Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Matsumoto, Keisuke*; Koyama, Tsukasa*; Mori, Shigeo*; Yoshii, Kenji; Kambe, Takashi*; Ikeda, Naoshi*
IOP Conference Series; Materials Science and Engineering, 18(9), p.092047_1 - 092047_4, 2011/09
Times Cited Count:1 Percentile:52.59(Materials Science, Ceramics)Changes of charge ordered (CO) structure by partial substitution of Mn for Fe in YbFeO were investigated by a transmission electron microscope (TEM), incombination with conventional dielectric measurement. It is revealed that partial substitution of Mn for Fe in YbFeO destroyed drastically the CO structure with the wave vector of q=1/3 1/3 1/2. Consequently polar clustering structure giving rise to honeycomb-shaped diffuse streaks was found in YbFeMnO. The random distribution of polar clustering structure gives rise to characteristic broad dielectric dispersion.
Matsumoto, Keisuke*; Matsuo, Yoji*; Oishi, Daisuke*; Akahama, Yuji*; Yoshii, Kenji; Hanasaki, Noriaki*; Kambe, Takashi*; Ikeda, Naoshi*; Kimizuka, Noboru*; Mori, Shigeo*
no journal, ,
We have investigated the charge-ordered structure and physical properties of YbFeMnO. Electron diffraction measurements showed a disappearance of charge-ordered structure of Fe ions by the Mn substitution. The Mn substitution also led to a monotonic decrease in magnetic transition temperature, low-temperature magnetization and dielectric constants. The results are explained in connection with several factors such as short-range ionic order.
Matsumoto, Keisuke*; Hoshiyama, Takuya*; Oishi, Daisuke*; Akahama, Hiroshi*; Yoshii, Kenji; Kano, Jun*; Hanasaki, Noriaki*; Kambe, Takashi*; Ikeda, Naoshi*; Mori, Shigeo*
no journal, ,
We have investigated the physical properties of YbFeMnO, a derivative system of the electronic ferroelectric RFeO (R: rare earths). Electron diffraction measurements showed taht long-range charge ordering of the Fe-3d charges was observed at room temperature for x=0; this ordering is the origin of ferroelectricity. The x=0.1 oxide showed diffuse scattering patterns at room temperature, instead of the charge-ordered pattern. Thus, 5% Mn substitution can collapse the long-range charge ordering. We will also present the correlation between the magnetic/dielectric properties and the crystal structure.