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Fukaya, Yuki; Entani, Shiro*; Sakai, Seiji*
Physical Review B, 108(15), p.155422_1 - 155422_6, 2023/10
Times Cited Count：0 Percentile：0(Materials Science, Multidisciplinary)no abstracts in English
-Al
O
(0001)Entani, Shiro*; Honda, Mitsunori; Naramoto, Hiroshi*; Li, S.*; Sakai, Seiji*
Surface Science, 704, p.121749_1 - 121749_6, 2021/02
Times Cited Count：4 Percentile：33.7(Chemistry, Physical)Graphene is expected to be one of the most promising materials for nanoelectronics and spintronics. In most graphene-based devices, the graphene channel is placed on insulating substrates. Therefore, the study of inter-facial interactions between graphene and the insulator surface is of critical importance. In this study, the vertical arrangement of graphene which is transferred on -AlO(0001) has been studied by normal incidence X-ray standing wave (NIXSW) technique. The analysis of the NIXSW profile reveals that the graphene layer is located at 3.57 (
) above the -AlO(0001) surface, which is larger than the interlayer distance of graphite at 3.356 (). Micro- Raman spectroscopy shows that the transferred graphene has a limited spatial distribution of hole concentration. The present study shows that transferred graphene on the sapphire substrate followed by vacuum-annealing has an atomically flat surface free from residual contaminations such as organic compounds and there occurs the hole-doping in graphene.
@C
; Photoelectron spectroscopy of the Li@C[PF
] salt and STM of the single Li@C molecules on Cu(111)Yamada, Yoichi*; Kuklin, A. V.*; Sato, Sho*; Esaka, Fumitaka; Sumi, Naoya*; Zhang, C.*; Sasaki, Masahiro*; Kwon, E.*; Kasama, Yasuhiko*; Avramov, P. V.*; et al.
Carbon, 133, p.23 - 30, 2018/07
Times Cited Count：17 Percentile：55.14(Chemistry, Physical)We report first STM observation of the Li ion endohedral C, which is of a new class of endohedral fullerenes, prepared by means of evaporation of high-purity Li@C[PF] salt in ultra-high vacuum. Prior to the STM measurements, the electronic structure of Li@C in the Li@C[PF] salt was also precisely determined. In the salt, it is shown that Li and PF have nearly single positive and negative charge, respectively, and the C cage is nearly neutral, suggesting that Li@C in the salt retains its original electronic state.
Entani, Shiro*; Honda, Mitsunori; Shimoyama, Iwao; Li, S.*; Naramoto, Hiroshi*; Yaita, Tsuyoshi; Sakai, Seiji*
Japanese Journal of Applied Physics, 57(4S), p.04FP04_1 - 04FP04_4, 2018/04
Times Cited Count：3 Percentile：14.78(Physics, Applied)Fukaya, Yuki; Entani, Shiro; Sakai, Seiji; Mochizuki, Izumi*; Wada, Ken*; Hyodo, Toshio*; Shamoto, Shinichi
Carbon, 103, p.1 - 4, 2016/07
Times Cited Count：22 Percentile：59.26(Chemistry, Physical)no abstracts in English
Haku, Satoshi*; Tashiro, Takaharu*; Nakayama, Hiroyasu*; Ieda, Junichi; Entani, Shiro; Sakai, Seiji; Ando, Kazuya*
Applied Physics Express, 8(7), p.073009_1 - 073009_3, 2015/07
Times Cited Count：4 Percentile：18.63(Physics, Applied)We found that the spin pumping in a Ni
Fe
/Pt bilayer is strongly suppressed by inserting single-layer graphene (SLG) at the interface. The spin pumping in the NiFe/Pt bilayer enhances the magnetization damping of the ferromagnetic layer, which is quantified from microwave frequency dependence of ferromagnetic resonance linewidth. We show that the enhancement of the magnetization damping due to the spin pumping disappears in a NiFe/SLG/Pt trilayer. This result indicates that the spin pumping is blocked by the atomic monolayer, demonstrating the crucial role of the interfacial short-range spin-exchange coupling in the spin pumping in metallic systems.
Entani, Shiro; Naramoto, Hiroshi*; Sakai, Seiji
Journal of Applied Physics, 117(17), p.17A334_1 - 17A334_4, 2015/05
Times Cited Count：20 Percentile：63.77(Physics, Applied)Entani, Shiro; Antipina, L. Y.*; Avramov, P.*; Otomo, Manabu*; Matsumoto, Yoshihiro*; Hirao, Norie; Shimoyama, Iwao; Naramoto, Hiroshi*; Baba, Yuji; Sorokin, P. B.*; et al.
Nano Research, 8(5), p.1535 - 1545, 2015/05
Times Cited Count：26 Percentile：71.65(Chemistry, Physical)Kuzubov, A. A.*; Kovaleva, E. A.*; Avramov, P. V.*; Kuklin, A. V.*; Mikhaleva, N. S.*; Tomilin, F. N.*; Sakai, Seiji; Entani, Shiro; Matsumoto, Yoshihiro*; Naramoto, Hiroshi*
Journal of Applied Physics, 116(8), p.084309_1 - 084309_4, 2014/08
Times Cited Count：9 Percentile：38.16(Physics, Applied)Avramov, P. V.*; Kuzubov, A. A.*; Sakai, Seiji; Otomo, Manabu*; Entani, Shiro; Matsumoto, Yoshihiro*; Eleseeva, N. S.*; Pomogaev, V. A.*; Naramoto, Hiroshi*
Journal of Porphyrins and Phthalocyanines, 18(7), p.552 - 568, 2014/07
Times Cited Count：1 Percentile：5.27(Chemistry, Multidisciplinary)Otomo, Manabu; Yamauchi, Yasushi*; Kuzubov, A. A.*; Eliseeva, N. S.*; Avramov, P.*; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi*; Sakai, Seiji
Applied Physics Letters, 104(5), p.051604_1 - 051604_4, 2014/02
Times Cited Count：12 Percentile：47.17(Physics, Applied)Hexagonal boron nitride (h-BN) is a promising barrier material for graphene spintronics. In this study, spin-polarized metastable de-excitation spectroscopy (SPMDS) is employed to study the spin-dependent electronic structure of monolayer h-BN on Ni(111). The extreme surface sensitivity of SPMDS enables us to elucidate a partial filling of the in-gap states of h-BN without any superposition of Ni 3
signals. The in-gap states are shown to have a considerable spin polarization parallel to the majority spin of Ni. The positive spin polarization is attributed to the 
- hybridization and the effective spin transfer to the nitrogen atoms at the h-BN/Ni(111) interface.
Mn
Si/Ge(111) heteroepitaxial interfacesNoguchi, Masaya*; Hirata, Tomoaki*; Kawakubo, Yuki*; Narumi, Kazumasa; Sakai, Seiji; Maeda, Yoshihito
Physica Status Solidi (C), 10(12), p.1732 - 1734, 2013/12
Times Cited Count：0 Percentile：0.01(Nanoscience & Nanotechnology)(Mn
Fe)Si(111) epitaxially grown on Ge(111)Kawakubo, Yuki*; Noguchi, Masaya*; Hirata, Tomoaki*; Narumi, Kazumasa; Sakai, Seiji; Yamada, Shinya*; Hamaya, Kohei*; Miyao, Masanobu*; Maeda, Yoshihito
Physica Status Solidi (C), 10(12), p.1828 - 1831, 2013/12
Times Cited Count：0 Percentile：0.01(Nanoscience & Nanotechnology)Matsumoto, Yoshihiro; Entani, Shiro; Koide, Akihiro*; Otomo, Manabu; Avramov, P.; Naramoto, Hiroshi*; Amemiya, Kenta*; Fujikawa, Takashi*; Sakai, Seiji
Journal of Materials Chemistry C, 1(35), p.5533 - 5537, 2013/09
Times Cited Count：32 Percentile：76.99(Materials Science, Multidisciplinary)
][1]benzothiophene monolayer on bismuth-terminated Si(111) vicinal surfaces with wettability optimizationOtomo, Manabu; Tsuchida, Yuya*; Muraya, Naoki*; Yanase, Takashi*; Sakai, Seiji; Yonezawa, Tetsu*; Nagahama, Taro*; Hasegawa, Tetsuya*; Shimada, Toshihiro*
Journal of Physical Chemistry C, 117(22), p.11555 - 11561, 2013/06
Times Cited Count：2 Percentile：8.72(Chemistry, Physical)We report in-plane orientation control of newly developed high-mobility organic semiconductor: 2,7-diphenyl[1]benzothieno[3,2-][1]benzothiophene (DPh-BTBT). As previously reported on monolayer pentacene, it was revealed that bunched steps on vicinal Si(111) with bismuth termination break the surface symmetry and reduce three-fold symmetry of DPh-BTBT grains into quasi-single orientation. Interestingly, the critical step height necessary for the orientation control was different from that of pentacene. We examined several mechanisms of orientation control and concluded that the facet nano structure fabricated by step bunching is working as an anisotropic template. We will also show the wettability control of bismuth terminated silicon surface and show that the growth mode of DPh-BTBT is dependent on the surface nanostructure of Bi-Si.
interface in the Fe-doped C filmSakai, Seiji; Matsumoto, Yoshihiro; Otomo, Manabu; Entani, Shiro; Avramov, P.; Sorokin, P. B.*; Naramoto, Hiroshi*
Synthetic Metals, 173, p.22 - 25, 2013/06
Times Cited Count：2 Percentile：10.3(Materials Science, Multidisciplinary)
-BN/Ni nanocompositesAvramov, P.; Kuzubov, A. A.*; Sakai, Seiji; Otomo, Manabu; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi*; Eliseeva, N. S.*
Journal of Applied Physics, 112(11), p.114303_1 - 114303_10, 2012/12
Times Cited Count：18 Percentile：59.41(Physics, Applied)
-FeSi nanocrystalsMaeda, Yoshihito; Nishimura, Kentaro*; Nakajima, Takahito*; Matsukura, Bui*; Narumi, Kazumasa; Sakai, Seiji
Physica Status Solidi (C), 9(10-11), p.1884 - 1887, 2012/10
Times Cited Count：4 Percentile：88.47(Materials Science, Multidisciplinary)We report enhancement of intrinsic photoluminescence (PL) from -FeSi nanocrystals by doping carbon. In the appropriate dose of C ion implantation into the average nanocrystal size of 14 nm, the PL intensity was enhanced by 260% and increase of the exciton binding energy of 1.8 meV in comparison with that of the non-doped nanocrystal. Furthermore, we found that there was a clear correlation between the PL enhancement and increase of the exciton binding energy. This important result suggests that carbon atoms doped in the silicide lattice may play as an isoelectronic trap and probably form bound excitons with stable states as predicted theoretically. We found a new mechanism of the PL enhancement for -FeSi nanocrystals.
-FeSi nanocrystals embedded in SiMaeda, Yoshihito; Nishimura, Kentaro*; Nakajima, Takahito*; Matsukura, Bui*; Narumi, Kazumasa; Sakai, Seiji
Physica Status Solidi (C), 9(10-11), p.1888 - 1891, 2012/10
Times Cited Count：3 Percentile：83.25(Materials Science, Multidisciplinary)We have systematically investigated photoluminescence (PL) properties of -phase nanocrystals which are formed by a phase transition from metastable 
-FeSi with a Fluorite structure to -FeSi, and succeeded in enhancement of the PL intensity in the optimum conditions of double annealing process. For the PL enhancement, the time of postannealing at 800
C is dominated by the time of the preannealing at 400 or 500C which is related to amount of the -phase. After discussing some possible factors, we speculate that the PL enhancement observed in this study may be attributed mainly to improvement of the interface condition between the nanocrystal and Si, because the crystallographic epitaxial relationship among the phases, Si(111)//(111)//(202)/(220) can be maintained during precipitation of the nanocrystal on Si(111).
Avramov, P.; Fedorov, D. G.*; Sorokin, P. B.*; Sakai, Seiji; Entani, Shiro; Otomo, Manabu; Matsumoto, Yoshihiro; Naramoto, Hiroshi*
Journal of Physical Chemistry Letters (Internet), 3(15), p.2003 - 2008, 2012/08
Times Cited Count：36 Percentile：79.49(Chemistry, Physical)