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Journal Articles

$$^{225}$$Ac metallofullerene; Toward $$^{225}$$Ac nanogenerator in fullerene

Akiyama, Kazuhiko*; Haba, Hiromitsu*; Sueki, Keisuke*; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Nagame, Yuichiro; Katada, Motomi*

Chemistry Letters, 38(10), p.978 - 979, 2009/09

 Times Cited Count:9 Percentile:37.68(Chemistry, Multidisciplinary)

We report on the successful production of a metallofullerene encapsulating the radioactive tracer $$^{225}$$Ac and on its electronic properties studied by radiochromatography. Considering the number of $$pi$$-electrons on the fullerene cage estimated from an HPLC retention time on the 5PBB column and the general oxidation state of Ac (+3), a chemical species of the dominant chromatographic peak is suggested to be Ac@C$$_{82}$$.

Journal Articles

A Metallofullerene that encapsulates $$^{225}$$Ac

Akiyama, Kazuhiko*; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Sueki, Keisuke*; Nagame, Yuichiro; Katada, Motomi*

Journal of Radioanalytical and Nuclear Chemistry, 280(2), p.329 - 331, 2009/05

 Times Cited Count:7 Percentile:45.28(Chemistry, Analytical)

The properties of a metallofullerene that encapsulates $$^{225}$$Ac were studied by radio-chromatographic methods. The results of chromatography on a Buckyclutcher column suggest that there are some metallofullerene isomers of AcC$$_{82}$$. The identical HPLC retention time of the major AcC$$_{82}$$ peak with that of La@C$$_{82}$$ indicates that the structure of one of the AcC$$_{82}$$ isomers is the same as La@C$$_{82}$$.

Journal Articles

Moessbauer spectroscopic study on glaze of pottery

*; *; *; *; Nakahara, Hiromichi*; Nakada, Masami; Saeki, Masakatsu; Aratono, Yasuyuki

Hyperfine Interactions, 91, p.645 - 649, 1994/00

 Times Cited Count:2 Percentile:20.81(Physics, Atomic, Molecular & Chemical)

no abstracts in English

Journal Articles

Mixed-valence states of $$^{57}$$Fe atoms produced in $$^{57}$$Co-labelled [CoFe$$_{2}$$O(CH$$_{2}$$ICO$$_{2}$$)$$_{6}$$(H$$_{2}$$O)$$_{3}$$] and [CoFe$$_{2}$$O(CH$$_{2}$$BrCO$$_{2}$$)$$_{6}$$(H$$_{2}$$O)$$_{3}$$]

*; *; *; *; Aratono, Yasuyuki; Sagawa, Chiaki; Saeki, Masakatsu

Chemistry Letters, 1991, p.403 - 406, 1991/00

no abstracts in English

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