Hydroxyl group/fluorine disorder in deuterated magnesium hydroxyfluoride and behaviors of hydrogen bonds under high pressure

He, X.*; Kagi, Hiroyuki*; Komatsu, Kazuki*; Iizuka, Riko*; Okajima, Hajime*; Hattori, Takanori; Sano, Asami; Machida, Shinichi*; Abe, Jun*; Goto, Hirotada*; et al.

Journal of Molecular Structure, 1310, p.138271_1 - 138271_8, 2024/08

https://doi.org/10.1016/j.molstruc.2024.138271

High-pressure responses of the O-DF hydrogen bonds in deuterated magnesium hydroxyfluoride were investigated using neutron powder diffraction and Raman spectroscopy. The Rietveld analysis at ambient conditions revealed a chemical formula of Mg(OD)F and hydroxyl group/fluorine disorder (OD/F disorder) in the crystal structure, which gave rise to two hydrogen-bonding configurations. The Rietveld analysis showed the hydrogen-bonding geometries remains up to 9.8 GPa, indicating no pressure-induced strengthening of hydrogen bonds. The Raman spectra at ambient conditions showed three hydroxyl stretching bands at 2613, 2694, and 2718 cm. The high frequencies of the O-D stretching modes indicated that the hydroxyls should be involved in weak or none hydrogen-bonding interactions. Up to 20.2 GPa, the mode initially centered at 2694 cm displayed a pressure-induced blue shift, revealing no strengthening of hydrogen bonds under compression. We discuss the existence of hydrogen bonds and the causes of the blue-shifting hydroxyls at ambient and at high pressures.

Study on waste acceptance criteria for waste packages destined for near surface disposal containing radioactive waste from research, industrial and medical facilities; Minimization of the amounts of scattering radionuclides caused by dropping impact

Nakata, Hisakazu; Okada, Shota; Amazawa, Hiroya; Sakai, Akihiro

JAEA-Technology 2023-021, 31 Pages, 2024/01

JAEA-Technology-2023-021.pdf:2.53MB

Radioactive waste packages, which Japan Atomic Energy Agency (JAEA) plans to dispose of, must meet the technical criteria specified by the Order of Nuclear Regulation Authority. One criteria is newly specified in 2019 such that it shall be impact resistant performance so as to be few in quantity of radionuclides released from the waste package in case of dropping from the maximum height assumed in the disposal process. Then, JAEA needs to prove the compliance of the waste package with the technical criteria by estimating the leakage of radionuclides. In this report, the amounts of scattering materials inside two waste packages caused by dropping impact from 8m height was estimated by numerical analysis, providing the ratio of the amounts of scattering materials to the weight of the waste package. The analysis objects were 1m cube container-filled and solidified waste package containing metal waste, which are expected to emplace into a vault-type disposal facility. Some considerations relating to the production method of the waste package using 1m cubic container and its waste acceptance criteria are provided on the basis of the drop analysis in this report.

Uranium-plutonium-americium cation interdiffusion in polycrystalline (U,Pu,Am)O mixed oxides

Vauchy, R.; Matsumoto, Taku; Hirooka, Shun; Uno, Hiroki*; Tamura, Tetsuya*; Arima, Tatsumi*; Inagaki, Yaohiro*; Idemitsu, Kazuya*; Nakamura, Hiroki; Machida, Masahiko; et al.

Journal of Nuclear Materials, 588, p.154786_1 - 154786_13, 2024/01

https://doi.org/10.1016/j.jnucmat.2023.154786

First report of geo- and thermochronological results from the Cordillera Central, Luzon, Philippines

Nakajima, Toru; Sueoka, Shigeru; Nagata, Mitsuhiro; Kohn, B. P.*; Ramos, N. T.*; Tsutsumi, Hiroyuki*; Tagami, Takahiro*

Earth, Planets and Space (Internet), 75(1), p.176_1 - 176_11, 2023/12

https://doi.org/10.1186/s40623-023-01927-z

Geo- and thermochronological methods were applied to dioritic rocks from the Cordillera Central, Luzon, Philippines, to understand their emplacement and exhumation history in the island arc mountains. Zircon U-Pb ages range from 32.54 0.70 to 6.11 0.15 (2SE) Ma, indicating that dioritic magmas intruded the middle and upper crust intermittently during Tertiary magmatism. Zircon fission-track (ZFT) pooled ages range from 35.63 2.17 to 6.91 0.36 (2SE) Ma, and are generally comparable with the U-Pb ages at each locality. These results suggest that the diorites cooled rapidly below 250-350 degree, (i.e. through the partial annealing zone of the ZFT system), following their intrusion. On the other hand, the zircon and apatite (U-Th-Sm)/He (ZHe and AHe) weighted mean ages, ranging from 11.71 0.36 to 8.82 0.26 and 9.21 0.52 to 0.98 0.088 (2SE) Ma respectively, indicate a decrease in cooling rates at a lower temperature range, especially through the partial retention zone of the AHe system. This observation suggests that the ZFT ages reflect initial cooling of the dioritic magma, whereas the AHe ages reflect the cooling history associated with regional exhumation following the initial cooling phase. Spatial distribution of the AHe ages suggest that rapid exhumation of the Cordillera Central during the Quaternary resulted from the block-like uplift of the entire mountain range.

Zircon U-Pb dates from the Taiheizan Complex Plutons in Akita Prefecture, NE Japan

Nakajima, Toru; Nagata, Mitsuhiro; Fukuda, Shoma; Sueoka, Shigeru

Chishitsugaku Zasshi (Internet), 129(1), p.503 - 507, 2023/11

https://doi.org/10.5575/geosoc.2023.0016

Zircon U-Pb dating was carried out on granitic rocks from plutons in the Taiheizan Complex in Akita Prefecture, NE Japan. Two granodiorites from the Main Intrusive Rocks yielded weighted mean 206Pb/238U dates of 103.41.0 Ma and 115.61.1 Ma (1SE). Three porphyrygranite from the Young Intrusive Rocks yielded weighted mean 206Pb/238U dates of 11.40.1 Ma, 4.70.1Ma, and 4.80.1 Ma (1SE). The older and younger dates can be interpreted as the ages of early and later stages of granitic intrusion at the sampling locations. The Pliocene U-Pb dates suggest that the Nibetsu Body in the Young Intrusive Rocks is one of the youngest granitic plutons currently exposed on Earth.

Numerical simulation technologies for safety evaluation in plant lifecycle optimization method, ARKADIA for advanced reactors

Uchibori, Akihiro; Doda, Norihiro; Aoyagi, Mitsuhiro; Sonehara, Masateru; Sogabe, Joji; Okano, Yasushi; Takata, Takashi*; Tanaka, Masaaki; Enuma, Yasuhiro; Wakai, Takashi; et al.

Nuclear Engineering and Design, 413, p.112492_1 - 112492_10, 2023/11

https://doi.org/10.1016/j.nucengdes.2023.112492

The ARKAIDA has been developed to realize automatic optimization of plant design from safety evaluation for the advanced reactors represented by a sodium-cooled fast reactor. ARKADIA-Design offers functions to support design optimization both in normal operating conditions and design basis events. The multi-level simulation approach by the coupled analysis such as neutronics, core deformation, core thermal hydraulics was developed as one of the main technologies. On the other hand, ARKAIDA-Safety aims for safety evaluation considering severe accidents. As a key technology, the numerical methods for in- and ex-vessel coupled phenomena during severe accidents in sodium-cooled fast reactors were tested through a hypothetical severe accident event. Improvement of the ex-vessel model and development of the AI technology to find best design solution have been started.

Annual report for research on geosphere stability for long-term isolation of radioactive waste in fiscal year 2022

Niwa, Masakazu; Shimada, Koji; Sueoka, Shigeru; Ishihara, Takanori; Ogawa, Hiroki; Hakoiwa, Hiroaki; Watanabe, Tsuyoshi; Nishiyama, Nariaki; Yokoyama, Tatsunori; Ogata, Manabu; et al.

JAEA-Research 2023-005, 78 Pages, 2023/10

JAEA-Research-2023-005.pdf:6.51MB

This annual report documents the progress of research and development (R&D) in the 1st fiscal year of the Japan Atomic Energy Agency 4th Medium- and Long-term Plan (fiscal years 2022-2028) to provide the scientific base for assessing geosphere stability for long-term isolation of high-level radioactive waste. The plan framework is structured into the following categories: (1) Development and systematization of investigation techniques, (2) Development of models for long-term estimation and effective assessment, (3) Development of dating techniques. The current status of R&D activities with previous scientific and technological progress is summarized.

JSME series in thermal and nuclear power generation Vol.3 (Sodium-cooled fast reactor development; R&Ds on thermal-hydraulics and safety assessment towards social implementation)

Tanaka, Masaaki; Uchibori, Akihiro; Okano, Yasushi; Yokoyama, Kenji; Uwaba, Tomoyuki; Enuma, Yasuhiro; Wakai, Takashi; Asayama, Tai

Dai-27-Kai Doryoku, Enerugi Gijutsu Shimpojiumu Koen Rombunshu (Internet), 5 Pages, 2023/09

The book, JSME Series in Thermal and Nuclear Power Generation Vol.3 Sodium-cooled Fast Reactor, was published as a 30th anniversary memorial project of Power & Energy Systems Division. This paper describes an introduction of the book on a part of key technologies regarding safety assessment, thermal-hydraulics, neutronics, and fuel and material development. This introductory paper also provides an overview of an integrated evaluation system named ARKADIA to offer the best possible solutions for challenges arising during the design process, safety assessment, and operation of a nuclear plant over its life cycle, in active use of the R&D efforts and knowledges on thermal-hydraulics and safety assessment with state-of-the-art numerical analysis technologies.

R&D of digital technology on inverse estimation of radioactive source distributions and related source countermeasures; R&D status of digital platform including 3D-ADRES-indoor

Machida, Masahiko; Yamada, Susumu; Kim, M.; Okumura, Masahiko; Miyamura, Hiroko; Shikaze, Yoshiaki; Sato, Tomoki*; Numata, Yoshiaki*; Tobita, Yasuhiro*; Yamaguchi, Takashi; et al.

RIST News, (69), p.2 - 18, 2023/09

https://www.rist.or.jp/rnews/69/69s2.pdf

The contamination of radioactive materials leaked from the reactor has resulted in numerous hot spots in the Fukushima Daiichi Nuclear Power Station (1F) building, posing obstacles to its decommissioning. In order to solve this problem, JAEA has conducted research and development of the digital technique for inverse estimation of radiation source distribution and countermeasures against the estimated source in virtual space for two years from 2021 based on the subsidy program "Project of Decommissioning and Contaminated Water Management" performed by the funds from the Ministry of Economy, Trade and Industry. In this article, we introduce the results of the project and the plan of the renewal project started in April 2023. For the former project, we report the derivative method for LASSO method considering the complex structure inside the building and the character of the source and show the result of the inverse estimation using the method in the real reactor building. Moreover, we explain the platform software "3D-ADRES-Indoor" which integrates these achievements. Finally, we introduce the plan of the latter project.

Intruder configurations in Ne at the transition into the island of inversion; Detailed structure study of Ne

Wang, H.*; Yasuda, Masahiro*; Kondo, Yosuke*; Nakamura, Takashi*; Tostevin, J. A.*; Ogata, Kazuyuki*; Otsuka, Takaharu*; Poves, A.*; Shimizu, Noritaka*; Yoshida, Kazuki; et al.

Physics Letters B, 843, p.138038_1 - 138038_9, 2023/08

https://doi.org/10.1016/j.physletb.2023.138038

Detailed -ray spectroscopy of the exotic neon isotope Ne has been performed using the one-neutron removal reaction from Ne. Based on an analysis of parallel momentum distributions, a level scheme with spin-parity assignments has been constructed for Ne and the negative-parity states are identified for the first time. The measured partial cross sections and momentum distributions reveal a significant intruder p-wave strength providing evidence of the breakdown of the N = 20 and N = 28 shell gaps. Only a weak, possible f-wave strength was observed to bound final states. Large-scale shell-model calculations with different effective interactions do not reproduce the large p-wave and small f-wave strength observed experimentally, indicating an ongoing challenge for a complete theoretical description of the transition into the island of inversion along the Ne isotopic chain.