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dynamics in the H conductors LaH
O
Tamatsukuri, Hiromu; Fukui, Keiga*; Iimura, Soshi*; Honda, Takashi*; Tada, Tomofumi*; Murakami, Yoichi*; Yamaura, Junichi*; Kuramoto, Yoshio*; Sagayama, Hajime*; Yamada, Takeshi*; et al.
Physical Review B, 107(18), p.184114_1 - 184114_8, 2023/05
Times Cited Count：0 Percentile：0(Materials Science, Multidisciplinary)
@C
; Photoelectron spectroscopy of the Li@C[PF
] salt and STM of the single Li@C molecules on Cu(111)Yamada, Yoichi*; Kuklin, A. V.*; Sato, Sho*; Esaka, Fumitaka; Sumi, Naoya*; Zhang, C.*; Sasaki, Masahiro*; Kwon, E.*; Kasama, Yasuhiko*; Avramov, P. V.*; et al.
Carbon, 133, p.23 - 30, 2018/07
Times Cited Count：17 Percentile：55.14(Chemistry, Physical)We report first STM observation of the Li ion endohedral C, which is of a new class of endohedral fullerenes, prepared by means of evaporation of high-purity Li@C[PF] salt in ultra-high vacuum. Prior to the STM measurements, the electronic structure of Li@C in the Li@C[PF] salt was also precisely determined. In the salt, it is shown that Li and PF have nearly single positive and negative charge, respectively, and the C cage is nearly neutral, suggesting that Li@C in the salt retains its original electronic state.
Hasegawa, Yuri; Yamada, Yoichi*; Sasaki, Masahiro*
Vacuum and Surface Science, 61(6), p.366 - 371, 2018/06
Molecular arrangements and electronic states of well-ordered (DNTT) and picene thin film on single crystal were measured by means of scanning tunneling microscope (STM) and angle-resolved photoemission spectroscopy, respectively. DNTT and picene form single crystalline-like molecular arrangement on inert Au(111) substrate. Splitting of HOMO energy due to overlapping with adjacent molecules was suggested by ultraviolet photoemission spectroscopy (UPS) and density functional theory (DFT) calculation. On the other hand, one-dimensional ordering of those molecule was observed on anisotropic Ag(110) substrate. However, the HOMO band dispersion was found to be 200 meV at maximum, showing that the overlapping of HOMO was smaller in such arrangement comparing with that in their single crystal.
1 surface; In situ synchrotron radiation photoemission studyYoshigoe, Akitaka; Yamada, Yoichi*; Taga, Ryo*; Ogawa, Shuichi*; Takakuwa, Yuji*
Japanese Journal of Applied Physics, 55(10), p.100307_1 - 100307_4, 2016/09
Times Cited Count：5 Percentile：24.79(Physics, Applied)Synchrotron radiation photoelectron spectroscopy during the oxidation of the Si(100)21 surface at room temperature revealed the existence of the molecularly adsorbed oxygen, which was considered to be absent. The O 1s spectra was found to be similar to that of the oxidation of Si(111)77 surfaces. Also the molecular oxygen was appeared after the initial surface oxides, indicating that this was not a precursor for dissociation oxygen adsorption onto the clean surface. We have proposed presumable structural models for atomic configurations, where the molecular oxygen was resided on the oxidized silicon with two oxygen atoms at the backbonds.
Sanada, Yukihisa; Mori, Airi; Ishizaki, Azusa; Munakata, Masahiro; Nakayama, Shinichi; Nishizawa, Yukiyasu; Urabe, Yoshimi; Nakanishi, Chika; Yamada, Tsutomu; Ishida, Mutsushi; et al.
JAEA-Research 2015-006, 81 Pages, 2015/07
JAEA-Research-2015-006.pdf:22.96MB
By the nuclear disaster of Fukushima Daiichi Nuclear Power Station (NPS), Tokyo Electric Power Company (TEPCO), caused by the East Japan earthquake and the following tsunami occurred on March 11, 2011, a large amount of radioactive materials was released from the NPP. These results of the aerial radiation monitoring using the manned helicopter in the fiscal 2014 were summarized in the report.
8) induced by supersonic O
beamsOkada, Ryuta; Yoshigoe, Akitaka; Teraoka, Yuden; Yamada, Yoichi*; Sasaki, Masahiro*
Applied Physics Express, 8(2), p.025701_1 - 025701_4, 2015/02
Times Cited Count：7 Percentile：30.95(Physics, Applied)We studied the surface oxidation on a Ge(111)-c(28) surface at room temperature using supersonic oxygen beams as a function of the translational energy of the incident oxygen molecules ranging from 26 meV to 2.3 eV. In situ synchrotron photoemission spectroscopy performed during the oxidation revealed that the surface oxidation terminated with the formation of a sub-monolayer oxide of at most 0.52 ML, for all the beam energies examined. In addition, the oxidation state of the surface oxides was found to depend on the translational energy. These results demonstrate the precise chemical control of the ultrathin surface oxides of Ge(111)-c(28).
synchrotron radiation photoelectron spectroscopy study of the oxidation of the Ge(100)-21 surface by supersonic molecular oxygen beamsYoshigoe, Akitaka; Teraoka, Yuden; Okada, Ryuta; Yamada, Yoichi*; Sasaki, Masahiro*
Journal of Chemical Physics, 141(17), p.174708_1 - 174708_7, 2014/11
Times Cited Count：8 Percentile：29.76(Chemistry, Physical)
synchrotron radiation photoelectron spectroscopy was performed during the oxidation of the Ge(100)-21 surface induced by a molecular oxygen beam with various incident energies up to 2.2 eV from the initial to saturation coverage of surface oxides. The saturation coverage of oxygen on the clean Ge(100) surface was much lower than one monolayer and the oxidation state of Ge was +2 at most. This indicates that the Ge(100) surface is in strong contrast to Si surfaces. The direct adsorption process can be activated by increasing the translational energy, resulting in an increased population of Ge
and a higher final oxygen coverage. Our findings will contribute to the fundamental understanding of oxygen adsorption processes at 300 K from the initial stages to saturated oxidation.
Sanada, Yukihisa; Nishizawa, Yukiyasu; Urabe, Yoshimi; Yamada, Tsutomu; Ishida, Mutsushi; Sato, Yoshiharu; Hirayama, Hirokatsu; Takamura, Yoshihide; Nishihara, Katsuya; Imura, Mitsuo; et al.
JAEA-Research 2014-012, 110 Pages, 2014/08
JAEA-Research-2014-012.pdf:169.17MBJAEA-Research-2014-012(errata).pdf:0.27MB
By the nuclear disaster of Fukushima Daiichi Nuclear Power Station (NPS), Tokyo Electric Power Company (TEPCO), caused by the East Japan earthquake and the following tsunami occurred on March 11, 2011, a large amount of radioactive materials was released from the NPP. This document was summarized in the results of the aerial radiation monitoring using the manned helicopter in the fiscal 2013.
)
(SrMnO) superlattice revealed by resonant soft X-ray scatteringKubota, Masato; Yamada, Hiroyuki*; Nakao, Hironori*; Okamoto, Jun*; Yamasaki, Yuichi*; Sawa, Akihito*; Murakami, Yoichi*
Japanese Journal of Applied Physics, 53(5S1), p.05FH07_1 - 05FH07_5, 2014/05
Times Cited Count：2 Percentile：8.84(Physics, Applied) high-spin state with a large orbital angular momentum in La
Ca
CoO
Okamoto, Jun*; Nakao, Hironori*; Yamasaki, Yuichi*; Wadachi, Hiroki*; Tanaka, Arata*; Kubota, Masato; Horigane, Kazumasa*; Murakami, Yoichi*; Yamada, Kazuyoshi*
Journal of the Physical Society of Japan, 83(4), p.044705_1 - 044705_6, 2014/04
Times Cited Count：9 Percentile：55.36(Physics, Multidisciplinary) molecules to step edges of the Si(110)-162 single domain surfaceYokoyama, Yuta; Yamada, Yoichi*; Asaoka, Hidehito; Sasaki, Masahiro*
Journal of Physics; Conference Series, 417, p.012036_1 - 012036_6, 2013/03
Times Cited Count：1 Percentile：38.58(Materials Science, Coatings & Films)The Si(110)-162 reconstructed structure can be a superior template for 1-D nanostructures. However, the controlled nanostructure using this surface has not been fabricated yet. In this study, we have investigated the adsorption of C on the Si(110)-162 surface at various surface temperatures, and found that the C preferable adsorption site is remarkably changed, depending on the surface temperature. The obtained results indicate the possibility that the organic 1-D nanostructure can be fabricated on the Si(110)-162 surface by controlling the surface temperature.
on one-dimensional template of single-domain Ge(110)-162 and Si(110)-162 surfacesYokoyama, Yuta; Sinsarp, A.*; Yamada, Yoichi*; Asaoka, Hidehito; Sasaki, Masahiro*
Applied Physics Express, 5(2), p.025203_1 - 025203_3, 2012/02
Times Cited Count：3 Percentile：13.53(Physics, Applied)We demonstrated the ordering of C in one dimension by using Ge(110)-162 and Si(110)-162 single-domain surfaces as an one-dimensional templates. On the Ge(110)-162 surface where surface diffusion of C was activated at room temperature such that it was aligned along the step edge, the formation of one-dimensional order of C molecules was achieved. In contrast, on the Si(110)-162 surface, the substantial reactivity of the surface limited the diffusion of adsorbed C, resulting in random adsorption at room temperature.
-FeSi
Yamada, Yoichi*; Mao, W.*; Asaoka, Hidehito; Yamamoto, Hiroyuki; Esaka, Fumitaka; Udono, Haruhiko*; Tsuru, Tomohito
Physics Procedia, 11, p.67 - 70, 2011/02
Times Cited Count：3 Percentile：82.2(Optics)Clean surfaces of the single crystalline -FeSi have been prepared and investigated. From XPS (X-ray Photoelectron Spectroscopy) measurements of the surface oxide, it is found that the surface Si is mainly oxidized while Fe isn't. After removing the surface oxide, clean surface can be obtained showing reasonable structure in LEED (Low-Energy Electron Diffraction) and STM (Scanning Tunneling Microscope). No drastic surface reconstruction is found reflecting strong Fe-Si bond. DFT (Density Functional Theory) calculation suggests the spin polarized surface DOS (Density Of State) when Fe comes at the surface.
Hatae, Takaki; Howard, J.*; Ebizuka, Noboru*; Yoshida, Hidetsugu*; Nakatsuka, Masahiro*; Fujita, Hisanori*; Narihara, Kazumichi*; Yamada, Ichihiro*; Funaba, Hisamichi*; Hirano, Yoichi*; et al.
Journal of Physics; Conference Series, 227, p.012002_1 - 012002_6, 2010/06
Times Cited Count：2 Percentile：66.93(Physics, Applied)-FeSi thin films fabricated by ion beam sputter depositionEsaka, Fumitaka; Yamamoto, Hiroyuki; Matsubayashi, Nobuyuki*; Yamada, Yoichi*; Sasase, Masato*; Yamaguchi, Kenji; Shamoto, Shinichi; Magara, Masaaki; Kimura, Takaumi
Applied Surface Science, 256(10), p.3155 - 3159, 2010/03
Times Cited Count：16 Percentile：56.9(Chemistry, Physical)A combination of X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS) using synchrotron radiation is applied to clarify surface chemical states of -FeSi films fabricated by an ion-beam sputtering deposition method. The differences in the chemical states of the films fabricated at substrate temperatures of 873, 973 and 1173 K are investigated.
adsorbed on Pt surfaceSuzuki, Chikashi; Yamada, Yoichi; Nakagiri, Toshio
Applied Surface Science, 256(3), p.862 - 869, 2009/11
Times Cited Count：8 Percentile：36.66(Chemistry, Physical)no abstracts in English
Oba, Hironori; Saeki, Morihisa; Esaka, Fumitaka; Yamada, Yoichi; Yamamoto, Hiroyuki; Yokoyama, Atsushi
Journal of the Vacuum Society of Japan, 52(6), p.369 - 371, 2009/07
no abstracts in English
Oba, Hironori; Suzuki, Hiroshi*; Esaka, Fumitaka; Taguchi, Tomitsugu; Yamada, Yoichi; Yamamoto, Hiroyuki; Sasase, Masato*; Yokoyama, Atsushi
Journal of the Vacuum Society of Japan, 52(6), p.292 - 295, 2009/07
no abstracts in English
cuprates studied by resonant inelastic X-ray scatteringIshii, Kenji; Hoesch, M.*; Inami, Toshiya; Kuzushita, Kaori*; Owada, Kenji; Tsubota, Masami; Murakami, Yoichi; Mizuki, Junichiro; Endo, Yasuo; Tsutsui, Kenji*; et al.
Journal of Physics and Chemistry of Solids, 69(12), p.3118 - 3124, 2008/12
Times Cited Count：3 Percentile：18.13(Chemistry, Multidisciplinary)-FeSiYamada, Yoichi; Wakaya, Ippei*; Ouchi, Shinji*; Yamamoto, Hiroyuki; Asaoka, Hidehito; Shamoto, Shinichi; Udono, Haruhiko*
Surface Science, 602(18), p.3006 - 3009, 2008/09
Times Cited Count：6 Percentile：30.34(Chemistry, Physical)Well-defined clean surfaces of single crystalline -FeSi have for the first time been prepared and characterized at the atomic scale. Surface oxide was removed by heating the crystal at 850 
C in ultra-high vacuum (UHV), resulted in an atomically-flat, clean surface. Scanning tunneling microscope (STM) and low-energy electron diffraction (LEED) measurements reveal the absence of long-range surface reconstruction in the low-index (100), (101) and (110) surfaces, which is unique among compound semiconductors. However a significant number of surface defects could still be found within the clean surface. Characterizing and controlling of those surface defects will be necessary in order to use this material in applications.
