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Masuda, Toshiyuki*; Arase, Junko*; Inagaki, Yusuke*; Kawahara, Masatoshi*; Yamaguchi, Kentaro*; Ohara, Takashi; Nakao, Akiko*; Momma, Hiroyuki*; Kwon, E.*; Setaka, Wataru*
Crystal Growth & Design, 16(8), p.4392 - 4401, 2016/08
Times Cited Count:27 Percentile:87.56(Chemistry, Multidisciplinary)Agui, Akane; Masuda, Ryo*; Kobayashi, Yasuhiro*; Kato, Tadashi*; Emoto, Shun*; Suzuki, Kosuke*; Sakurai, Hiroshi*
Journal of Magnetism and Magnetic Materials, 408, p.41 - 45, 2016/06
Times Cited Count:4 Percentile:21.26(Materials Science, Multidisciplinary)We investigated the magnetization process of Fe (110) film using the field dependence of magnetic Compton scattering and Mssbauer spectroscopy. From the magnetic Compton profiles, the spin and orbital magnetic moment specific magnetization versus magnetizing field curves were obtained. From the Mssbauer spectra, the angles between the magnetizing field and the magnetic moment were obtained. It was found that the magnetizing field dependence of the ratio between orbital moment and spin moment was related to the angles between the magnetizing field and the magnetic moment. We indicate that the magnetic field dependence of the orbital magnetic moment plays a role in the magnetization process.
Masuda, Ryo*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Kurokuzu, Masayuki*; Saito, Makina*; Yoda, Yoshitaka*; Mitsui, Takaya; Hosoi, Kohei*; Kobayashi, Hirokazu*; Kitagawa, Hiroshi*; et al.
Scientific Reports (Internet), 6, p.20861_1 - 20861_8, 2016/02
Times Cited Count:9 Percentile:40.77(Multidisciplinary Sciences)Mibu, Ko*; Mitsui, Takaya; Tanaka, Masaaki*; Masuda, Ryo*; Kitao, Shinji*; Kobayashi, Yasuhiro*; Yoda, Yoshitaka*; Seto, Makoto*
Journal of Applied Physics, 117(17), p.17E126_1 - 17E126_4, 2015/05
Times Cited Count:2 Percentile:9.14(Physics, Applied)Mitsui, Takaya; Imai, Yasuhiko*; Masuda, Ryo*; Seto, Makoto*; Mibu, Ko*
Journal of Synchrotron Radiation, 22(2), p.427 - 435, 2015/03
Times Cited Count:11 Percentile:49.69(Instruments & Instrumentation)Murakami, Motohiko*; Goncharov, A. F.*; Hirao, Naohisa*; Masuda, Ryo*; Mitsui, Takaya; Thomas, S. M.*; Bina, C. R.*
Nature Communications (Internet), 5, p.5428_1 - 5428_6, 2014/11
Times Cited Count:19 Percentile:51.61(Multidisciplinary Sciences)Mashimo, Izumi*; Otani, Eiji*; Hirao, Naohisa*; Mitsui, Takaya; Masuda, Ryo*; Seto, Makoto*; Sakai, Takeshi*; Takahashi, Suguru*; Nakano, Satoshi*
American Mineralogist, 99(8-9), p.1555 - 1561, 2014/08
Times Cited Count:7 Percentile:24.02(Geochemistry & Geophysics)Kurokuzu, Masayuki*; Kitao, Shinji*; Kobayashi, Yasuhiro*; Saito, Makina*; Masuda, Ryo*; Mitsui, Takaya; Yoda, Yoshitaka*; Seto, Makoto*
Hyperfine Interactions, 226(1), p.687 - 691, 2014/04
Times Cited Count:3 Percentile:69.82(Physics, Atomic, Molecular & Chemical)Kurokuzu, Masayuki*; Kitao, Shinji*; Kobayashi, Yasuhiro*; Saito, Makina*; Masuda, Ryo*; Mitsui, Takaya; Yoda, Yoshitaka*; Seto, Makoto*
Journal of the Physical Society of Japan, 83(4), p.044708_1 - 044708_4, 2014/04
Times Cited Count:2 Percentile:20.41(Physics, Multidisciplinary)Masuda, Ryo*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Kurokuzu, Masayuki*; Saito, Makina*; Yoda, Yoshitaka*; Mitsui, Takaya; Iga, Fumitoshi*; Seto, Makoto
Applied Physics Letters, 104(8), p.082411_1 - 082411_5, 2014/02
Times Cited Count:21 Percentile:65.2(Physics, Applied)A detection system for synchrotron-radiation (SR)-based Mssbauer spectroscopy was developed to enhance the nuclear resonant scattering counting rate and thus increase the available nuclides. In the system, a windowless avalanche photodiode (APD) detector was combined with a vacuum cryostat to detect the internal conversion (IC) electrons and fluorescent X-rays accompanied by nuclear de-excitation. As a feasibility study, the SR-based Mssbauer spectrum using the 76.5 keV level of Yb was observed without Yb enrichment of the samples. The counting rate was five times higher than that of our previous system, and the spectrum was obtained within 10 h. This result shows that nuclear resonance events can be more efficiently detected by counting IC electrons for nuclides with high IC coefficients. Furthermore, the windowless detection system enables us to place the sample closer to the APD elements and is advantageous for nuclear resonant inelastic scattering measurements. Therefore, this detection system can not only increase the number of nuclides accessible in SR-based Mssbauer spectroscopy but also allows the nuclear resonant inelastic scattering measurements of small single crystals or enzymes with dilute probe nuclides that are difficult to measure with the previous detection system.
Mitsui, Takaya; Masuda, Ryo*; Seto, Makoto; Hirao, Naohisa*; Matsuoka, Takehiro*; Nakamura, Yumiko*; Sakaki, Koji*; Enoki, Hirotoshi*
Journal of Alloys and Compounds, 580(Suppl.1), p.S264 - S267, 2013/12
Times Cited Count:8 Percentile:42.73(Chemistry, Physical)Mitsui, Takaya; Masuda, Ryo; Hirao, Naohisa*; Mibu, Ko*; Seto, Makoto
Hyperfine Interactions, 204(1-3), p.97 - 100, 2012/04
Times Cited Count:4 Percentile:87.07(Physics, Atomic, Molecular & Chemical)Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Sakaki, Koji*; Enoki, Hirotoshi*; Nakamura, Yumiko*; Seto, Makoto
Hyperfine Interactions, 204(1-3), p.139 - 142, 2012/03
Times Cited Count:2 Percentile:76.72(Physics, Atomic, Molecular & Chemical)We have been developing a system for in situ Mssbauer studies using synchrotron radiation (SR) to elucidate the mechanism of hydrogenation processes. In the system, samples reacts in an atmosphere chamber and SR-based Mssbauer spectra using variable-frequency nuclear monochromator and energy spectra of inelastic nuclear resonant scattering (NRS) of SR are measured. As a feasibility study, the temperature dependence of the Mssbauer and inelastic NRS spectra of Fe in -GdFeH under vacuum were measured. In both spectra, clear differences were observed between 373 K and 573 K. These differences can be interpreted by the change of microscopic environment around Fe at the dehydrogenation. Thus, it is confirmed that this system works well enough to perform the in-situ Mssbauer study on the dehydrogenation of -GdFeH.
Mitsui, Takaya; Masuda, Ryo*; Seto, Makoto; Suharyadi, E.*; Mibu, Ko*
Journal of Synchrotron Radiation, 19(2), p.198 - 204, 2012/03
Times Cited Count:20 Percentile:66.69(Instruments & Instrumentation)An energy-domain grazing-incidence Fe-Mssbauer spectroscopy(E-GIMS) with synchrotron radiation (SR) has been developed to studysurface and interface structures of thin films. A high-brilliant Fe-Mssbauer radiation, filtered from SR by a FeBO single crystal nuclear Bragg monochromator (NBM), allows us to perform the conventional Mssbauer spectroscopy (MS) for the dilute Fe in a mirror-like film in any bunch-mode operation of SR. Theoretical and experimental study of the specular reflections from isotope-enriched (Fe: 95%) and natural-abundance (Fe: 2%) iron thin films has been carried out to clarify the basic features of coherent interference between electronic and nuclear resonant scattering of Fe-Mo"ssbauer radiation in thin films. Moreover, a new surface and interface sensitive method has been developed by the combination of SR based E-GIMS and Fe-probe layer technique, which enables us to probe interfacial complex magnetic structures in thin film with atomic-scale depth resolution.
Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Seto, Makoto
Journal of the Physical Society of Japan, 81(3), p.034714_1 - 034714_6, 2012/03
Times Cited Count:3 Percentile:26.68(Physics, Multidisciplinary)Kameyama, Hideo*; Sakurai, Makoto*; Masuda, Akiyuki*; Fukui, Tomoaki*; Onuki, Kaoru; Kubo, Shinji; Imai, Yoshiyuki
Suiso Enerugi Shisutemu, 37(1), p.3 - 10, 2012/03
The technical present status of hydrogen production process using IS thermochemical cycle was introduced. This process is experimentally investigated in Japan, U.S.A., Germany, France, Italy, India, China and Korea. Japan Atomic Energy Agency succeeded in consecutive hydrogen production as a proof examination. The trend of the research and development about the reactions, separation technology, device materials and the process equipment were reported. Thermochemical ammonia production cycle was also introduced. This new cycle is named ISN cycle which was modified from IS cycle in order to produce ammonia from water and nitrogen.
Matsuoka, Takahiro*; Fujihisa, Hiroshi*; Hirao, Naohisa*; Oishi, Yasuo*; Mitsui, Takaya; Masuda, Ryo; Seto, Makoto*; Yoda, Yoshitaka*; Shimizu, Katsuya*; Machida, Akihiko; et al.
Physical Review Letters, 107(2), p.025501_1 - 025501_4, 2011/07
Times Cited Count:28 Percentile:77.59(Physics, Multidisciplinary)Europium-hydride EuH exposed to high-pressure H conditions has been found to exhibit structural and valence changes, (=2, divalent) 63/ (=2, 7.2-8.7 GPa) 4/ (2, 8.7-9.7 GPa) 4/ (2, 9.7 GPa-, trivalent). Having trivalent character and distorted cubic fcc structure, the 4/ structure is the -phase which has been commonly observed for other rare-earth metal hydrides. Our study clearly demonstrates that EuH is no longer an "irregular" member of the rare earth metal hydrides.
Masuda, Ryo; Mitsui, Takaya; Kobayashi, Yasuhiro*; Higashitaniguchi, Satoshi*; Seto, Makoto
Japanese Journal of Applied Physics, 48(12), p.120221_1 - 120221_3, 2009/12
Times Cited Count:8 Percentile:33.37(Physics, Applied)A neV-resolution spectrometer using 14.4 keV synchrotron-based Fe Mssbauer radiation has been developed to observe the quasi-elastic scattering by condensed matter. It consists of a FeO nuclear resonant Bragg monochromator and a Fe stainless steel nuclear analyzer. As a feasibility study, the quasi-elastic scattering by supercooled glycerol near its melting point has been observed. The instrumental function of the spectrometer was 42.2 neV. The energy broadening of 11 neV due to the quasi-elastic scattering was observed.
Seto, Makoto; Masuda, Ryo; Higashitaniguchi, Satoshi*; Kitao, Shinji*; Kobayashi, Yasuhiro*; Inaba, Chika*; Mitsui, Takaya; Yoda, Yoshitaka*
Physical Review Letters, 102(21), p.217602_1 - 217602_4, 2009/05
Times Cited Count:57 Percentile:88.05(Physics, Multidisciplinary)We have developed a new method that yields Mssbauer absorption spectra using synchrotron radiation (SR); this method is applicable for almost all Mssbauer nuclides including those that cannot be measured by previous methods using radioisotope (RI) sources. The Mssbauer spectrum of the 68.752 keV excited state of Ge, which cannot be measured using a RI source, was measured using SR. Our results show that this method can be used to perform advanced Mssbauer spectroscopy measurements owing to the excellent features of SR.
Mitsui, Takaya; Seto, Makoto; Masuda, Ryo; Kobayashi, Yasuhiro*; Kitao, Shinji*
Japanese Journal of Applied Physics, 47(9), p.7136 - 7139, 2008/10
Times Cited Count:7 Percentile:30.06(Physics, Applied)no abstracts in English