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Journal Articles

Immobilisation of caesium by zeolites and characterisation of ceramic solid forms

Tomiyama, Shin*; Mimura, Hitoshi*; Niibori, Yuichi*; Yamagishi, Isao; Morita, Yasuji

Proceedings of 11th OECD/NEA Information Exchange Meeting on Actinide and Fission Product Partitioning and Transmutation (Internet), 10 Pages, 2012/00

The immobilization of Cs has been studied by the calcination of the Cs-form of various kinds of mordenites. In this study, the effect of various parameters such as calcining temperature and time, components in mordenites, conditions for cold and hot pressing, on the immobilization of Cs in ceramic products are evaluated by using X-ray diffractometry (XRD), density balance (Archimedes' method), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). Results showed that recrystallization to the stable ceramic solid forms of CsAlSi$$_{5}$$O$$_{12}$$ was achieved only in calcination of Synthetic Mordenite-C which contains Ti and Fe as binder. The Cs-form mordenites were pelletized into a disk by cold isostatic pressing and the density of the solid forms increased with calcining temperature and time.

JAEA Reports

Development Tools for Large-Scale Computer Programs

*; Tsunematsu, Toshihide; ; ; Takeda, Tatsuoki; ; *;

JAERI-M 85-142, 72 Pages, 1985/10

JAERI-M-85-142.pdf:1.73MB

no abstracts in English

Oral presentation

Immobilization of cesium using zeolites

Tomiyama, Shin*; Mimura, Hitoshi*; Niibori, Yuichi*; Yamagishi, Isao; Morita, Yasuji

no journal, , 

Immobilization of cesium separated from high-level liquid waste was studied by using a mordenite, which adsorbs cesium selectively. Ceramic samples were prepared by pressing and sintering the mordenite loaded with cesium. Ceramics of the higher density were obtained by sintering the pressed mordenites of the smaller particle size. The density of the sample sintered with pressing, which is called hot-pressing, was higher than that of the sample sintered after pressing by a facor of 1.5.

Oral presentation

Immobilization of cesium by zeolites and characterization of ceramic solid forms

Tomiyama, Shin*; Mimura, Hitoshi*; Niibori, Yuichi*; Yamagishi, Isao; Morita, Yasuji

no journal, , 

The immobilization of Cs has been studied by the calcination of the Cs-form of various kinds of mordenites. In this study, the effect of various parameters such as calcining temperature and time, components in mordenites, conditions for cold and hot pressing, on the immobilization of Cs in ceramic products are evaluated by using X-ray diffractometry (XRD), density balance (Archimedes' method), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). Results showed that re-crystallization to the stable ceramic solid forms of CsAlSi$$_{5}$$O$$_{12}$$ was achieved only in calcination of Synthetic Mordenite-C which contains Ti and Fe as binder. The Cs-form mordenites were pelletized into a disk by cold isostatic pressing.

Oral presentation

Immobilization of cesium by zeolites and characterization of solid forms

Tomiyama, Shin*; Mimura, Hitoshi*; Niibori, Yuichi*; Yamagishi, Isao; Morita, Yasuji

no journal, , 

The immobilization of Cs has been studied by the calcination of the Cs-form of various kinds of mordenites. In this study, the effect of various parameters such as calcining temperature and time, components in mordenites, conditions for cold and hot pressing, on the immobilization of Cs in ceramic products are evaluated by using X-ray diffractometry (XRD), density balance (Archimedes' method), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). Results showed that re-crystallization to the stable ceramic solid forms of CsAlSi$$_{5}$$O$$_{12}$$ was achieved only in calcination of Synthetic Mordenite-C which contains Ti and Fe as binder. The Cs-form mordenites were pelletized into a disk by cold isostatic pressing.

Oral presentation

Measurement and analysis of radiolytically generated hydrogen from HALW, 1; Measurement and evaluation of the hydrogen concentration in the vessel off-gas

Tomiyama, Masahiro; Yasuda, Takeshi; Tsutagi, Koichi; Yoshino, Yasuyuki; Shirato, Yoji; Nakamura, Yoshinobu; Kinuhata, Hiroshi*; Kodama, Takashi*; Nakano, Masanao*; Tamauchi, Yoshikazu*; et al.

no journal, , 

no abstracts in English

Oral presentation

Measurement and analysis of radiolytically generated hydrogen from HALW, 2; Comparison of measured hydrogen concentration and its estimation

Kinuhata, Hiroshi*; Kodama, Takashi*; Nakano, Masanao*; Tamauchi, Yoshikazu*; Matsuoka, Shingo*; Tomiyama, Masahiro; Yasuda, Takeshi; Tsutagi, Koichi; Yoshino, Yasuyuki; Shirato, Yoji; et al.

no journal, , 

no abstracts in English

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