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Tsuru, Tomohito; Nishimura, Katsuhiko*; Matsuda, Kenji*; Nunomura, Norio*; Namiki, Takahiro*; Lee, S.*; Higemoto, Wataru; Matsuzaki, Teiichiro*; Yamaguchi, Masatake; Ebihara, Kenichi; et al.
Metallurgical and Materials Transactions A, 54(6), p.2374 - 2383, 2023/06
Times Cited Count:0 Percentile:0(Materials Science, Multidisciplinary)Although hydrogen embrittlement susceptibility of high-strength Al alloys is recognized as a critical issue in the practical use of Al alloys, identifying the hydrogen trapping or distribution has been challenging. In the present study, an effective approach based on experiment and simulation is proposed to explore the potential trap sites in Al alloys. Zero-field muon spin relaxation experiments were carried out for Al-0.5%Mg, Al-0.2%Cu, Al-0.15%Ti, Al-0.011%Ti, Al-0.28%V, and Al-0.015%V (at.%) in the temperature range from 5 to 300 K. The temperature variations of the dipole field widths have revealed three peaks for Al-0.5%Mg, four peaks for Al-0.2%Cu, three peaks for Al-0.011%Ti and Al-0.015%V. Atomic configurations of the muon trapping sites corresponding to the observed peaks are well assigned using the first-principles calculations for the trap energies of hydrogen around a solute and solute-vacancy pair. The extracted linear relationship between the muon peak temperature and the trap energy enables us to explore the potential alloying elements and their complex that have strong binding energies with hydrogen in Al alloys.
Bendo, A.*; Matsuda, Kenji*; Nishimura, Katsuhiko*; Nunomura, Norio*; Tsuchiya, Taiki*; Lee, S.*; Marioara, C. D.*; Tsuru, Tomohito; Yamaguchi, Masatake; Shimizu, Kazuyuki*; et al.
Materials Science and Technology, 36(15), p.1621 - 1627, 2020/09
Times Cited Count:8 Percentile:47.13(Materials Science, Multidisciplinary)Metastable phases in aluminum alloys are the primary nano-scale precipitates which have the biggest contribution to the increase in the tangible mechanical properties. The continuous increase in hardness in the 7xxx aluminum alloys is associated with the phase transformation from clusters or GP-zones to the metastable phase. The transformation which is structural and compositional should occur following the path of the lowest activation energy. This work is an attempt to gain insight into how the structural transformation may occur based on the shortest route of diffusion for the eventual structure to result in that of phase. However, for the compositional transformation to occur, the proposed mechanism may not stand, since it is a prerequisite for the atoms to be at very precise positions in the aluminum lattice, at the very beginning of structural transformation, which may completely differ from that of the GP-zones atomic arrangements.
Bendo, A.*; Matsuda, Kenji*; Lervik, A.*; Tsuru, Tomohito; Nishimura, Katsuhiko*; Nunomura, Norio*; Holmestad, R.*; Marioara, C. D.*; Shimizu, Kazuyuki*; Toda, Hiroyuki*; et al.
Materials Characterization, 158, p.109958_1 - 109958_7, 2019/12
Times Cited Count:19 Percentile:78.27(Materials Science, Multidisciplinary)Characterization of precipitates in Al-Zn-Mg alloys, using a combination of electron diffraction, bright field transmission electron microscopy and atomic scale scanning transmission electron microscopy imaging revealed the presence of an unreported orientation relationship between the -MgZn phase and the Al lattice with the following orientation relationship (0001) (120) and () (001), plate on (120). The precipitate interfaces were observed and analyzed along two projections 90 to one-another. The precipitate coarsening was through the common thickening ledge mechanism. The ledges were significantly stepped along one lateral direction. An interface relaxation model using density functional theory was carried out to explain the precipitate behavior.
Matsuda, Kenji*; Yasumoto, Toru*; Bendo, A.*; Tsuchiya, Taiki*; Lee, S.*; Nishimura, Katsuhiko*; Nunomura, Norio*; Marioara, C. D.*; Lervik, A.*; Holmestad, R.*; et al.
Materials Transactions, 60(8), p.1688 - 1696, 2019/08
Times Cited Count:14 Percentile:63.04(Materials Science, Multidisciplinary)no abstracts in English
Bendo, A.*; Maeda, Tomoyoshi*; Matsuda, Kenji*; Lervik, A.*; Holmestad, R.*; Marioara, C. D.*; Nishimura, Katsuhiko*; Nunomura, Norio*; Toda, Hiroyuki*; Yamaguchi, Masatake; et al.
Philosophical Magazine, 99(21), p.2619 - 2635, 2019/07
Times Cited Count:26 Percentile:82.72(Materials Science, Multidisciplinary)Nishimura, Katsuhiko*; Matsuda, Kenji*; Lee, S.*; Nunomura, Norio*; Shimano, Tomoki*; Bendo, A.*; Watanabe, Katsumi*; Tsuchiya, Taiki*; Namiki, Takahiro*; Toda, Hiroyuki*; et al.
Journal of Alloys and Compounds, 774, p.405 - 409, 2019/02
Times Cited Count:3 Percentile:17.96(Chemistry, Physical)Toda, Hiroyuki*; Yamaguchi, Masatake; Matsuda, Kenji*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Su, H.*; Fujihara, Hiro*; Ebihara, Kenichi; Itakura, Mitsuhiro; Tsuru, Tomohito; et al.
Tetsu To Hagane, 105(2), p.240 - 253, 2019/02
Times Cited Count:0 Percentile:0(Metallurgy & Metallurgical Engineering)no abstracts in English