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JAEA Reports

Spatial distribution of desaturation around the tunnel predicted by three-dimensional two-phase flow modeling of the degassing process of dissolved gases in groundwater

Miyakawa, Kazuya; Yamamoto, Hajime*

JAEA-Research 2022-003, 40 Pages, 2022/05

JAEA-Research-2022-003.pdf:6.08MB

The excavation of large-scale underground facilities, such as geological disposal of high-level radioactive waste, creates an excavation damaged zone (EDZ) with cracks around the tunnel. In the EDZ, oxygen invades the bedrock through unsaturated cracks and affects environmental conditions for nuclide migration. When a tunnel is excavated in a geological formation containing a high concentration of dissolved CH$$_{4}$$, such as the Neogene marine sediments, degassed CH$$_{4}$$ prevents oxygen intrusion. However, it may be promoted through gas-phase diffusion through desaturation. The purpose of this study is to illustrate the method of estimating the spatial distribution of desaturation associated with the construction and operation of underground facilities in a stratum that contains a large amount of dissolved CH$$_{4}$$. A sequential excavation analysis that reflected the actual process of 10-year excavation of the Horonobe Underground Research Laboratory (URL) was carried out along with gas-water two-phase flow analysis. The analysis results of the amount of groundwater and gas discharged from the URL were about 100 to 300 m$$^{3}$$ d$$^{-1}$$ and 250 to 350 m$$^{3}$$ d$$^{-1}$$, respectively, as of January 2017. These results showed values close to the observations (100 m$$^{3}$$ d$$^{-1}$$ and 300 m$$^{3}$$ d$$^{-1}$$, respectively). The analysis results of the saturation distribution were relatively high around the 250 m gallery and relatively low around the 350 m gallery, confirming that they are consistent with the in-situ observations. Although there were still technical issues of analysis regarding the conditions for groundwater drainage from the tunnel wall and the method of handling grout effects, the numerical calculation was generally appropriate. Although the results of the saturation distribution associated with the excavation were insufficient as the quantitative evaluation, they were almost correct from a qualitative point of view.

JAEA Reports

A Numerical simulation study of the desaturation and oxygen infusion into the sedimentary rock around the tunnel in the Horonobe Underground Research Laboratory

Miyakawa, Kazuya; Aoyagi, Kazuhei; Akaki, Toshifumi*; Yamamoto, Hajime*

JAEA-Data/Code 2021-002, 26 Pages, 2021/05

JAEA-Data-Code-2021-002.pdf:2.14MB
JAEA-Data-Code-2021-002-appendix(CD-ROM).zip:40.99MB

Investigations employing numerical simulation have been conducted to study the mechanisms of desaturation and oxygen infusion into sedimentary formations. By mimicking the conditions of the Horonobe underground research laboratory, numerical simulations aided geoscientific investigation of the effects of dissolved gas content and rock permeability on the desaturation (Miyakawa et al., 2019) and mechanisms of oxygen intrusion into the host rock (Miyakawa et al., 2021). These simulations calculated multi-phase flow, including flows of groundwater and exsolved gas, and conducted sensitivity analysis changing the dissolved gas content, rock permeability, and humidity at the gallery wall. Only the most important results from these simulations have been reported previously, because of publishers' space limitations. Hence, in order to provide basic data for understanding the mechanisms of desaturation and oxygen infusion into rock, all data for 27 output parameters (e.g., advective fluxes of heat, gas, and water, diffusive fluxes of water, CH$$_{4}$$, CO$$_{2}$$, O$$_{2}$$, and N$$_{2}$$, saturation degree, water pressure, and mass fraction of each component) over a modeling period of 100 years are presented here.

Journal Articles

Numerical simulation of oxygen infusion into desaturation resulting from artificial openings in sedimentary formations

Miyakawa, Kazuya; Aoyagi, Kazuhei; Akaki, Toshifumi*; Yamamoto, Hajime*

Dai-15-Kai Iwa No Rikigaku Kokunai Shimpojiumu Koen Rombunshu (Internet), p.609 - 614, 2021/01

Desaturation is expected due to excavation of an underground repository, especially in the newly created fractures zone (EDZ). During the construction and operation of facilities, the air in the gallery infuses into the rock around the gallery though the excavation affected area and causes oxidation of host rock and groundwater, which increase nuclide mobilities. In the Horonobe underground research laboratory (HURL), which is excavated in the Neogene sedimentary formations, no pyrite dissolution or precipitation of calcium sulfates was found from the cores drilled in the rock around the gallery. The reason for no oxidation is estimated that the release of dissolved gases from groundwater due to pressure decrease flows against the air infusion. In this research, the mechanism of O$$_{2}$$ intrusion into the rock was investigated by numerical multiphase flow simulation considering advection and diffusion of groundwater and gases. In the simulation, only Darcy's and Henry's laws were considered, that is, chemical reaction related to oxidation was not handled. The effects of dissolved gas and rock permeability on O$$_{2}$$ infusion into the rock were almost identical. Decreasing humidity with relatively low permeability leads to extensive accumulation of O$$_{2}$$ into the EDZ even though with a relatively large amount of dissolved gas. In the HURL, the shotcrete attenuates O$$_{2}$$ concentration and keeps 100% humidity at the boundary of the gallery wall, which inhibits O$$_{2}$$ infusion. Without the shotcrete, humidity at the gallery wall decreases according to seasonal changes and ventilation, which promotes O$$_{2}$$ intrusion into the EDZ but the chemical reaction related to O$$_{2}$$ buffering such as pyrite oxidation consumes O$$_{2}$$.

Journal Articles

The Effect of dissolved gas on rock desaturation in artificial openings in geological formations

Miyakawa, Kazuya; Aoyagi, Kazuhei; Sasamoto, Hiroshi; Akaki, Toshifumi*; Yamamoto, Hajime*

Proceedings of 5th ISRM Young Scholars' Symposium on Rock Mechanics and International Symposium on Rock Engineering for Innovative Future (YSRM 2019 and REIF 2019) (USB Flash Drive), 6 Pages, 2019/12

The construction and operation of geological repositories require excavation and ventilation of galleries, with significant groundwater drainage. Desaturation of rock around galleries is unavoidable and may affect hydraulic properties and redox conditions. This study used numerical modeling to assess the influence of dissolved gas on the degree of saturation of rock surrounding excavated galleries, focusing on siliceous mudstone rock in the 140 m, 250 m, and 350-m-deep galleries of the Horonobe Underground Research Laboratory, Japan. Based on previous ${it in situ}$ electrical survey, the degree of saturation in the 250 m gallery was higher than that in the 140 m and 350 m galleries. In the Horonobe area, deep groundwater contains high concentrations of dissolved methane, and exsolution of this methane from pore water can affect desaturation. Simple numerical modeling, including simulation of multiphase flows, was undertaken for each gallery to confirm the effect of dissolved gas and rock permeability on desaturation. A sensitivity analysis was performed by varying dissolved gas contents and permeability. Results indicate that the dissolved gas content affects both the degree of saturation and its spatial extent, whereas rock permeability affects only the latter. Higher dissolved gas concentrations result in lower degrees of saturation with a greater spatial extent of desaturation, and higher permeability leads to greater extents of desaturation. It is therefore likely that gas content, rather than rock permeability, caused the observed variations in the saturation degree.

Journal Articles

New precise measurements of muonium hyperfine structure at J-PARC MUSE

Strasser, P.*; Abe, Mitsushi*; Aoki, Masaharu*; Choi, S.*; Fukao, Yoshinori*; Higashi, Yoshitaka*; Higuchi, Takashi*; Iinuma, Hiromi*; Ikedo, Yutaka*; Ishida, Katsuhiko*; et al.

EPJ Web of Conferences, 198, p.00003_1 - 00003_8, 2019/01

 Times Cited Count:13 Percentile:99.06(Quantum Science & Technology)

Journal Articles

New precise measurement of muonium hyperfine structure interval at J-PARC

Ueno, Yasuhiro*; Aoki, Masaharu*; Fukao, Yoshinori*; Higashi, Yoshitaka*; Higuchi, Takashi*; Iinuma, Hiromi*; Ikedo, Yutaka*; Ishida, Katsuhiko*; Ito, Takashi; Iwasaki, Masahiko*; et al.

Hyperfine Interactions, 238(1), p.14_1 - 14_6, 2017/11

 Times Cited Count:3 Percentile:86.59(Physics, Atomic, Molecular & Chemical)

Journal Articles

New muonium HFS measurements at J-PARC/MUSE

Strasser, P.*; Aoki, Masaharu*; Fukao, Yoshinori*; Higashi, Yoshitaka*; Higuchi, Takashi*; Iinuma, Hiromi*; Ikedo, Yutaka*; Ishida, Katsuhiko*; Ito, Takashi; Iwasaki, Masahiko*; et al.

Hyperfine Interactions, 237(1), p.124_1 - 124_9, 2016/12

 Times Cited Count:7 Percentile:90.97(Physics, Atomic, Molecular & Chemical)

JAEA Reports

Groundwater/porewater hydrochemistry at Horonobe URL; Data freeze II; Preliminary data quality evaluation for boreholes HDB-1 to 8

Kunimaru, Takanori; Ota, Kunio; Alexander, W. R.*; Yamamoto, Hajime*

JAEA-Research 2011-010, 52 Pages, 2011/06

JAEA-Research-2011-010.pdf:2.29MB

Work has been currently ongoing to establish an appropriate quality management system (QMS), which is applicable to all aspects of the site characterisation process, in the Horonobe Underground Research Laboratory project. A quality assurance (QA) audit of hydrochemical datasets for JAEA's deep boreholes HDB-1 to HDB-8 was carried out, along similar lines to that of the previous study for boreholes HDB-9 to HDB-11, by applying both the groundwater QA methodology employed in the recent site assessments in Sweden and a porewater QA regime proposed in this study. The results of the QA audit indicated that data were classified into low QA categories because mainly of a lack of relevant information, such as the records of groundwater sampling, which are necessary for more fully assessing the data quality. As such, a formalised field manual for hydrochemical sampling was developed. In addition, work to further improve the site characterisation QMS progressed.

JAEA Reports

Groundwater/porewater hydrochemistry at Horonobe URL: Data Freeze I; Preliminary data quality evaluation for boreholes HDB-9, 10 and 11

Kunimaru, Takanori; Ota, Kunio; Alexander, W. R.*; Yamamoto, Hajime*

JAEA-Research 2010-035, 109 Pages, 2010/11

JAEA-Research-2010-035.pdf:2.53MB

A quality management system (QMS) will save on effort by reducing errors and the requirement to re-sample and re-analysis and eventually lead to ensuring the reliability of the investigation results. In the Horonobe Underground Research Laboratory project, work has been ongoing to develop an appropriate QMS which is applicable to surface-based investigations. A quality assurance (QA) audit of hydrochemical datasets for boreholes HDB-9 - 11 has been carried out by applying both the groundwater QA methodology employed in the recent site assessments in Sweden and the porewater QA regime newly proposed for assigning the QA categories. This QA audit exercise indicates that the HDB-9 - 11 hydrochemical data are classified into lower categories because mainly of contamination of waters by drilling fluids, poor time-series data coverage and oxidation of core materials and also clarifies areas where additional information/work would be required to the ongoing programme.

Journal Articles

EUV spectra from highly charged tin ions observed in low density plasma in LHD

Suzuki, Chihiro*; Kato, Takako*; Sato, Kuninori*; Tamura, Naoki*; Kato, Daiji*; Sudo, Shigeru*; Yamamoto, Norimasa*; Tanuma, Hajime*; Ohashi, Hayato*; Suda, Shintaro*; et al.

Journal of Physics; Conference Series, 163, p.012019_1 - 012019_4, 2009/06

 Times Cited Count:11 Percentile:94.18(Physics, Multidisciplinary)

We have measured EUV spectra from highly charged tin ions in low density plasmas produced in the Large Helical Device (LHD). The well known dense spectral structure around 13.5 nm is measured when the plasma is rapidly cooled and approaching radioactive collapse, while the sparse spectrum with several unidentified discrete lines from 13.8-14.6 nm is observed if the plasma is cooled more slowly. The dominant charge states in the former case are Sn$$^{11+}$$ -Sn$$^{14+}$$. The latter case may be explained by considering the spectral lines from charge states higher than Sn$$^{19+}$$.

JAEA Reports

Analysis of ground water from boreholes, river water and precipitation in the Underground Research Laboratory Project

Kunimaru, Takanori; Shibano, Kazunori; Kurikami, Hiroshi; Tomura, Goji; Hara, Minoru; Yamamoto, Hajime*

JAEA-Data/Code 2007-015, 113 Pages, 2007/11

JAEA-Data-Code-2007-015.pdf:6.62MB

In the Horonobe Underground Research Laboratory (URL) Project, ground water from boreholes, river water and precipitation have been preiodically analyzed for the environmental monitoring since the fiscal year 2001. This report shows the data set of water chemistry since the fiscal year 2001 to the fiscal year 2006.

Journal Articles

Long-term simulation of ambient groundwater chemistry at Horonobe underground research laboratory, Japan; Application of coupled hydro-geochemical model

Yamamoto, Hajime*; Kunimaru, Takanori; Kurikami, Hiroshi; Shimo, Michito*; Xu, T.*

Proceedings of 2nd International Conference on Coupled T-H-M-C Processes in Geo-systems; Fundamentals, Modeling, Experiments and Applications (GeoProc 2006), p.382 - 387, 2006/05

no abstracts in English

JAEA Reports

Modeling study on geological environment at Horonobe URL site

Shimo, Michito*; Yamamoto, Hajime*; Kumamoto, So*; Fujiwara, Yasushi*; Ono, Makoto*

JNC TJ5400 2004-004, 120 Pages, 2005/02

JNC-TJ5400-2004-004.pdf:78.08MB
JNC-TJ5400-2004-004(errata).pdf:0.08MB

The Horonobe underground research project has been carried out by Japan Nuclear Cycle Development Institute to study the geological environment of sedimentary rocks in deep underground. The objectives of this study are to develop a geological environment model, which incorporate current findings and latest data obtained through the geological, geophysical, and borehole investigations at Horonobe site, and to predict the hydrological and geochemical impacts caused by the URL shaft excavation to the surrounding area.

JAEA Reports

Study on the prediction accuracy of nuclide generation and depletion with JENDL

Okumura, Keisuke; Oki, Shigeo*; Yamamoto, Munenari*; Matsumoto, Hideki*; Ando, Yoshihira*; Tsujimoto, Kazufumi; Sasahara, Akihiro*; Katakura, Junichi; Matsumura, Tetsuo*; Aoyama, Takafumi*; et al.

JAERI-Research 2004-025, 154 Pages, 2005/01

JAERI-Research-2004-025.pdf:19.46MB

This report summarizes the activity (FY2000-2003) of Working Group (WG) on Evaluation of Nuclide Generation and Depletion under Subcommittee on Nuclear Fuel Cycle of Japanese Nuclear Data Committee. In the WG, analyses of Post Irradiation Examinations have been carried out for UO$$_{2}$$ and MOX fuels irradiated in PWRs, BWRs and FBRs, and for actinide samples irradiated in fast reactors, by using ORIGEN or more detailed calculation codes with their libraries based on JENDL-3.2, JENDL-3.3 and other foreign nuclear data files. From these results, current prediction accuracy and problems for evaluation of nuclide generation and depletion are discussed. Furthermore, this report covers other products of our activity; development of the ORIGEN libraries for PWR, BWR and FBR based on JENDL-3.3, study on introduction of neutron spectrum index to ORIGEN calculations, and results of questionnaire survey on desirable accuracy of ORIGEN calculations.

JAEA Reports

Research and development on reduced-moderation light water reactor with passive safety features (Contract research)

Iwamura, Takamichi; Okubo, Tsutomu; Akie, Hiroshi; Kugo, Teruhiko; Yonomoto, Taisuke; Kureta, Masatoshi; Ishikawa, Nobuyuki; Nagaya, Yasunobu; Araya, Fumimasa; Okajima, Shigeaki; et al.

JAERI-Research 2004-008, 383 Pages, 2004/06

JAERI-Research-2004-008.pdf:21.49MB

The present report contains the achievement of "Research and Development on Reduced-Moderation Light Water Reactor with Passive Safety Features", which was performed by Japan Atomic Energy Research Institute (JAERI), Hitachi Ltd., Japan Atomic Power Company and Tokyo Institute of Technology in FY2000-2002 as the innovative and viable nuclear energy technology (IVNET) development project operated by the Institute of Applied Energy (IAE). In the present project, the reduced-moderation water reactor (RMWR) has been developed to ensure sustainable energy supply and to solve the recent problems of nuclear power and nuclear fuel cycle, such as economical competitiveness, effective use of plutonium and reduction of spent fuel storage. The RMWR can attain the favorable characteristics such as high burnup, long operation cycle, multiple recycling of plutonium (Pu) and effective utilization of uranium resources based on accumulated LWR technologies.

JAEA Reports

Hydrogeological Modeling and Groundwater Flow Analysis of the Underground Research Laboratory Site Using the Various Conceptual Model (Phase 2)

Ijiri, Yuji*; Ono, Makoto*; Sugihara, Yutaka*; Shimo, Michito*; Yamamoto, Hajime*; Fumimura, Kenichi*

JNC TJ7400 2004-015, 732 Pages, 2003/10

JNC-TJ7400-2004-015.pdf:34.55MB

In order to establish the most effective procedures for groundwater flow characterization in order to reduce the uncertainty this study, the identidication of essential uncertainty factors for the groundwater flow characterization has been attempted using various conceptual model. In this study, an integrated data flow on the groundwater flow simuration was developed for previously applied various conceptural models. The data flow consists of five steps in order: (1) field investigation, (2) raw / conditioned data, (3) interpretation / data set, (4) conceptualization / modeling / simulation, and (5) results / applications. These are uncertainties in each work and assumption in every step, and the uncertainties have an influence on the modeling methods and simulation resuls. Following the data flow, the uncertain factors affecting the groundwater flow simulation were extracted based on the simulation resuls. Investigation data, methods of investigation and modeling, and analysis technique were examined to solve the problems due to the uncertainties. Acquired information is summarized in the following. As for each work process in the data flow, the uncertainty factors that are considered to affect the results of simulations are extracted by two kinds of comparison methods as follows: (1) comparison of data flow among analysis cases for each conceptual model, and (2) comparison of data flow among conceptual models for each case. The uncertainty factors include hydrogeological mechanism of fault and effective porosity, and the likes. The development of each data flow for four modeling methods was additionally used to clarify the data interpretation technique, the modeling procedure, and the uncertainty factor in each data flow along with the data flow from investigation through evaluation. Extensive through information without bias is, therefore, reflected in groundwater flow analysis by defining the data flow. Establishment of data flow...

JAEA Reports

Evaluation of Uncertainties in Hydrogeological Modeling and Groundwater Flow Analyses -Model Calibration-

Ijiri, Yuji*; Ono, Makoto*; Sugihara, Yutaka*; Shimo, Michito*; Yamamoto, Hajime*; Fumimura, Kenichi*

JNC TJ7400 2004-005, 415 Pages, 2003/03

JNC-TJ7400-2004-005.pdf:23.86MB

For the purpose of evaluating how uncertainties included in modeling of hydrogeological structure and results of groundwater simulation decreased with progress of investigation research, updating and calibration of the models about several modeling techniques of hydrogeological structure and groundwater flow analysis techniques were carried out, based on the information and knowledge which were newly acquired. The acquired knowledge is as follows.The model calibration is performed by the method of matching numericals simulation with observation, about the pressure response caused by opening and closing of a packer in MIU-2 borehole. Each analysis technique attains reducing of residual sum of squares of observations and results of numerical simulation by adjusting hydrogeological parameters. However, each model adjusts different parameters as water conductivity, effective porosity, specific storage, and anisotropy. When calibrating models, sometimes it is impossible to explain the phenomena only by adjusting parameters. In such case, another investigation may be required to clarify details of hydrogeological structure more.Since it is a little more flexible about boundary condition and faults except Tsukiyoshi fault than last year, travel paths themselves vary a little rather than last year. However, as a result, when travel paths are almost the same, model calibration can reduce the variation of travel length and Darcy velocity among models within about one order. It will be necessary to propose investigation aiming at reducing the uncertainty of data, such as water conductivity and effective porosity and at making hydrogeological structure more detailed from a viewpoint of modeling.

JAEA Reports

Hydrogeological Modeling and Groundwater Flow Analyses of the Underground Research Laboratory Site Using the Various Conceptual Model

Ijiri, Yuji*; Ono, Makoto*; Sugihara, Yutaka*; Shimo, Michito*; Yamamoto, Hajime*; Fumimura, Kenichi*

JNC TJ7400 2004-003, 610 Pages, 2003/03

JNC-TJ7400-2004-003.pdf:42.03MB

This study involves evaluation of uncertainty in hydrogeological modeling and groundwater flow analysis. Three-dimensional groundwater flow analisys in underground research laboratory site in Tono was carried out using three continuum models and one discontinuum model in the domain of 9km$$times$$9km area. The acquired knowledge is as follows.The effect of variety of modeling method was evaluated under the condition that same analysis domain and same shape of Tsukiyoshi fault were assingned. The results indicated that the variation of travel pathway and travel length resulted from heterogeneity is sometimes larger than from the difference of models, depending on a place. Besides, since the difference between the models in travel time was larger than a travel pathway and travel length, it turns out that the uncertainty of effective porosity used for alculation of the actual flow velocity is large.Moreover, the existing data flow was reconstituted through a series of modeling and analysis of this work. The results indicated that it is necessary to continue reflecting the results of investigation and evaluation in data flow, since data flow varied with modeling concepts.

JAEA Reports

Study on Flow and Mass Transport through Fractured Soft Sedimentary Rocks

Shimo, Michito*; Yamamoto, Hajime*; Kumamoto, So*

JNC TJ8400 2003-036, 46 Pages, 2003/02

JNC-TJ8400-2003-036.pdf:0.99MB

The objective of this study is to establish a conceptual model for flow and transport in fractured soft sedimentary rock. In this fiscal year, this study was carried out for two tasks: (1) classification of soft sedimentary rocks by literature survey, (2) laboratory experiments on the flow and mass transport using rock specimens obtained at HDB-4 borehole in Horonobe Deep Underground Research Center.Classification of soft sedimentary rocks is carried out using two databases of rock properties collected by JNC and Geological Survey of Japan. In laboratory experiments, core samples of the Tertiary siliceous mud rock obtained from the HDB-4 borehole, which was excavated in the Horonobe area in this year, were studied. The matrix porosity of intact cores measured by wet and dry weight was ranging from 33% to 41%. he hydraulic conductivities of rock matrix determined by the transient pulse test were in an order of 10-11 m/s. The effective diffusion coefficients obtained from the "through diffusion test" were 0.8 to 2.5$$times$$10-11 m2/s. This suggested that, in these cores, the flow in the rock matrix is not significant comparing with the flow in fractures, and the matrix diffusion from fractures into rock matrix should cause a significant effect to the mass transport phenomenon. Non-sorbing tracer experiment was conducted in fractured cores. As a tracer, potassium iodide solution was injected at a constant rate and the tracer concentration change during injection was observed at the outlet. The obtained breakthrough curve was interpreted and fitted by using a numerical simulator for flow and mass transport called FRAC3DVS (Therrien et al., 1999), and finally, mass transport parameters are obtained. The result indicates that the matrix diffusion plays an important role for mass transport in the fractured soft sedimentary rocks.

JAEA Reports

Study on Flow and Mass Transport through Fractured Soft Sedimentary Rocks

Shimo, Michito*; Yamamoto, Hajime*; Kumamoto, So*

JNC TJ8400 2003-028, 135 Pages, 2003/02

JNC-TJ8400-2003-028.pdf:3.79MB

The objective of this study is to establish a conceptual model for flow and transport in fractured soft sedimentary rock.In this fiscal year, this study was carried out for two tasks: (1) classification of soft sedimentary rocks by literature survey, (2) laboratory experiments on the flow and mass transport using rock specimens obtained at HDB-4 borehole in Horonobe Deep Underground Research Center. Classification of soft sedimentary rocks is carried out using two databases of rock properties collected by JNC and Geological Survey of Japan. In laboratory experiments, core samples of the Tertiary siliceous mud rock obtained from the HDB-4 borehole, which was excavated in the Horonobe area in this year, were studied. The matrix porosity of intact cores measured by wet and dry weight was ranging from 33% to 41%. The hydraulic conductivities of rock matrix determined by the transient pulse test were in an order of 10-11 m/s. The effective diffusion coefficients obtained from the through diffusion test were 0.8 to 2.5x10-11 m2/s. This suggested that, in these cores, the flow in the rock matrix is not significant comparing with the flow in fractures, and the matrix diffusion from fractures into rock matrix should cause a significant effect to the mass transport phenomenon. Non-sorbing tracer experiment was conducted in fractured cores. As a tracer, potassium iodide solution was injected at a constant rate and the tracer concentration change during injection was observed at the outlet. The obtained breakthrough curve was interpreted and fitted by using a numerical simulator for flow and mass transport called FRAC3DVS (Therrien et al., 1999), and finally, mass transport parameters are obtained. The result indicates that the matrix diffusion plays an important role for mass transport in the fractured soft sedimentary rocks.

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