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Imai, Yosuke*; Tokiwa, Yuhei*; Ueno, Shusaku*; Tanida, Hajime; Watanabe, Iwao*; Matsubara, Hiroki*; Takiue, Takanori*; Aratono, Makoto*
Bulletin of the Chemical Society of Japan, 91(10), p.1487 - 1494, 2018/10
Times Cited Count:2 Percentile:8.1(Chemistry, Multidisciplinary)Competitive binding of binary mixed counterions to the headgroups of adsorbed surfactant films has been investigated at solution surfaces by total reflection X-ray absorption fine structure (XAFS) spectroscopy. The obtained extended XAFS spectra for bromide counterions are linear combinations of the spectra of fully hydrated bromide ions (free Br) and partially dehydrated bromide ions bound to the headgroups of the surfactant ions (bound Br). From the fraction of bound Br in counterion mixed systems, two series of the relative strengths of counterion binding are proposed for the trimethylammonium (TA) and 3-methylimidazolium (MIM) headgroups: (a) TA-SO TA-Cl TA-Br TA-BF and (b) MIM-Br TA-Br TA-BF MIM-BF. For the TA headgroup, matching the hydration of the headgroups and counterions gives series (a) according to Collins' law, which states that the tendency of contact ion pair formation becomes larger when the absolute values of the hydration enthalpies of the ions match. For the MIM headgroup, the number of binding sites of hydrogen bonds between the MIM headgroup and counterion is essential, which leads to series (b) because of competition between the counterion and water for interaction with the MIM headgroup.
Haruna, Takumi*; Miyataki, Yuki*; Hirohata, Yohei*; Shibata, Toshio*; Taniguchi, Naoki; Tachikawa, Hirokazu*
Zairyo To Kankyo, 67(9), p.375 - 380, 2018/09
This research aimed to confirm the formation of FeO film on Fe immersed in aqueous 45 mass% NaOH solution containing some oxidants at the boiling temperature, to recognize the optimum immersion time for the formation of thick and protective film, and to reveal the absorption behavior of DO in the FeO film at room temperature. The results were obtained as follows. It was confirmed that FeO film was formed on Fe immersed in the NaOH solution for a time more than 0.6 ks, and the film thickness increased parabolically with an increase in the immersion time. DO absorption test was carried out to the films formed in the NaOH solution for immersion times of 1.2 and 3.6 ks. An amount of DO absorbed into the film increased with an increase in an absorption time up to 1000 ks, and an absorption time more than 1000 ks made an amount of DO constant. The constant amount of DO was larger for the film formed on Fe immersed in the NaOH solution for 3.6 ks than that for 1.2 ks. The transient of the amount of DO absorbed into the film was analyzed on the basis of Fick's law for diffusion, and diffusion coefficients of DO were obtained to be 5.110 cm s and 9.910 cm s for the films formed for 1.2 and 3.6 ks, respectively. Therefore it was estimated that the diffusion coefficient of the FeO film was in the region from 5.110 cm s to 9.910 cm s.
Kotaki, Hideyuki; Kando, Masaki; Daito, Izuru; Kameshima, Takashi*; Kawase, Keigo*; Chen, L. M.*; Fukuda, Yuji; Koga, J. K.; Kiriyama, Hiromitsu; Kondo, Shuji; et al.
Japanese Journal of Applied Physics, 50(6), p.066401_1 - 066401_3, 2011/06
Times Cited Count:1 Percentile:4.76(Physics, Applied)Kotaki, Hideyuki; Kando, Masaki; Daito, Izuru; Homma, Takayuki; Kameshima, Takashi; Kawase, Keigo; Chen, L.-M.*; Fukuda, Yuji; Kiriyama, Hiromitsu; Kondo, Shuji; et al.
AIP Conference Proceedings 1153, p.176 - 181, 2009/07
Tsuchiya, Harufumi*; Enoto, Teruaki*; Torii, Tatsuo; Nakazawa, Kazuhiro*; Yuasa, Takayuki*; Torii, Shunsuke*; Fukuyama, Taro*; Yamaguchi, Takahiro*; Kato, Hiroshi*; Okano, Shinji*; et al.
Physical Review Letters, 102(25), p.255003_1 - 255003_4, 2009/06
Times Cited Count:70 Percentile:90.33(Physics, Multidisciplinary)During thunderstorms on 2008 September 20, a simultaneous detection of -rays and electrons was made at a mountain observatory in Japan located 2770 m above sea level. Both emissions, lasting 90 seconds, were associated with thunderclouds rather than lightning. The photon spectrum, extending to 10 MeV, can be interpreted as consisting of bremsstrahlung -rays arriving from a source which is 60-130 m in distance at 90% confidence level. The observed electrons are likely to be dominated by a primary population escaping from an acceleration region in the clouds.
Kiriyama, Hiromitsu; Mori, Michiaki; Nakai, Yoshiki; Shimomura, Takuya; Tanoue, Manabu*; Akutsu, Atsushi; Okada, Hajime; Motomura, Tomohiro*; Kondo, Shuji; Kanazawa, Shuhei; et al.
Reza Kenkyu, 37(6), p.425 - 430, 2009/06
This paper reviews the temporal contrast and spatial beam quality improvement techniques in a high intensity Ti:sapphire laser system that is based on chirped-pulse amplification (CPA). We describe an optical parametric chirped-pulse amplification (OPCPA) preamplifier that is seeded by a cleaned high-energy pulse. It demonstrates a background amplified spontaneous emission (ASE) level of 10 relative to the peak main femtosecond pulse on the picosecond timescale. We also report a cryogenically-cooled Ti:sapphire final amplifier which generates focused peak intensity in excess of 10 W/cm at a 10 Hz repetition rate.
Kiriyama, Hiromitsu; Mori, Michiaki; Nakai, Yoshiki; Shimomura, Takuya; Tanoue, Manabu*; Akutsu, Atsushi; Okada, Hajime; Motomura, Tomohiro*; Kondo, Shuji; Kanazawa, Shuhei; et al.
Optics Communications, 282(4), p.625 - 628, 2009/02
Times Cited Count:54 Percentile:89.81(Optics)We demonstrate a high-contrast, high-intensity double chirped-pulse amplification (CPA) Ti:sapphire laser system using an optical parametric chirped-pulse (OPCPA) pre- amplifier. By injecting cleaned microjoule seed pulses into the OPCPA, a temporal contrast greater than within picosecond times before the main femtosecond pulse is demonstrated with an output pulse energy of 1.7 J and a pulse duration of 30 fs, corresponding to a peak power of 60 TW at a 10 Hz repetition rate. This system uses a cryogenically-cooled Ti:sapphire final amplifier and generates focused peak intensities in excess of W/.
Kiriyama, Hiromitsu; Mori, Michiaki; Nakai, Yoshiki; Shimomura, Takuya*; Tanoue, Manabu*; Akutsu, Atsushi; Okada, Hajime; Motomura, Tomohiro*; Kondo, Shuji; Kanazawa, Shuhei; et al.
JAEA-Conf 2008-007, p.13 - 16, 2008/08
One of the main bottlenecks for the applications of ultrashort and ultrahigh-peak power lasers in high-field physics is a temporal contrast of the pulses. In ultrahigh-peak power lasers, a nanosecond background of the amplified spontaneous emission (ASE) is generated at the same time as the femtosecond pulse. This background is mostly generated in the preamplifier (regenerative, multipass amplifier). Even though the contrast level is usually in the range from 10 to 10, this level is not sufficiently low at relativistic intensities greater than 10W/cm to avoid unwanted pre-plasmas generation. We demonstrated a high-contrast, high-peak power laser with optical parametric chirped-pulse amplification (OPCPA). With the use of OPCPA, contrast is enhanced to better than 710 in a few picoseconds before the main pulse, which corresponds to an improvement of three to four orders in magnitude compared with conventional systems.
Otsuka, Ichiro; Taki, Hiroshi*; Yamaguchi, Tetsuji; Iida, Yoshihisa; Yamada, Fumika; Inada, Daisuke*; Tanaka, Tadao
JAEA-Research 2008-043, 101 Pages, 2008/03
The influence of carbon steel overpack corrosion on redox potential (h) of bentonite pore water under geological disposal environment was investigated. The thermodynamics data of corrosion products, the corrosion rate of carbon steel, and the information on cathode reactions were acquired by experiments and literature survey. We conducted preliminary analysis of h, ascertained the validity of Phreeq C and identified important points on the analysis. Results were summarized as follows. (1) Thermodynamic data of Fe, FeOH, Fe(OH)(aq), Fe(OH), Fe(OH), Fe, FeS(pyrite), FeCO(siderite),Fe(OH)(s), FeO(magnetite), Fe(cr) were determined by literature survey. The solubility product of FeCO(OH) was determined experimentally, and thermodynamic data were estimated. (2) The corrosion rate of carbon steel was obtained as a function of pH and sulfide ion concentration. (3) After corrosion tests of carbon steel, no CH, HS and HS, the reduction product of CO and SO,were not detected in liquid and gas phases. (4) Preliminary analysis showed that the redox couple changed as HS(aq)/SO, CH(aq)/CO, H(aq)/HO during the evaluation period. After 1000 years, h attained about -500 to -600 mV (vs. NHE) or -750 mV controlled by CH(aq)/CO,or H(aq)/HO, respectively.
Kiriyama, Hiromitsu; Mori, Michiaki; Daito, Izuru; Kotaki, Hideyuki; Kanazawa, Shuhei; Kondo, Shuji; Nakai, Yoshiki; Shimomura, Takuya*; Tanoue, Manabu*; Akutsu, Atsushi; et al.
Reza Gakkai Dai-362-Kai Kenkyukai Hokoku; Kokino Kotai Reza To Sono Oyo, p.33 - 37, 2007/07
We report a high-peak-power, high-contrast laser system, which combines both conventional Ti:sapphire chirped-pulse amplification (CPA) and optical parametric chirped-pulse amplification (OPCPA) techniques for use in experiments where relativistic effects dominate the physics. We have achieved an amplified energy of 2.9 J and an ultrashort recompressed amplified pulse duration of 19fs, corresponding to the peak power of 80 TW, at a 10 Hz repetition rate. With the use of OPCPA, the pre-pulse contrast is enhanced to better than 7 10 in a few picoseconds before the main pulse, which corresponds to an improvement of three to four orders in magnitude compared with conventional systems. By cooling the crystal in the final Ti:sapphire power amplifier down to 77 K, the thermal focal length of about 4 km is obtained when pumped with the maximum pumping condition and has almost no effect on thermal lensing.
Fukuda, Yuji; Akahane, Yutaka; Aoyama, Makoto; Hayashi, Yukio; Homma, Takayuki; Inoue, Norihiro*; Kando, Masaki; Kanazawa, Shuhei; Kiriyama, Hiromitsu; Kondo, Shuji; et al.
Physics Letters A, 363(2-3), p.130 - 135, 2007/02
Collimated relativistic electrons up to 58 MeV with an electron charge of 2.1 nC were generated by the interaction of intense laser pulses with the Ar cluster target at the laser intensity of 3.510W/cm. The resulting spectrum does not fit a Maxwellian distribution, but is well described by a two-temperature Maxwellian, which indicates two mechanisms of the electron acceleration. Two dimensional particle-in-cell simulations demonstrate an important role of clusters. The higher energy electrons are injected when they are expelled from the clusters by the laser pulse field. They then gain their energy during the direct acceleration by the laser pulse, whose phase velocity in the underdense plasma is larger than speed of light in vacuum. The lower energy electrons, which are injected during the plasma wave breaking, are accelerated by the wakefield.
Yamaguchi, Tetsuji; Sakamoto, Yoshifumi; Iida, Yoshihisa; Negishi, Kumi; Taki, Hiroshi; Akai, Masanobu; Jinno, Fumika; Kimura, Yuichiro; Ueda, Masato; Tanaka, Tadao; et al.
Proceedings of International Conference on Nuclear Energy System for Future Generation and Global Sustainability (GLOBAL 2005) (CD-ROM), 6 Pages, 2005/10
no abstracts in English
Iida, Yoshihisa; Taki, Hiroshi; Yamaguchi, Tetsuji; Tanaka, Tadao; Negishi, Kumi; Nakayama, Shinichi
JAERI-Conf 2005-007, p.230 - 235, 2005/08
A variation in data should be quantitatively incorporated in a probabilistic safety assessment of radioactive waste disposal. We focus our experimental efforts on parameters that induce major uncertainties in the radionuclide migration analysis and that have not been quantitatively assessed. Possible sources of uncertainty includes increase in ionic strength of groundwater caused by intrusion of seawater and/or dissolution of sodium nitrate in TRU waste, highly alkaline conditions originating from cementitious materials, and a variation of porewater composition accompanied with corrosion of. This study is a summary of current status of our investigations for solubility and diffusion.
Kando, Masaki; Masuda, Shinichi; Zhidkov, A.*; Yamazaki, Atsushi; Kotaki, Hideyuki; Kondo, Shuji; Homma, Takayuki*; Kanazawa, Shuhei; Nakajima, Kazuhisa; Hayashi, Yukio; et al.
Physical Review E, 71(1), p.015403_1 - 015403_4, 2005/01
Times Cited Count:33 Percentile:77.25(Physics, Fluids & Plasmas)no abstracts in English
*; *; Kugo, Teruhiko; Nakakawa, Masayuki; *; *
Nihon Genshiryoku Gakkai-Shi, 37(6), p.472 - 481, 1995/00
Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)no abstracts in English
Fukuda, Yuji; Akahane, Yutaka; Hayashi, Yukio; Homma, Takayuki; Inoue, Norihiro*; Kando, Masaki; Kanazawa, Shuhei; Kiriyama, Hiromitsu; Kondo, Shuji; Kotaki, Hideyuki; et al.
no journal, ,
no abstracts in English
Tanaka, Tadao; Yamaguchi, Tetsuji; Iida, Yoshihisa; Kimura, Yuichiro; Taki, Hiroshi; Fujiwara, Takeshi; Ueda, Masato*; Mukai, Masayuki; Yamada, Fumika; Mizuno, Tsuyoshi; et al.
no journal, ,
no abstracts in English
Kotaki, Hideyuki; Daito, Izuru; Kando, Masaki; Fukuda, Yuji; Hayashi, Yukio; Chen, L.-M.; Homma, Takayuki; Bolton, P.*; Ma, J.-L.; Mori, Michiaki; et al.
no journal, ,
no abstracts in English
Otsuka, Ichiro; Yamaguchi, Tetsuji; Iida, Yoshihisa; Taki, Hiroshi; Tanaka, Tadao; Nakayama, Shinichi
no journal, ,
no abstracts in English