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Journal Articles

Experimental and modeling study on long-term alteration of compacted bentonite with alkaline groundwater

Yamaguchi, Tetsuji; Sakamoto, Yoshifumi; Akai, Masanobu; Takazawa, Mayumi; Iida, Yoshihisa; Tanaka, Tadao; Nakayama, Shinichi

Physics and Chemistry of the Earth, 32(1-7), p.298 - 310, 2007/00

 Times Cited Count:44 Percentile:72.78(Geosciences, Multidisciplinary)

Dissolution rate of montmorillonite, diffusivity of hydroxide ion and permeability coefficient in compacted sand-bentonite mixtures were experimentally determined and formulated. A coupled mass-transport/chemical-reaction code was developed to predict variation in permeability of engineered bentonite barrier with alkaline fluid by using the formulae.

Journal Articles

Experimental study on long-term safety assessment considering uncertainties for geological disposal of radioactive wastes; JAERI status at 2005

Yamaguchi, Tetsuji; Sakamoto, Yoshifumi; Iida, Yoshihisa; Negishi, Kumi; Taki, Hiroshi; Akai, Masanobu; Jinno, Fumika; Kimura, Yuichiro; Ueda, Masato; Tanaka, Tadao; et al.

Proceedings of International Conference on Nuclear Energy System for Future Generation and Global Sustainability (GLOBAL 2005) (CD-ROM), 6 Pages, 2005/10

no abstracts in English

Journal Articles

Long-term alteration of bentonite; For safety evaluation of deep geological disposal

Tanaka, Tadao; Sakamoto, Yoshifumi; Yamaguchi, Tetsuji; Takazawa, Mayumi; Akai, Masanobu; Negishi, Kumi; Iida, Yoshihisa; Nakayama, Shinichi

JAERI-Conf 2005-007, p.105 - 110, 2005/08

Highly alkaline environments induced by cementitious materials in radioactive waste repositories are likely to dissolve and to alter montmorillonite, the main constituent of bentonite buffer materials. For the prediction of the long-term variations in permeability of compacted sand-bentonite mixtures, long-term alteration of bentonite should be quantified based on information accumulated by using the compacted or powdered bentonite materials, with batch experiments or column experiments. In this study, we summarize distinctive information obtained from various experimental systems, and propose functional and effective integration of experimental approaches to prediction of bentonite alteration.

Journal Articles

Experimental and modeling study to predict long-term alteration of bentonite buffer materials with alkaline groundwater

Takazawa, Mayumi; Negishi, Kumi; Sakamoto, Yoshifumi; Akai, Masanobu; Yamaguchi, Tetsuji; Iida, Yoshihisa; Tanaka, Tadao; Nakayama, Shinichi

JAERI-Conf 2005-007, p.236 - 241, 2005/08

no abstracts in English

Journal Articles

Dissolution of montmorillonite in compacted bentonite by highly alkaline aqueous solutions and diffusivity of hydroxide ions

Nakayama, Shinichi; Sakamoto, Yoshifumi; Yamaguchi, Tetsuji; Akai, Masanobu; Tanaka, Tadao; Sato, Tsutomu*; Iida, Yoshihisa

Applied Clay Science, 27(1-2), p.53 - 65, 2004/10

 Times Cited Count:83 Percentile:89.21(Chemistry, Physical)

Alkaline environments induced by cement in radioactive waste repositories are likely to alter montmorillonite, the main constituent of bentonite buffer materials. Over long time periods, the alteration may cause the physical and/or chemical properties of the buffer to deteriorate. For the purpose of acquiring numerical data to quantify the effect of alteration on permeability of bentonite buffer, dissolution rates of montmorillonite and diffusivity of hydroxide ions in compacted sand-bentonite mixture specimens have been measured under highly alkaline, simulated groundwater conditions. The dissolution rate of montmorillonite was given by the linear dependence on time under the employed experimental conditions of pH 13 to 14 and temperatures of 90 to 170$$^{circ}$$C. The diffusivity of hydroxide ions was obtained in through-diffusion experiments combined with a pore diffusion model. The experiments were performed under relatively low temperatures of 10 to 50$$^{circ}$$C to minimize the effect of alteration of bentonite. The effective diffusivity was on the order of 10$$^{-10}$$ to 10$$^{-11}$$ m$$^{2}$$/s.

Journal Articles

Modeling of variation in permeability of compacted bentonite with alkaline fluid for long-term safety assessment of geological disposal system

Takazawa, Mayumi; Yamaguchi, Tetsuji; Sakamoto, Yoshifumi; Akai, Masanobu; Tanaka, Tadao; Nakayama, Shinichi

NUMO-TR-04-05, p.A3_59 - A3_62, 2004/10

no abstracts in English

Oral presentation

Development of a coupled mass-transport/chemical reaction code for simulating variation in hydraulic conductivity of bentonite buffer in radioactive waste disposal

Yamada, Fumika; Yamaguchi, Tetsuji; Maeda, Toshikatsu; Mizuno, Tsuyoshi; Sakamoto, Yoshifumi*; Negishi, Kumi*; Tanaka, Tadao; Iida, Yoshihisa

no journal, , 

no abstracts in English

Oral presentation

Modeling of pore-water chemistry as a common base for understanding dissolution of montmorillonite and mass transport in compacted bentonite

Iida, Yoshihisa; Yamaguchi, Tetsuji; Yamada, Fumika; Maeda, Toshikatsu; Sakamoto, Yoshifumi*; Mizuno, Tsuyoshi; Tanaka, Tadao; Nakayama, Shinichi

no journal, , 

no abstracts in English

Oral presentation

Experimental research for long term evaluation on radioactive waste disposal; Progress in 2006

Tanaka, Tadao; Yamaguchi, Tetsuji; Iida, Yoshihisa; Kimura, Yuichiro; Taki, Hiroshi; Fujiwara, Takeshi; Ueda, Masato*; Mukai, Masayuki; Yamada, Fumika; Mizuno, Tsuyoshi; et al.

no journal, , 

no abstracts in English

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