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Journal Articles

Detection of hydroxyl and hydride functional groups in a ceria crystal under hydrogen reduction

Matsukawa, Takeshi*; Iida, Kazuki*; Nakamura, Mitsutaka; Ishigaki, Toru*

CrystEngComm (Internet), 23(12), p.2355 - 2359, 2021/03

 Times Cited Count:4 Percentile:55.82(Chemistry, Multidisciplinary)

Journal Articles

Local disorder in proton conductor BaSn$$_{0.5}$$In$$_{0.5}$$O$$_{2.75}$$ analyzed by neutron diffraction/ atomic pair distribution function

Igawa, Naoki; Kodama, Katsuaki; Taguchi, Tomitsugu*; Yoshida, Yukihiko*; Matsukawa, Takeshi*; Hoshikawa, Akinori*; Ishigaki, Toru*

Transactions of the Materials Research Society of Japan, 43(6), p.329 - 332, 2018/12

For the understanding of the crystal structural effect on the electrical properties, the local disorder in BaSn$$_{0.5}$$In$$_{0.5}$$O$$_{2.75}$$ which is one of the excellent proton conductors for solid oxide fuel cells was estimated by using the Atomic Pair Distribution Function (PDF) analysis method with the neutron diffraction. The local structure is almost the same as the average structure which was estimated by the Rietveld analysis using the cubic crystal structure (space group, $${it Pm}$$$$overline{3}$$$${it m}$$) in the atomic distance range of ${it r}$ $$>$$ 6${AA}$. The PDF profile was fitted better using the tetragonal crystal structure with the space group of ${it P}$4/${it mmm}$ than those with $${it Pm}$$$$overline{3}$$$${it m}$$ in the range ${it r}$ $$<$$ 6${AA}$. Those results indicate the presence of the local disorder in the lattice. In this work, the relationship between the average and local structures of BaSn$$_{0.5}$$In$$_{0.5}$$O$$_{2.75}$$ will be discussed.

Journal Articles

Time-of-flight elastic and inelastic neutron scattering studies on the localized 4d electron layered perovskite La$$_5$$Mo$$_4$$O$$_{16}$$

Iida, Kazuki*; Kajimoto, Ryoichi; Mizuno, Yusuke*; Kamazawa, Kazuya*; Inamura, Yasuhiro; Hoshikawa, Akinori*; Yoshida, Yukihiko*; Matsukawa, Takeshi*; Ishigaki, Toru*; Kawamura, Yukihiko*; et al.

Journal of the Physical Society of Japan, 86(6), p.064803_1 - 064803_6, 2017/06

 Times Cited Count:1 Percentile:12.03(Physics, Multidisciplinary)

Journal Articles

The Two-step nucleation of G-phase in ferrite

Matsukawa, Yoshitaka*; Takeuchi, Tomoaki; Kakubo, Yuta*; Suzudo, Tomoaki; Watanabe, Hideo*; Abe, Hiroaki*; Toyama, Takeshi*; Nagai, Yasuyoshi*

Acta Materialia, 116, p.104 - 113, 2016/09

 Times Cited Count:73 Percentile:95.76(Materials Science, Multidisciplinary)

Atom probe tomography (APT) and TEM were combined for identifying the stage at which solute clusters transform into compounds crystallographically distinct from the matrix, in the precipitation of the G-phase (Ni$$_{16}$$Si$$_{7}$$Mn$$_{6}$$) from ferrite solid solution subjected to isothermal annealing at 673 K. Based on a systematic analysis of solute clusters as a function of annealing time, the nucleation of the G-phase was found to occur via a two-step process. Moreover, the structural change was found to occur via another two-step process. There was a time lag between the end of cluster growth to become a critical size and the start of the structural change. During the incubation period solute enrichment occurred inside the clusters without further size growth, indicating that the nucleation of the G-phase occurs at the critical size with a critical composition. Judging from the results of APT, TEM and the simulation of electron diffraction patterns, the critical composition was estimated to be Ni$$_{16}$$Si$$_{3.5}$$(Fe,Cr)$$_{3.5}$$Mn$$_{6}$$.

Journal Articles

Effects of thermal aging on microstructure and hardness of stainless steel weld-overlay claddings of nuclear reactor pressure vessels

Takeuchi, Tomoaki; Kakubo, Yuta*; Matsukawa, Yoshitaka*; Nozawa, Yasuko*; Toyama, Takeshi*; Nagai, Yasuyoshi*; Nishiyama, Yutaka; Katsuyama, Jinya; Yamaguchi, Yoshihito; Onizawa, Kunio; et al.

Journal of Nuclear Materials, 452(1-3), p.235 - 240, 2014/09

 Times Cited Count:40 Percentile:95.16(Materials Science, Multidisciplinary)

Microstructures and hardness of stainless steel weld overlay cladding of reactor pressure vessels subjected to the thermal aging at 400 $$^{circ}$$C for 100-10,000 h were investigated using atom probe tomography and nanoindentation technique. The Cr concentration fluctuation in the $$delta$$-ferrite phase caused by spinodal decomposition rapidly progressed by the 100 h aging while NiSiMn clusters increased in number density at 2,000 h and coarsened at 10,000 h. The hardness of the $$delta$$-ferrite phase also rapidly increased at the short aging time. The Cr concentration fluctuation and the hardness were in good correlation with the degree of the Cr concentration fluctuation rather than the formation of the NiSiMn clusters. These results strongly suggested that the dominant factor of the hardening of the $$delta$$-ferrite phase by the thermal aging was Cr spinodal decomposition.

Journal Articles

Effects of neutron irradiation on microstructures and hardness of stainless steel weld-overlay cladding of nuclear reactor pressure vessels

Takeuchi, Tomoaki; Kakubo, Yuta*; Matsukawa, Yoshitaka*; Nozawa, Yasuko*; Toyama, Takeshi*; Nagai, Yasuyoshi*; Nishiyama, Yutaka; Katsuyama, Jinya; Yamaguchi, Yoshihito; Onizawa, Kunio

Journal of Nuclear Materials, 449(1-3), p.273 - 276, 2014/06

 Times Cited Count:19 Percentile:81.57(Materials Science, Multidisciplinary)

Microstructural changes and hardness of stainless steel weld overlay cladding of reactor pressure vessels subjected to the neutron irradiation with a dose of 7.2 $$times$$ 10$$^{19}$$n cm$$^{-2}$$ (E $$>$$ 1 MeV) and a flux of 1.1 $$times$$ 10$$^{13}$$n cm$$^{-2}$$ s$$^{-1}$$ at 290$$^{circ}$$C were investigated by atom probe tomography and with nanoindentation technique. In order to isolate the effect of the irradiation, we compared the results of the measurements of the irradiated sample with that of the aged one at 300$$^{circ}$$C for the time equivalent to the irradiation. The Cr concentration fluctuation was enhanced in the $$delta$$-ferrite phase of the irradiated sample. In addition, the enhancement of the concentration fluctuation of Si, which was not observed in the aged sample, was observed. The hardening at the $$delta$$-ferrite phase was occurred by both the irradiation and the aging. However, the former was more than that expected from the Cr concentration fluctuation, which suggested that the Si concentration fluctuation and irradiation-induced defects were possible origins of the additional hardening.

Journal Articles

The First electron bunch measurement by means of dast organic EO crystals

Okayasu, Yuichi*; Tomizawa, Hiromitsu*; Matsubara, Shinichi*; Sato, Takahiro*; Ogawa, Kanade*; Togashi, Tadashi*; Takahashi, Eiji*; Minamide, Hiroaki*; Matsukawa, Ken*; Aoyama, Makoto; et al.

Proceedings of 1st International Beam Instrumentation Conference (IBIC 2012) (Internet), 5 Pages, 2012/10

no abstracts in English

Journal Articles

Development of 300$$^{circ}$$C heat resistant boron-loaded resin for neutron shielding

Morioka, Atsuhiko; Sakurai, Shinji; Okuno, Koichi*; Sato, Satoshi; Verzirov, Y. M.; Kaminaga, Atsushi; Nishitani, Takeo; Tamai, Hiroshi; Shibama, Yusuke; Yoshida, Shigeru*; et al.

Journal of Nuclear Materials, 367-370(2), p.1085 - 1089, 2007/08

 Times Cited Count:25 Percentile:83.32(Materials Science, Multidisciplinary)

A 300$$^{circ}$$C heat-resistant neutron shielding material is newly developed, which consists of phenol-based resin with 6 weight-% boron. The neutron shielding performance of the developed resin, examined by the $$^{252}$$Cf neutron source, is almost the same as that of the polyethylene. The neutron shielding characteristic was also estimated by 3D Monte Carlo Code MCNP-4C2 using the continuous energy cross section data sets based on the JENDL-3.2. The calculation result agrees well with the experimental result. To understand the kinds of the outgas from the developed resin in the high temperature region, the mass spectrum of the outgas was measured until $$sim$$300$$^{circ}$$C by Thermal Desorption Specroscopy (TDS). The observed mass number was 2, 17, 18, 28, 32, and 44. The number corresponds to hydrogen (H$$_{2}$$), ammonia (NH$$_{3}$$), water (H$$_{2}$$O), carbon monoxide (CO), oxygen (O$$_{2}$$), carbon dioxide (CO$$_{2}$$), respectively. The main outgas component from the resin at 100$$sim$$150$$^{circ}$$C was NH $$_{3}$$ and H$$_{2}$$O. The outgas of NH$$_{3}$$ and H$$_{2}$$O from the resin have been measured, however, the neutron shielding performance of the resin after 200$$^{circ}$$C baking was almost the same as that before baking. The quantitative analysis of the outgas from the resin in the high temperature region was done by the Temperature Programmed Desorption (TPD) / Gas Chromatography and Mass spectrometry (GC/MS). The 13 kinds of organic gases have been observed by the amount of $$mu$$g/g at 300$$^{circ}$$C. The neutron shielding performance of the developed resin at 300$$^{circ}$$C was simulated by the 3D analysis. The resonance cross section of the nucleus is broad at the high temperature region by the Doppler effect. The calculation results using 327$$^{circ}$$C library and 20$$^{circ}$$C library are almost same.

Journal Articles

Tokamak and spherical tokamak research in Japan

Takase, Yuichi*; Kikuchi, Mitsuru; Maekawa, Takashi*; Matsukawa, Makoto; Nagata, Masayoshi*; Nishio, Satoshi; Ono, Yasushi*; Sato, Konosuke*; Tobita, Kenji

Fusion Science and Technology, 51(2T), p.46 - 51, 2007/02

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

Japanese tokamak and spherical tokamak (ST) research programs are described. Tokamak research will focus on steady state high($$beta$$$$_{N}$$ = 3.5-5.5) research on JT-60SA (formerly NCT) in support of ITER and DEMO. JT-60SA will also serve as the Satellite Tokamak under the JA-EU Broader Approach framework. ST research has been reorganized as the All-Japan ST Research Program, aiming for creative and innovative research focused on ultra-high and ultra-long pulse regimes. Results of plasma start-up, RF heating, and plasma merging reconnection experiments are summarized. Prospects of contribution of low aspect ratio tokamaks to fusion energy development, are presented.

Journal Articles

Design study of fusion DEMO plant at JAERI

Tobita, Kenji; Nishio, Satoshi; Enoeda, Mikio; Sato, Masayasu; Isono, Takaaki; Sakurai, Shinji; Nakamura, Hirofumi; Sato, Satoshi; Suzuki, Satoshi; Ando, Masami; et al.

Fusion Engineering and Design, 81(8-14), p.1151 - 1158, 2006/02

 Times Cited Count:123 Percentile:99.01(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Irradiation and penetration tests of boron-doped low activation concrete using 2.45 MeV and 14 MeV neutron sources

Morioka, Atsuhiko; Sato, Satoshi; Kinno, Masaharu*; Sakasai, Akira; Hori, Junichi*; Ochiai, Kentaro; Yamauchi, Michinori*; Nishitani, Takeo; Kaminaga, Atsushi; Masaki, Kei; et al.

Journal of Nuclear Materials, 329-333(2), p.1619 - 1623, 2004/08

 Times Cited Count:10 Percentile:55.72(Materials Science, Multidisciplinary)

The neutron penetration and the activation characteristics of the boron-doped low activation concrete were investigated for irradiation of 2.45 and 14 MeV neutrons. The shielding property of the 2 wt% boron-doped low activation concrete is superior to that of the 1 wt% boron for the thermal neutron, on the contrary to the no clear difference for the fast neutron. The total activity detected in the boron-doped low activation concrete was about one hundredth of that in the geostandard sample at more than 30 days cooling time. The total activity of the boron-doped concrete by major nuclei does not depend on the boron density for the 14 MeV neutron irradiation.

Journal Articles

Electric power flow in a nuclear fusion power plant

Matsukawa, Makoto; Tobita, Kenji; Chikaraishi, Hirotaka*; Sagara, Akio*; Norimatsu, Takayoshi*

Purazuma, Kaku Yugo Gakkai-Shi, 80(7), p.559 - 562, 2004/07

Final purpose of the fusion energy development is to utilize the produced fusion power mainly as electric power for the easiness of transmission and conversion. In spite of the type of fusion power plant, large circulating electric power should exist in the plant for the plasma heating, current drive. This paper describes the electric power flow in the nuclear fusion power plants to be built as the DEMO reactor beyond ITER. Here, the necessity of the local energy storage and high efficient converter will be also discussed.

Journal Articles

Neutron transmission experiment of boron-doped resin for the JT-60SC neutron shield using 2.45 MeV neutron source

Morioka, Atsuhiko; Sato, Satoshi; Ochiai, Kentaro; Sakasai, Akira; Hori, Junichi; Yamauchi, Michinori*; Nishitani, Takeo; Kaminaga, Atsushi; Masaki, Kei; Sakurai, Shinji; et al.

Journal of Nuclear Science and Technology, 41(Suppl.4), p.109 - 112, 2004/03

Neutron shielding material of the port section of JT-60 superconducting modification (JT-60SC) serves as a design which used resin (KRAFTON-HB4) excellent in the temperature characteristic from polyethylene. In order to make port weight mitigate and reduce the nuclear heating of the superconducting coil, we were developed the resin which added natural BORON to resin. The 2.45MeV neutron generated in the D-D reaction was irradiated, the penetration of the neutron was measured in some kinds of samples which changed the amount of BORON, and the shielding performance of the resin containing BORON was compared with them. The penetration rates of fast neutron flux do not depend on the doped density of boron in both measurements. Whereas the penetration rates of thermal neutron flux in the resin with 2 wt% B are about 25% lower than those with 1 wt% at the back surface of the test specimens.

Journal Articles

Advanced fusion technologies developed for JT-60 superconducting Tokamak

Sakasai, Akira; Ishida, Shinichi; Matsukawa, Makoto; Akino, Noboru; Ando, Toshinari*; Arai, Takashi; Ezato, Koichiro; Hamada, Kazuya; Ichige, Hisashi; Isono, Takaaki; et al.

Nuclear Fusion, 44(2), p.329 - 334, 2004/02

no abstracts in English

Journal Articles

Advanced fusion technologies developed for JT-60 superconducting Tokamak

Sakasai, Akira; Ishida, Shinichi; Matsukawa, Makoto; Akino, Noboru; Ando, Toshinari*; Arai, Takashi; Ezato, Koichiro; Hamada, Kazuya; Ichige, Hisashi; Isono, Takaaki; et al.

Nuclear Fusion, 44(2), p.329 - 334, 2004/02

 Times Cited Count:7 Percentile:22.95(Physics, Fluids & Plasmas)

no abstracts in English

Journal Articles

Progress in physics and technology developments for the modification of JT-60

Tamai, Hiroshi; Matsukawa, Makoto; Kurita, Genichi; Hayashi, Nobuhiko; Urata, Kazuhiro*; Miura, Yushi; Kizu, Kaname; Tsuchiya, Katsuhiko; Morioka, Atsuhiko; Kudo, Yusuke; et al.

Plasma Science and Technology, 6(1), p.2141 - 2150, 2004/02

 Times Cited Count:2 Percentile:6.49(Physics, Fluids & Plasmas)

The dominant issue for the the modification program of JT-60 (JT-60SC) is to demonstrate the steady state reactor relevant plasma operation. Physics design on plasma parameters, operation scenarios, and the plasma control method are investigated for the achievement of high-$$beta$$. Engineering design and the R&D on the superconducting magnet coils, radiation shield, and vacuum vessel are performed. Recent progress in such physics and technology developments is presented.

Journal Articles

Objectives and design of the JT-60 superconducting tokamak

Ishida, Shinichi; Abe, Katsunori*; Ando, Akira*; Chujo, T.*; Fujii, Tsuneyuki; Fujita, Takaaki; Goto, Seiichi*; Hanada, Kazuaki*; Hatayama, Akiyoshi*; Hino, Tomoaki*; et al.

Nuclear Fusion, 43(7), p.606 - 613, 2003/07

no abstracts in English

Journal Articles

Objectives and design of the JT-60 superconducting tokamak

Ishida, Shinichi; Abe, Katsunori*; Ando, Akira*; Cho, T.*; Fujii, Tsuneyuki; Fujita, Takaaki; Goto, Seiichi*; Hanada, Kazuaki*; Hatayama, Akiyoshi*; Hino, Tomoaki*; et al.

Nuclear Fusion, 43(7), p.606 - 613, 2003/07

 Times Cited Count:33 Percentile:69.14(Physics, Fluids & Plasmas)

no abstracts in English

Journal Articles

Engineering design study of JT-60 superconducting modification

Sakasai, Akira; Ishida, Shinichi; Matsukawa, Makoto; Kurita, Genichi; Akino, Noboru; Ando, Toshinari*; Arai, Takashi; Ichige, Hisashi; Kaminaga, Atsushi; Kato, Takashi; et al.

Proceedings of 19th IEEE/NPSS Symposium on Fusion Engineering (SOFE), p.221 - 225, 2002/00

no abstracts in English

Journal Articles

Steady-state operation scenarios with a central current hole for JT-60SC

Tamai, Hiroshi; Ishida, Shinichi; Kurita, Genichi; Sakamoto, Yoshiteru; Fujita, Takaaki; Shirai, Hiroshi; Tsuchiya, Katsuhiko; Matsukawa, Makoto; Sakasai, Akira; Sakurai, Shinji; et al.

Proceedings of 29th European Physical Society Conference on Plasma Physics and Controlled Fusion, 4 Pages, 2002/00

This paper presents the feasibility and issues of steady state operation with a central current hole for JT-60SC, the superconducting tokamak to be modified from JT-60, from the view of reactor applicability of the current hole. An impact of the current hole on fusion engineering would stand in no necessity of central current drive leading to a remarkable reduction of neutral beam injection energy. The 1.5D time-dependent transport code analysis is made with using thermal and particle transport coefficients deduced from observations in JT-60U as a function of the magnetic shear. A steady state operation with HHy2~1.6 and beta_N~4 is obtained at Ip=1.5 MA, Bt=2 T and q95=4.5 by off-axis beams of 11.2 MW. The bootstrap fraction of ~75% of the plasma current and the current hole region of ~30% of the minor radius are sustained up to 70 s. The results suggest that a bootstrap current evolution near the current hole region and a relation between the location of ITB and the central current hole region are important to achieve a steady state plasma compatible with the current hole.

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