantitative knowledge regarding the interaction between H distribution and stress field near cracks. In this study, using a multi-modal three-dimensional image-based simulation combining the crystal plasticity finite element method and H diffusion analysis, we tried to capture the stress distribution near the crack, its influence on the H distribution, and the probability of crack initiation in the experimental condition. As a result, it was found that grain boundary cracks transition to quasi-cleavage cracks in the region where the cohesive energy of the semi-coherent interface of MgZn precipitates decreases due to H accumulation near the tip. We believe the present simulation method successfully bridges nanoscale delamination and macroscale brittle fracture.
Tang, J.*; Wang, Y.*; Fujihara, Hiro*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Ebihara, Kenichi; Takeuchi, Akihisa*; Uesugi, Masayuki*; Toda, Hiroyuki*
Scripta Materialia, 239, p.115804_1 - 115804_5, 2024/01
Times Cited Count:0 Percentile:0(Nanoscience & Nanotechnology)Stress corrosion cracking (SCC) behaviors induced by the combination of external and internal hydrogen (H) in an Al-Zn-Mg-Cu alloy were systematically investigated via in situ 3D characterization techniques. SCC of the Al-Zn-Mg-Cu alloy could initiate and propagate in the potential crack region where the H concentration exceeded a critical value, in which the nanoscopic H-induced decohesion of -MgZn precipitates resulted in macroscopic cracking. External H that penetrated the alloy from the environment played a crucial role during the SCC of the Al-Zn-Mg-Cu alloy by generating gradient-distributed H-affected zones near the crack tips, which made Al alloys in water environment more sensitive to SCC. Additionally, the pre-existing internal H was driven toward the crack tips during plastic deformation. It was involved in the SCC and made contributions to both the cracks initiation and propagation.
Higa, Ryota*; Fujihara, Hiro*; Toda, Hiroyuki*; Kobayashi, Masakazu*; Ebihara, Kenichi; Takeuchi, Akihisa*
Keikinzoku, 73(11), p.530 - 536, 2023/11
In Al-Zn-Mg alloys, suppression of hydrogen embrittlement is necessary to improve their strength. In this study, the distribution of stress, strain, and hydrogen concentration in the actual fracture region was investigated using the crystal plasticity finite element method and hydrogen diffusion analysis based on a model derived from three-dimensional polycrystalline microstructural data obtained by X-ray CT. In addition, the distributions of stress, strain, and hydrogen concentration were compared with the actual crack initiation behavior by combining in-situ observation of tensile tests using X-ray CT and simulation. The results show that stress loading perpendicular to the grain boundary due to crystal plasticity dominates grain boundary crack initiation. It was also found that internal hydrogen accumulation due to crystal plasticity has little effect on crack initiation.
Yamashita, Keishiro*; Nakayama, Kazuya*; Komatsu, Kazuki*; Ohara, Takashi; Munakata, Koji*; Hattori, Takanori; Sano, Asami; Kagi, Hiroyuki*
Acta Crystallographica Section B; Structural Science, Crystal Engineering and Materials (Internet), 79(5), p.414 - 426, 2023/10
Times Cited Count:0 Percentile:0.02(Chemistry, Multidisciplinary)The structure of a recently-found hyperhydrated form of sodium chloride, NaCl 13H(D)O, has been determined by single-crystal neutron diffraction at 1.7 GPa and 298 K. It has large hydrogen-bond networks and some water molecules have distorted bonding features such as bifurcated hydrogen bonds and five-coordinated water molecules. The hydrogen-bond network has similarities to ice VI in terms of network topology and disordered hydrogen bonds. Assuming the equivalence of network components connected by pseudo symmetries, the overall network structure of this hydrate can be expressed by breaking it down into smaller structural units which correspond to the ice VI network structure. This hydrogen-bond network contains orientational disorder of water molecules in contrast to the known salt hydrates. Here, we present an example for further insights into a hydrogen-bond network containing ionic species.
Shimizu, Kazuyuki*; Toda, Hiroyuki*; Fujihara, Hiro*; Yamaguchi, Masatake; Uesugi, Masayuki*; Takeuchi, Akihisa*; Nishijima, Masahiko*; Kamada, Yasuhiro*
Corrosion, 79(8), p.818 - 830, 2023/08
Times Cited Count:0 Percentile:0(Materials Science, Multidisciplinary)7xxx aluminum alloys are representative high-strength aluminum alloys; however, mechanical property degradation due to hydrogen hinders further strengthening. We propose the dispersion of Mn-based second-phase particles as a novel technique for preventing 7xxx aluminum alloy hydrogen embrittlement. In this study, the deformation and fracture behaviors of high hydrogen 7xxx alloys containing 0.0% Mn and 0.6% Mn are observed in situ using synchrotron radiation X-ray tomography. The obtained macroscopic hydrogen embrittlement is quantitatively analyzed based on hydrogen partitioning in alloys. Adding 0.6% Mn, generating second-phase particles with high hydrogen trapping abilities, significantly suppresses hydrogen-induced quasicleavage fracture.
Tsuru, Tomohito; Nishimura, Katsuhiko*; Matsuda, Kenji*; Nunomura, Norio*; Namiki, Takahiro*; Lee, S.*; Higemoto, Wataru; Matsuzaki, Teiichiro*; Yamaguchi, Masatake; Ebihara, Kenichi; et al.
Metallurgical and Materials Transactions A, 54(6), p.2374 - 2383, 2023/06
Times Cited Count:0 Percentile:0(Materials Science, Multidisciplinary)Although hydrogen embrittlement susceptibility of high-strength Al alloys is recognized as a critical issue in the practical use of Al alloys, identifying the hydrogen trapping or distribution has been challenging. In the present study, an effective approach based on experiment and simulation is proposed to explore the potential trap sites in Al alloys. Zero-field muon spin relaxation experiments were carried out for Al-0.5%Mg, Al-0.2%Cu, Al-0.15%Ti, Al-0.011%Ti, Al-0.28%V, and Al-0.015%V (at.%) in the temperature range from 5 to 300 K. The temperature variations of the dipole field widths have revealed three peaks for Al-0.5%Mg, four peaks for Al-0.2%Cu, three peaks for Al-0.011%Ti and Al-0.015%V. Atomic configurations of the muon trapping sites corresponding to the observed peaks are well assigned using the first-principles calculations for the trap energies of hydrogen around a solute and solute-vacancy pair. The extracted linear relationship between the muon peak temperature and the trap energy enables us to explore the potential alloying elements and their complex that have strong binding energies with hydrogen in Al alloys.
Ohshima, Hiroyuki; Morishita, Masaki*; Aizawa, Kosuke; Ando, Masanori; Ashida, Takashi; Chikazawa, Yoshitaka; Doda, Norihiro; Enuma, Yasuhiro; Ezure, Toshiki; Fukano, Yoshitaka; et al.
Sodium-cooled Fast Reactors; JSME Series in Thermal and Nuclear Power Generation, Vol.3, 631 Pages, 2022/07
This book is a collection of the past experience of design, construction, and operation of two reactors, the latest knowledge and technology for SFR designs, and the future prospects of SFR development in Japan. It is intended to provide the perspective and the relevant knowledge to enable readers to become more familiar with SFR technology.
Yamashita, Keishiro*; Komatsu, Kazuki*; Ohara, Takashi; Munakata, Koji*; Irifune, Tetsuo*; Shimmei, Toru*; Sugiyama, Kazumasa*; Kawamata, Toru*; Kagi, Hiroyuki*
High Pressure Research, 42(1), p.121 - 135, 2022/03
Times Cited Count:3 Percentile:58.88(Physics, Multidisciplinary)Kusano, Kanya*; Ichimoto, Kiyoshi*; Ishii, Mamoru*; Miyoshi, Yoshizumi*; Yoden, Shigeo*; Akiyoshi, Hideharu*; Asai, Ayumi*; Ebihara, Yusuke*; Fujiwara, Hitoshi*; Goto, Tadanori*; et al.
Earth, Planets and Space (Internet), 73(1), p.159_1 - 159_29, 2021/12
Times Cited Count:6 Percentile:51.19(Geosciences, Multidisciplinary)The PSTEP is a nationwide research collaboration in Japan and was conducted from April 2015 to March 2020, supported by a Grant-in-Aid for Scientific Research on Innovative Areas from the Ministry of Education, Culture, Sports, Science and Technology of Japan. It has made a significant progress in space weather research and operational forecasts, publishing over 500 refereed journal papers and organizing four international symposiums, various workshops and seminars, and summer school for graduate students at Rikubetsu in 2017. This paper is a summary report of the PSTEP and describes the major research achievements it produced.
Otsuka, Yusuke*; Kanazawa, Naoya*; Hirayama, Motoaki*; Matsui, Akira*; Nomoto, Takuya*; Arita, Ryotaro*; Nakajima, Taro*; Hanashima, Takayasu*; Ukleev, V.*; Aoki, Hiroyuki; et al.
Science Advances (Internet), 7(47), p.eabj0498_1 - eabj0498_9, 2021/11
Times Cited Count:7 Percentile:40.96(Multidisciplinary Sciences)Go, Shintaro*; Ideguchi, Eiji*; Yokoyama, Rin*; Aoi, Nori*; Azaiez, F.*; Furutaka, Kazuyoshi; Hatsukawa, Yuichi; Kimura, Atsushi; Kisamori, Keiichi*; Kobayashi, Motoki*; et al.
Physical Review C, 103(3), p.034327_1 - 034327_8, 2021/03
Times Cited Count:4 Percentile:57.13(Physics, Nuclear)Yamamoto, Tomohiko; Kato, Atsushi; Chikazawa, Yoshitaka; Hara, Hiroyuki*
Nuclear Technology, 206(12), p.1875 - 1890, 2020/12
Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)This paper gives a detailed evaluation of the countermeasures for the external hazards and severe accidents that could impact the 2010 JSFR design building by lessons learned from the Fukushima Daiichi Nuclear Power Plant (Fukushima I NPP) accident.
Ito, Kanae; Harada, Masashi*; Yamada, Norifumi*; Kudo, Kenji*; Aoki, Hiroyuki; Kanaya, Toshiji*
Langmuir, 36(43), p.12830 - 12837, 2020/11
Times Cited Count:13 Percentile:58.64(Chemistry, Multidisciplinary)Yamaguchi, Masatake; Tsuru, Tomohito; Ebihara, Kenichi; Itakura, Mitsuhiro; Matsuda, Kenji*; Shimizu, Kazuyuki*; Toda, Hiroyuki*
Materials Transactions, 61(10), p.1907 - 1911, 2020/10
Times Cited Count:11 Percentile:55.63(Materials Science, Multidisciplinary)no abstracts in English
Ishikawa, Takatsugu*; Fujimura, Hisako*; Fukasawa, Hiroshi*; Hashimoto, Ryo*; He, Q.*; Honda, Yuki*; Hosaka, Atsushi; Iwata, Takahiro*; Kaida, Shun*; Kasagi, Jirota*; et al.
Physical Review C, 101(5), p.052201_1 - 052201_6, 2020/05
Times Cited Count:4 Percentile:45.12(Physics, Nuclear)Tang, T. L.*; Uesaka, Tomohiro*; Kawase, Shoichiro; Beaumel, D.*; Dozono, Masanori*; Fujii, Toshihiko*; Fukuda, Naoki*; Fukunaga, Taku*; Galindo-Uribarri, A.*; Hwang, S. H.*; et al.
Physical Review Letters, 124(21), p.212502_1 - 212502_6, 2020/05
Times Cited Count:14 Percentile:74.18(Physics, Multidisciplinary)The structure of a neutron-rich F nucleus is investigated by a quasifree () knockout reaction. The sum of spectroscopic factors of orbital is found to be 1.0 0.3. The result shows that the O core of F nucleus significantly differs from a free O nucleus, and the core consists of 35% O, and 65% excited O. The result shows that the O core of F nucleus significantly differs from a free O nucleus. The result may infer that the addition of the proton considerably changes the neutron structure in F from that in O, which could be a possible mechanism responsible for the oxygen dripline anomaly.
Tsuru, Tomohito; Shimizu, Kazuyuki*; Yamaguchi, Masatake; Itakura, Mitsuhiro; Ebihara, Kenichi; Bendo, A.*; Matsuda, Kenji*; Toda, Hiroyuki*
Scientific Reports (Internet), 10, p.1998_1 - 1998_8, 2020/04
Times Cited Count:31 Percentile:82.42(Multidisciplinary Sciences)Age-hardening has been one and only process to achieve high strength aluminum alloys since unlike iron and titanium, pure aluminum does not have other solid phases during heat treatment. Highly-concentrated precipitations play therefore dominant role in mechanical properties and hydrogen embrittlement of aluminium alloys. It has been considered that the coherent interface between matrix and precipitation does not contribute to the crack initiation and embrittlement due to its coherency. Here, we discovered the origin of unprecedented quasi-cleavage fracture mode. Hydrogen partitioning at various defect sites is investigated comprehensively combined with experiment, theory and first-principles calculations. We demonstrate that despite low excess free volume, the aluminum-precipitation interface is more preferable trap site than void and grain boundary. The cohesivity of the interface deteriorates significantly with increasing occupancy while hydrogen atoms are trapped stably up to extremely high occupancy equivalent to spontaneous cleavage.
Kurihara, Momo*; Yasutaka, Tetsuo*; Aono, Tatsuo*; Ashikawa, Nobuo*; Ebina, Hiroyuki*; Iijima, Takeshi*; Ishimaru, Kei*; Kanai, Ramon*; Karube, Jinichi*; Konnai, Yae*; et al.
Journal of Radioanalytical and Nuclear Chemistry, 322(2), p.477 - 485, 2019/11
Times Cited Count:2 Percentile:21.58(Chemistry, Analytical)We assessed the repeatability and reproducibility of methods for determining low dissolved radiocesium concentrations in freshwater in Fukushima. Twenty-one laboratories pre-concentrated three of 10 L samples by five different pre-concentration methods (prussian-blue-impregnated filter cartridges, coprecipitation with ammonium phosphomolybdate, evaporation, solid-phase extraction disks, and ion-exchange resin columns), and activity of radiocesium was measured. The z-scores for all of the Cs results were within 2, indicating that the methods were accurate. The relative standard deviations (RSDs) indicating the variability in the results from different laboratories were larger than the RSDs indicating the variability in the results from each separate laboratory.
Yamashiki, Yosuke*; Maehara, Hiroyuki*; Airapetian, V.*; Notsu, Yuta*; Sato, Tatsuhiko; Notsu, Shota*; Kuroki, Ryusuke*; Murashima, Keiya*; Sato, Hiroaki*; Namekata, Kosuke*; et al.
Astrophysical Journal, 881(2), p.114_1 - 114_24, 2019/08
Times Cited Count:31 Percentile:83.73(Astronomy & Astrophysics)The impact of Stellar flares on extrasolar planetary systems has been discussed and argued, especially whether there is a potential impact on their life systems. Here, we propose a comprehensive evaluation system for stellar flares, focusing on Stellar Proton Events (SPE) on selected extrasolar planets with hypothetical atmospheres and oceans. This is done by cross-linking KIC flare-observed and flare-estimated stars by their start pots that are directly linked with the Monte Carlo simulation system PHITS through the exoplanetary database system ExoKyoto. The estimated dose at ground level for each planetary surface did not exceed the critical dose for complex animals.
Toda, Hiroyuki*; Yamaguchi, Masatake; Matsuda, Kenji*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Su, H.*; Fujihara, Hiro*; Ebihara, Kenichi; Itakura, Mitsuhiro; Tsuru, Tomohito; et al.
Tetsu To Hagane, 105(2), p.240 - 253, 2019/02
Times Cited Count:0 Percentile:0(Metallurgy & Metallurgical Engineering)no abstracts in English