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Mizumachi, Takumi*; Sato, Minami*; Kaneko, Masashi; Takeyama, Tomoyuki*; Tsushima, Satoru*; Takao, Koichiro*
Inorganic Chemistry, 61(16), p.6175 - 6181, 2022/04
Times Cited Count:4 Percentile:34.43(Chemistry, Inorganic & Nuclear)Based on unique 5-fold equatorial coordination of UO, water-compatible pentadentate planar ligands, Hsaldian and its derivatives, were designed as strong and selective capture of UO in seawater. In the simulated seawater condition (0.5 M NaCl + 2.3 mM HCO/CO, pH 8), saldian shows the strongest complexation with UO to form UO(saldian) (log = 28.05 0.07), which is more than 10 order of magnitude greater than amidoxime-based or -inspired ligand systems most commonly employed for U capture from seawater. Good selectivity for UO from other metal ions coexisting in seawater was also demonstrated.
Oyama, Kenji*; Yokoo, Tetsuya*; Ito, Shinichi*; Suzuki, Junichi*; Iwasa, Kazuaki*; Sato, Taku*; Kira, Hiroshi*; Sakaguchi, Yoshifumi*; Ino, Takashi*; Oku, Takayuki; et al.
no journal, ,
Kaneko, Takumi*; Sato, Katsuya; Narumi, Issey*
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no abstracts in English