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Journal Articles

Effect of the headgroup structure on counterion binding in adsorbed surfactant films investigated by total reflection X-ray absorption fine structure spectroscopy

Imai, Yosuke*; Tokiwa, Yuhei*; Ueno, Shusaku*; Tanida, Hajime; Watanabe, Iwao*; Matsubara, Hiroki*; Takiue, Takanori*; Aratono, Makoto*

Bulletin of the Chemical Society of Japan, 91(10), p.1487 - 1494, 2018/10

 Times Cited Count:2 Percentile:8.1(Chemistry, Multidisciplinary)

Competitive binding of binary mixed counterions to the headgroups of adsorbed surfactant films has been investigated at solution surfaces by total reflection X-ray absorption fine structure (XAFS) spectroscopy. The obtained extended XAFS $$chi$$ spectra for bromide counterions are linear combinations of the spectra of fully hydrated bromide ions (free Br) and partially dehydrated bromide ions bound to the headgroups of the surfactant ions (bound Br). From the fraction of bound Br in counterion mixed systems, two series of the relative strengths of counterion binding are proposed for the trimethylammonium (TA$$^{+}$$) and 3-methylimidazolium (MIM$$^{+}$$) headgroups: (a) TA-SO$$_{4}$$ $$<$$ TA-Cl $$<$$ TA-Br $$<$$ TA-BF$$_{4}$$ and (b) MIM-Br $$<$$ TA-Br $$<$$ TA-BF$$_{4}$$ $$<$$ MIM-BF$$_{4}$$. For the TA headgroup, matching the hydration of the headgroups and counterions gives series (a) according to Collins' law, which states that the tendency of contact ion pair formation becomes larger when the absolute values of the hydration enthalpies of the ions match. For the MIM headgroup, the number of binding sites of hydrogen bonds between the MIM headgroup and counterion is essential, which leads to series (b) because of competition between the counterion and water for interaction with the MIM headgroup.

Journal Articles

ESR studies of defects in P-type 6H-SiC irradiated with 3MeV-electrons

D.Cha*; Ito, Hisayoshi; Morishita, Norio; Kawasuso, Atsuo; Oshima, Takeshi; ; J.Ko*; K.Lee*; Nashiyama, Isamu

Mater. Sci. Forum, 264-268, p.615 - 618, 1998/00

no abstracts in English

Journal Articles

Sterilization of Bacillus spores by converted X rays

Ito, Hitoshi; *; ; Sunaga, Hiromi; Ishigaki, Isao

Radiation Physics and Chemistry, 42(4-6), p.597 - 600, 1993/00

 Times Cited Count:2 Percentile:29.78(Chemistry, Physical)

no abstracts in English

Journal Articles

Sterilization of Bacillus spores by converted X-rays

Ito, Hitoshi; *; ; Sunaga, Hiromi; Ishigaki, Isao

Bokin Bobai-Shi, 19(4), p.161 - 166, 1991/00

no abstracts in English

Journal Articles

Radiation-induced degradation of PHB and its copolymer

Mitomo, Hiroshi*; *; ; Ito, Hitoshi; Ishigaki, Isao

Reports on Progress in Polymer Physics in Japan, 34, p.415 - 416, 1991/00

no abstracts in English

Journal Articles

Comparative sensitivity of endospores from some Bacillus species to gamma-rays, X-rays and electron beams for sterilization

*; Ito, Hitoshi; ; Sunaga, Hiromi; Ishigaki, Isao

Shokuhin Shosha, 25(1-2), p.71 - 74, 1990/00

no abstracts in English

Journal Articles

Effect of dose rate on electron beam and $$gamma$$-ray sensitivities of B.pumilus E601 spores

; *; Ito, Hitoshi; Ishigaki, Isao

Shokuhin Shosha, 25(1-2), p.66 - 70, 1990/00

no abstracts in English

Journal Articles

Radiation sensitivity in the spores of BBacillus pumilus E601 strain to electron beams

; Ito, Hitoshi; Ishigaki, Isao

Bokin Bobai-Shi, 17(7), p.311 - 317, 1989/00

no abstracts in English

Journal Articles

Influence of heating on inactivation of irradiated Bacillus pumilus spores

; Ito, Hitoshi; Ishigaki, Isao

Shokuhin Shosha, 24(1-2), p.16 - 20, 1989/00

no abstracts in English

Journal Articles

Target size analysis of bioactive substance by radiation inactivation: Comparison with electron beam and $$gamma$$-ray

Kume, Tamikazu; ; *; Ishigaki, Isao

Shokuhin Shosha, 23(2), p.84 - 87, 1988/00

no abstracts in English

Journal Articles

Electron-beam sensitivity of dry B. pumilus spores

; Ito, Hitoshi; Ishigaki, Isao

Shokuhin Shosha, 23(2), p.88 - 92, 1988/00

no abstracts in English

Journal Articles

Study on electron beam sensitivities of Bacillus pumilus spores

Watanabe, Yuhei; Ito, Hitoshi; Ishigaki, Isao

Shokuhin Shosha, 22(2), p.12 - 15, 1987/11

In order to estimate the sterility dose of medical supplies for EB, the dry spores of ${it Bacillus pumilus}$ 601 were used as a microbial indicator.

Journal Articles

Morphological effects on oxidation mechanisms of a linear polyethylene

; Hayakawa, Naohiro; *

Reports on Progress in Polymer Physics in Japan, 30, p.171 - 174, 1987/00

no abstracts in English

Journal Articles

Radiation induced oxidation of polyethylene,ethylene-butene copolymer,and ethylene-propylene copolymer

Arakawa, Kazuo; Seguchi, Tadao; ; Hayakawa, Naohiro

Journal of Polymer Science; Polymer Chemistry Edition, 20, p.2681 - 2692, 1982/00

no abstracts in English

Journal Articles

Radiation induced oxidative degradation of polymers, II; Effects of radiation on swelling and gel function of polymers

Seguchi, Tadao; Arakawa, Kazuo; Hayakawa, Naohiro; ; Kuriyama, Isamu

Radiation Physics and Chemistry, 19(4), p.321 - 327, 1982/00

no abstracts in English

Journal Articles

Dose rate effect on radiation-induced oxidation of polyethylene and ethylene-propylene copolymer

Arakawa, Kazuo; Seguchi, Tadao; ; Hayakawa, Naohiro; Kuriyama, Isamu; Machi, Sueo

Journal of Polymer Science; Polymer Chemistry Edition, 19, p.2123 - 2125, 1981/00

no abstracts in English

Journal Articles

Journal Articles

Iodine-initiated,solid-state copolymerization of tetraoxane with 1, 3-dioxolane in the presence of methylal, 6; Studies on copolymer composition

Morita, Yosuke; ; ; ;

J.Appl.Polym.Sci., 23(11), p.3395 - 3409, 1979/00

 Times Cited Count:2

no abstracts in English

Journal Articles

Iodine-initiated,solid-state copolymerization of tetraoxane with 1, 3-dioxolane in the presence of methylal, 8; Mechanical properties of copolymer

Morita, Yosuke; ; ; *;

J.Appl.Polym.Sci., 23(11), p.3421 - 3426, 1979/00

 Times Cited Count:0

no abstracts in English

Journal Articles

Radiation-induced copolymerization of thiophene with maleic anhydride

; ; ; *

J.Macromol.Sci.,Part A, 12(6), p.837 - 851, 1978/00

no abstracts in English

26 (Records 1-20 displayed on this page)