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Journal Articles

Growth of $$beta$$-FeSi$$_2$$ thin films on $$beta$$-FeSi$$_2$$ (110) substrates by molecular beam epitaxy

Muroga, Masataka*; Suzuki, Hirokazu*; Udono, Haruhiko*; Kikuma, Isao*; Zhuravlev, A. V.; Yamaguchi, Kenji; Yamamoto, Hiroyuki; Terai, Takayuki*

Thin Solid Films, 515(22), p.8197 - 8200, 2007/08

 Times Cited Count:6 Percentile:31.25(Materials Science, Multidisciplinary)

Semiconducting ${it $beta$}$-FeSi$$_2$$ has received much attention as a material for Si-based optoelectronic devices. There are a number of studies on heteroepitaxy of ${it $beta$}$-FeSi$$_2$$ film on Si. However, growth experiments of ${it $beta$}$-FeSi$$_2$$ film on single crystalline ${it $beta$}$-FeSi$$_2$$ substrate have not been investigated yet. Recently, single crystalline ${it $beta$}$-FeSi$$_2$$ with large growth facets by solution growth method using Ga solvent. By obtaining a smooth surface on the substrate, we have succeeded in growing ${it $beta$}$-FeSi$$_2$$ film on ${it $beta$}$-FeSi$$_2$$(110) substrate using molecular-beam epitaxy.

Journal Articles

Single crystalline $$beta$$-FeSi$$_{2}$$ grown using high-purity FeSi$$_{2}$$ source

Goto, Kohei*; Suzuki, Hirokazu*; Udono, Haruhiko*; Kikuma, Isao*; Esaka, Fumitaka; Uchikoshi, Masahito*; Isshiki, Minoru*

Thin Solid Films, 515(22), p.8263 - 8267, 2007/08

 Times Cited Count:15 Percentile:55.86(Materials Science, Multidisciplinary)

We have investigated the effect of FeSi$$_{2}$$ source purity on the electrical property of $$beta$$-FeSi$$_{2}$$ grown from solution. A high purity FeSi$$_{2}$$ source avoided a contamination of Cu and W metals was synthesized by melting a high purity Fe (5N) and Si (5N-up) in a quartz ampoule. The $$beta$$-FeSi$$_{2}$$ crystals grown using the high purity FeSi$$_{2}$$ and Zn solvent showed n-type conduction, whereas those grown using the arc-melted FeSi$$_{2}$$ showed p-type. From the SIMS analysis of the grown crystals, we found that dominant impurity concentrations in the p-type crystals were higher than those in the n-type ones.

Journal Articles

Structural analysis of Co-extracted heptavalent technetium and rhenium complexes by EXAFS

Suzuki, Shinichi; Yaita, Tsuyoshi; Okamoto, Yoshihiro; Shiwaku, Hideaki; Motohashi, Haruhiko*

Physica Scripta, T115, p.306 - 307, 2005/00

In spent fuel reprocessing, distribution behavior of technetium in tri- butyl phosphate (TBP) extraction system is a very complicated. Especially, in the presence of metallic ions, i.e., U(VI), Pu(IV)and Zr(IV)in the TBP extraction system, the extraction of technetium is enhanced by the co- extraction with U, Pu and Zr. The mechanism of co-extraction mechanism of technetium is performed by exchange with nitric acid ion and per-technetate ion. In this research, we perform the structural analysis of technetium complexes in ethanol solution compared with rhenium and manganese complexes by EXAFS. Furthermore we measured some organic complexes and co-extracted complexes of technetium with uranium and zirconium extracted by TBP as compared with those of rhenium.

Journal Articles

Construction and commissioning of a 215-m-long beamline at SPring-8

Goto, Shunji*; Takeshita, Kunikazu*; Suzuki, Yoshio*; Ohashi, Haruhiko*; Asano, Yoshihiro; Kimura, Hiroaki*; Matsushita, Tomohiro*; Yagi, Naoto*; Isshiki, M.*; Yamazaki, H.*; et al.

Nuclear Instruments and Methods in Physics Research A, 467-468(Part1), p.682 - 685, 2001/07

no abstracts in English

Journal Articles

Construction and commissioning of a 215-m-long beamline at SPring-8

Goto, Shunji*; Takeshita, Kunikazu*; Suzuki, Yoshio*; Ohashi, Haruhiko*; Asano, Yoshihiro; Kimura, Hiroaki*; Matsushita, Tomohiro*; Yagi, Naoto*; Isshiki, Maiko*; Yamazaki, H.*; et al.

Nuclear Instruments and Methods in Physics Research A, 467-468(Part1), p.682 - 685, 2001/07

 Times Cited Count:141 Percentile:99.13(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Structural studies of lanthanide(III) complexes with oxydiacetic acid and iminodiacetic acid in aqueous solution by EXAFS

Narita, Hirokazu; Yaita, Tsuyoshi; Suzuki, Shinichi; Takai, Konomi; Tachimori, Shoichi; Motohashi, Haruhiko*

Journal of Synchrotron Radiation, 8(Part2), p.672 - 673, 2001/03

no abstracts in English

Journal Articles

Structural study of lanthanides(III) in aqueous nitrate and chloride solutions by EXAFS

Yaita, Tsuyoshi; Narita, Hirokazu*; Suzuki, Shinichi; Tachimori, Shoichi; Motohashi, Haruhiko; Shiwaku, Hideaki

Journal of Radioanalytical and Nuclear Chemistry, 239(2), p.371 - 375, 1999/00

 Times Cited Count:95 Percentile:98.36(Chemistry, Analytical)

no abstracts in English

Journal Articles

Structural study of holmium(III) and uranium(VI) organic ligand complexes by extended X-ray absorption fine-structure spectroscopy

Yaita, Tsuyoshi; Narita, Hirokazu*; Suzuki, Shinichi; Tachimori, Shoichi; Motohashi, Haruhiko; Shiwaku, Hideaki

Journal of Alloys and Compounds, 271-273, p.184 - 188, 1998/00

 Times Cited Count:17 Percentile:69.24(Chemistry, Physical)

no abstracts in English

Journal Articles

XAFS studies of uranium(VI) and thorium(IV)-amide and TBP complexes in ethanol solution

Yaita, Tsuyoshi; Narita, Hirokazu*; Suzuki, Shinichi; Shiwaku, Hideaki; Motohashi, Haruhiko; Ono, Hideo; Usami, Noriko*; Kobayashi, Katsumi*

Photon Factory Activity Report 1997, P. 81, 1997/00

no abstracts in English

Oral presentation

Nuclear demagnetization ultra-low temperaure stage for neutron scattering experiments

Metoki, Naoto; Abe, Satoshi*; Nagasaki, Fuminori*; Mori, Takuma*; Matsumoto, Koichi*; Suzuki, Haruhiko*; Kaneko, Koji; Koike, Yoshihiro*

no journal, , 

We report a nuclear demagnetization ultra-low temperature stage, which is under construction for the neutron scattering experiments below 1 mK. This stage will be used for the study of heavy fermion nature, or multiple ordering in f electron compounds.

Oral presentation

Instrumentation for neutron scattering experiments at ultra-low temperatures at MUSASI beam port in JRR-3

Metoki, Naoto; Kaneko, Koji; Sugai, Takashi; Abe, Satoshi*; Suzuki, Haruhiko*; Koike, Yoshihiro*

no journal, , 

We will report for the recent development of the ultra-low temperature neutron scattering experiments on the beam port, "multi-purpose thermal neutron application and science" (MUSASI) in JRR-3. This beam port provides an opportunity for difficult or time consuming experiments such as neutron scattering at ultra-low temperature. A nuclear demagnetization stage is now under construction for this purpose. We briefly present the recent situation and future of our study on f electron compounds.

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