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Journal Articles

Mineralogical factors causing underestimation of $$K$$$$_{rm d}$$ values calculated from radiocesium interception potential

Uno, Koichiro*; Nakao, Atsushi*; Okumura, Masahiko; Yamaguchi, Akiko; Kogure, Toshihiro*; Yanai, Junta*

Nihon Dojo Hiryo Gaku Zasshi, 94(5), p.376 - 384, 2023/10

Radiocesium interception potential (RIP) has been widely used as a quantitative indicator of cesium (Cs) adsorption capacity of soil, but it has been found that RIP does not always correlate with the distribution coefficient ($$K$$$$_{rm d}$$) of Cs in the actual environment. In order to clarify the cause of this discrepancy, we measured Kd using more realistic solutions, compared it with RIP, and evaluated the mineral structure. As a result, it was found that the concentration of competing cations, such as potassium and ammonium ions, and the structural change of the mineral itself are important.

Oral presentation

Are solution conditions of RIP optimal for estimating transfer risk?

Uno, Koichiro*; Nakao, Atsushi*; Okumura, Masahiko; Kogure, Toshihiro*; Wagai, Rota*; Yamaguchi, Akiko; Yanai, Junta*

no journal, , 

no abstracts in English

Oral presentation

Mechanism of soil-to-plant transfer of Cs and K using element-substituted biotite

Uno, Koichiro*; Nakao, Atsushi*; Okumura, Masahiko; Kogure, Toshihiro*; Yamaguchi, Akiko; Takeda, Hikaru*; Maruyama, Hayato*; Shinano, Takuro*; Yanai, Junta*

no journal, , 

Biotite inhibits radiocesium (RCs) transfer from soil to plants by two functions of selective adsorption of radiocesium (Cs) between layers (Cs adsorption ability) and K supply from between layers (K supply ability). However, it was difficult to distinguish between the two. In this study, the authors succeeded in preparing biotite in which both functions are variously different by preparing weathered biotite in which interlayer pottasium (K) was replaced with rubidium (Rb) to lose K supply ability. By systematically comparing these biotites, the authors clarified the effects of Cs adsorption ability and K supply ability on Cs transfer to plants.

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