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JAEA Reports

Physical property investigation of gloves for glove boxes in nuclear fuel reprocessing plants; Physical properties of used gloves and estimation of its life-time

Yamamoto, Masahiko; Nishida, Naoki; Kobayashi, Daisuke; Nemoto, Ryo*; Hayashi, Hiroyuki*; Kitao, Takahiko; Kuno, Takehiko

JAEA-Technology 2023-004, 30 Pages, 2023/06

JAEA-Technology-2023-004.pdf:1.94MB

Glove-box gloves, that are used for handling nuclear fuel materials at the Tokai Reprocessing Plant (TRP) of the Japan Atomic Energy Agency, have an expiration date by internal rules. All gloves are replaced at a maximum of every 4-year. However, degrees of glove deterioration varies depending on its usage environment such as frequency, chemicals, and radiation dose. Therefore, physical properties such as tensile strength, elongation, hardness of gloves are measured and technical evaluation method for the glove life-time is established. It was found that gloves without any defects in its appearance have enough physical properties and satisfies the acceptance criteria values of new gloves. Thus, it was considered that the expired gloves could be used for total of 8-year, by adding 4-year of new glove life-time. In addition, the results of extrapolation by plotting the glove's physical properties versus the used years showed that the physical properties at 8-year is on the safer side than the reported physical properties of broken glove. Also, the data are not significantly different from the physical properties of the long-term storage glove (8 and 23 years). Based on these results, life-time of gloves at TRP is set to be 8-year. The frequency of glove inspections are not changed, and if any defects is found, the glove is promptly replaced. Thus, the risk related to glove usage is not increased. The cost of purchasing gloves, labor for glove replacement, and the amount of generated waste can be reduced by approximately 40%, respectively, resulting in more efficient and rationalized glove management.

Journal Articles

Investigation of physical properties of glove for glove-box and estimation of its life-time

Kobayashi, Daisuke; Yamamoto, Masahiko; Nishida, Naoki; Miyoshi, Ryuta; Nemoto, Ryo*; Hayashi, Hiroyuki*; Kato, Keisuke; Nishino, Saki; Kuno, Takehiko; Kitao, Takahiko; et al.

Nihon Hozen Gakkai Dai-18-Kai Gakujutsu Koenkai Yoshishu, p.237 - 240, 2022/07

All gloves attached to glove-box in Tokai Reprocessing Plant have a fixed expiration date and have to be replaced every 4-year. However, degrees of glove deterioration are different depending on its usage environment (frequency, chemicals, radiation, etc.), because of rubber products. Therefore, physical properties such as tensile strength, elongation, hardness of gloves are measured, and the life-time of gloves are estimated. As a result, gloves without any defects in its appearance have enough physical property for acceptance criteria of new glove. The extrapolated physical property of glove is sufficiently larger than the reported values of damaged glove. No deterioration in physical properties of gloves, that are periodically replaced without any defects in its appearance, is observed and the usable life-time of the glove is estimated to be 8 years.

Journal Articles

Oxidation mechanisms of hafnium overlayers deposited on an Si(111) substrate

Kakiuchi, Takuhiro*; Matoba, Tomoki*; Koyama, Daisuke*; Yamamoto, Yuki*; Yoshigoe, Akitaka

Langmuir, 38(8), p.2642 - 2650, 2022/03

 Times Cited Count:1 Percentile:14.86(Chemistry, Multidisciplinary)

0xidation processes at the interface and the surface of Si(111) substrate with thin Hf films were studied using photoelectron spectroscopy in conjunction with supersonic oxygen molecular beams (SOMB). The oxidation starts at the outermost Hf layers and produces stoichiometric HfO$$_{2}$$. Hf silicates (Hf-O-Si configuration) were generated in the vicinity of the HfO$$_{2}$$/Si interface in the case of the irradiation of 2.2 eV SOMB. The oxidation of the Si substrate takes place to generate SiO$$_{2}$$ compounds. Si atoms were emitted from the SiO$$_{2}$$/Si interface region underneath the HfO$$_{2}$$ overlayers to release the stress generated within the strained Si layers. The emitted Si atoms can pass through the HfO$$_{2}$$ overlayers and react with the impinging O$$_{2}$$ gas.

Journal Articles

Precise chemical state analyses of ultrathin hafnium films deposited on clean Si(111)-7$$times$$7 surface using high-resolution core-level photoelectron spectroscopy

Kakiuchi, Takuhiro*; Matoba, Tomoki*; Koyama, Daisuke*; Yamamoto, Yuki*; Kato, Daiki*; Yoshigoe, Akitaka

Surface Science, 701, p.121691_1 - 121691_8, 2020/11

 Times Cited Count:1 Percentile:6.04(Chemistry, Physical)

Ultrathin hafnium films on Si(111)-7$$times$$7 were studied using synchrotron radiation photoelectron spectroscopies to reveal the chemical states at interface and surface. Ultrathin Hf layers grow on clean Si(111)-7$$times$$7 surface by lever rule. Surface and interface of Hf/Si(111) contain three components (metallic Hf layers, Hf monosilicide (HfSi) and Si-rich Hf silicide). Ultrathin Hf layers changes HfSi$$_{2}$$ islands on bared Si(111)-7$$times$$7 surface after annealing at 1073 K. It was found that the long axes of the rectangle islands expand the direction connecting the corner holes in DAS model of clean Si(111)-7$$times$$7 surface.

Journal Articles

Characterization of two types of cesium-bearing microparticles emitted from the Fukushima accident via multiple synchrotron radiation analyses

Miura, Hikaru*; Kuribara, Yuichi; Yamamoto, Masayoshi*; Sakaguchi, Aya*; Yamaguchi, Noriko*; Sekizawa, Oki*; Nitta, Kiyofumi*; Higaki, Shogo*; Tsumune, Daisuke*; Itai, Takaaki*; et al.

Scientific Reports (Internet), 10, p.11421_1 - 11421_9, 2020/07

 Times Cited Count:18 Percentile:68.95(Multidisciplinary Sciences)

Journal Articles

Detailed structural study on the poly(vinyl alcohol) adsorption layers on a Si substrate with solvent vapor-induced swelling

Miyazaki, Tsukasa*; Miyata, Noboru*; Yoshida, Tessei*; Arima, Hiroshi*; Tsumura, Yoshihiro*; Torikai, Naoya*; Aoki, Hiroyuki; Yamamoto, Katsuhiro*; Kanaya, Toshiji*; Kawaguchi, Daisuke*; et al.

Langmuir, 36(13), p.3415 - 3424, 2020/04

 Times Cited Count:14 Percentile:58.64(Chemistry, Multidisciplinary)

Journal Articles

Elucidation of a heterogeneous layered structure in the thickness direction of poly(vinyl alcohol) films with solvent vapor-induced swelling

Miyazaki, Tsukasa*; Miyata, Noboru*; Asada, Mitsunori*; Tsumura, Yoshihiro*; Torikai, Naoya*; Aoki, Hiroyuki; Yamamoto, Katsuhiro*; Kanaya, Toshiji*; Kawaguchi, Daisuke*; Tanaka, Keiji*

Langmuir, 35(34), p.11099 - 11107, 2019/08

 Times Cited Count:22 Percentile:67.64(Chemistry, Multidisciplinary)

Journal Articles

Localized magnetic excitations in the fully frustrated dimerized magnet Ba$$_{2}$$CoSi$$_{2}$$O$$_{6}$$Cl$$_{2}$$

Kurita, Nubuyuki*; Yamamoto, Daisuke*; Kanesaka, Takuya*; Furukawa, Nobuo*; Kawamura, Seiko; Nakajima, Kenji; Tanaka, Hidekazu*

Physical Review Letters, 123(2), p.027206_1 - 027206_6, 2019/07

 Times Cited Count:4 Percentile:36.66(Physics, Multidisciplinary)

Journal Articles

Basic vacuum test of 500-kV photocathode DC gun components at KEK

Yamamoto, Masahiro*; Uchiyama, Takashi*; Miyajima, Tsukasa*; Honda, Yosuke*; Sato, Kotaro*; Matsuba, Shunya*; Saito, Yoshio*; Kobayashi, Masanori*; Kurisu, Hiriki*; Hajima, Ryoichi; et al.

Proceedings of 7th Annual Meeting of Particle Accelerator Society of Japan (DVD-ROM), p.717 - 720, 2010/08

A 500-kV photocathode DC electron gun which can supply the beam of a low emittance and a high average current has been developed in collaboration with KEK, JAEA, Hiroshima Univ., Nagoya Univ. and Yamaguchi Univ. The vacuum of the gun chamber has to be lower Extreme High Vacuum for maintain cathode-life time. A titanium chamber and new material of ceramic were employed to reduce outgassing rate. The result of outgassing rate of the gun chamber is described in this report.

Journal Articles

Design of a 500kV electron gun for ERL light source at KEK

Yamamoto, Masahiro*; Honda, Yosuke*; Miyajima, Tsukasa*; Uchiyama, Takashi*; Kobayashi, Masanori*; Muto, Toshiya*; Matsuba, Shunya*; Sakanaka, Shogo*; Sato, Kotaro*; Saito, Yoshio*; et al.

Proceedings of 6th Annual Meeting of Particle Accelerator Society of Japan (CD-ROM), p.860 - 862, 2009/08

A newly 500 kV electron gun (2nd - 500 kV gun) for an ERL light source is designed at KEK. A new concept and state of-the-art technologies of vacuum system, ceramic insulators, high voltage power supply, photocathode and preparation system will be employed. The details are described in this report.

JAEA Reports

Application study on low alkaline cementitious materials for deep geological repository of high level radioactive wastes, 2; Organization of previous finding and understanding of material properties of low alkaline cement (Joint research)

Kobayashi, Yasushi; Yamada, Tsutomu; Naito, Morimasa; Yui, Mikazu; Nakayama, Masashi; Sato, Haruo; Nishida, Takahiro*; Hironaga, Michihiko*; Yamamoto, Takeshi*; Sugiyama, Daisuke*; et al.

JAEA-Research 2009-013, 70 Pages, 2009/06

JAEA-Research-2009-013.pdf:8.85MB

Cementitious materials will be used to ensure construction and operational safety and work efficiency in a deep geological repository. The low alkaline cement has been developed to reduce uncertainties due to hyper alkaline for the long-term safety performance of the repository system. Functions of cementitious material required in each phase of repository construction, operation and closure were summarized in a separate report entitled "Application Study on Low Alkaline Cementitious Materials for Deep Geological Repository of High Level Radioactive Wastes (Phase I) "In this report, properties of low alkaline cement/concrete which have been developed both at home and abroad, and recipes of the low alkaline concrete taken account of application to the repository component have been investigated. Fresh and hardened properties of the low alkaline cement are equivalent to the OPC and the low alkaline cement has an advantage over OPC in terms of leaching resistance. The HFSC developed by JAEA, which belongs to a pozzolanic type low alkaline cement will be able to apply to the shotcrete and the lining concrete by choosing an adequate recipe. Clarification of influences of the chemical composition of groundwater on leachate properties of the hydrates, examination of pH measurement of cement leachate, evaluation of corrosion behavior of rebar embedded in the HFSC concrete are raised as open questions for future activities.

JAEA Reports

Application study on low alkaline cementitious materials for deep geological repository of high level radioactive wastes, 1; Requirements for use of cementitious materials in deep geological repository system (Joint research)

Kobayashi, Yasushi; Yamada, Tsutomu; Naito, Morimasa; Yui, Mikazu; Nakayama, Masashi; Sato, Haruo; Nishida, Takahiro*; Hironaga, Michihiko*; Yamamoto, Takeshi*; Sugiyama, Daisuke*; et al.

JAEA-Research 2008-112, 43 Pages, 2009/03

JAEA-Research-2008-112.pdf:4.58MB

In deep geological repository, use of cementitious material for rock support, lining, and grouting is essential for construction and operation and possibly raises in groundwater pH due to leachate from the cements. Since this hyperalkaline condition may lead to degradation of barriers, there is concern that it gives significant impact on long-term safety performance of the repository system. Because of these backgrounds, developments of low alkaline cement have been conducted both at home and abroad. JAEA is now planning to conduct an in-situ test for shotcreting using low alkaline cement at the Horonobe URL. On the other hand, CRIEPI has studied and developed cementitious materials for disposal of radioactive wastes. This joint research report summarizes requirements and expected performance of cementitious materials in repository taking account of surrounding conditions in each stage of the repository program so as to reflect them to further development of the low alkaline cement.

Journal Articles

Redox front formation in an uplifting sedimentary rock sequence; An Analogue for redox-controlling processes in the geosphere around deep geological repositories for radioactive waste

Yoshida, Hidekazu; Metcalfe, R.*; Yamamoto, Koshi*; Amano, Yuki; Hoshii, Daisuke*; Kanekiyo, Akiko*; Naganuma, Takeshi*; Hayashi, Toru*

Applied Geochemistry, 23(8), p.2364 - 2381, 2008/08

 Times Cited Count:9 Percentile:26.2(Geochemistry & Geophysics)

Subsurface redox fronts control the mobilization and fixation of many trace elements. Any safety assessment for a deep geological repository for radioactive wastes needs to take into account adequately the long-term redox processes in the geosphere surrounding the repository. The water-rock-microbe interactions can be considered analogous to the processes occurring in the redox fronts that would develop around geological repositories for radioactive waste. Once formed, the Fe-ooxyhydroxides within such a front would be preserved even after reducing conditions resume following repository closure.

Journal Articles

Research and development on environmental radionuclides for nuclear non-proliferation at Japan Atomic Energy Agency

Usuda, Shigekazu; Shinohara, Nobuo; Sakurai, Satoshi; Magara, Masaaki; Miyamoto, Yutaka; Esaka, Fumitaka; Yasuda, Kenichiro; Kokubu, Yoko; Hirayama, Fumio; Lee, C. G.; et al.

KEK Proceedings 2007-16, p.13 - 22, 2008/02

For the purpose of controlling and monitoring radiations and radioactive materials emitted from nuclear facilities to the environment and also evaluating their effects, various R&D on environmental radioactivity has been carried out at Japan Atomic Energy Agency (JAEA). Especially, for the abolition of nuclear weapons and for peaceful uses nuclear energy, ultra-trace analysis of environmental samples for safeguards and ultra-high sensitive monitoring of radionuclides for the CTBT verification, which have been scheduled in the middle of 1990s, have been promotted under the auspices of the Japanese Government at JAERI, the former of JAEA. In this presentation, the outline of R&D on environmental radioactivity for nuclear non-proliferation is introduced. In addition, applications of the developed techniques and future perspectives will be discussed.

Journal Articles

Site determination of the binary metal adsorbates on a single crystalline surface by means of the transmission channeling technique

Morita, Kenji*; Ishikawa, Dai*; Yuhara, Junji*; Nakamura, Daisuke*; Soda, Kazuo*; Yamamoto, Shunya; Narumi, Kazumasa; Naramoto, Hiroshi; Saito, Kazuo*

JAERI-Review 99-025, TIARA Annual Report 1998, p.179 - 181, 1999/10

no abstracts in English

Oral presentation

Characteristics of carbon ion beam induced UVB hyper-resistant mutant of rice

Takano, Nao*; Takahashi, Yuko*; Yamamoto, Mitsuru*; Teranishi, Mika*; Yokozawa, Daisuke*; Hase, Yoshihiro; Sakamoto, Ayako; Tanaka, Atsushi; Hidema, Jun*

no journal, , 

no abstracts in English

Oral presentation

Study on distribution and migration of radioactive substances around the Fukushima Daiichi Nuclear Power Plant, 2; Distribution and temporal changes of air dose rate and radiocesium inventory in ground measured in flat terrain

Mikami, Satoshi; Ishikawa, Daisuke; Nakano, Masakazu; Matsuda, Norihiro; Uno, Kiichiro; Sato, Akane; Matsumoto, Shinichiro; Yamamoto, Hideaki; Saito, Kimiaki

no journal, , 

Distributions of air dose rate and inventory of radioactive cesium deposited on ground were investigated in 2013, within 80-km radial area centered around the Fukushima Daiichi Nuclear Power Plant. We revealed the characteristics of the time-dependent change of the air dose rate and the inventory by comparison with the measurement results of the past investigations.

Oral presentation

Development of the hydrogen detection technique using tungsten trioxide crystal in narrow portion

Kitsunai, Daisuke; Furuyama, Takehiro*; Nishimura, Akihiko; Yamamoto, Shunya

no journal, , 

no abstracts in English

Oral presentation

Diffusion behavior of iodide and cesium ions in hardened cement paste

Kawato, Takaya*; Ishida, Keisuke*; Yamamoto, Takeshi*; Minato, Daisuke*; Fujisaki, Kiyoshi*; Hamamoto, Takafumi*; Mihara, Morihiro

no journal, , 

no abstracts in English

19 (Records 1-19 displayed on this page)
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