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Yamashita, Keishiro*; Komatsu, Kazuki*; Klotz, S.*; Fabelo, O.*; Fernndez-Daz, M. T.*; Abe, Jun*; Machida, Shinichi*; Hattori, Takanori; Irifune, Tetsuo*; Shimmei, Toru*; et al.
Proceedings of the National Academy of Sciences of the United States of America, 119(40), p.e2208717119_1 - e2208717119_6, 2022/10
Times Cited Count:2 Percentile:20.4(Multidisciplinary Sciences)Here we present the first elucidation of the disordered structure of ice VII, the dominant high-pressure form of water, at 2.2 GPa and 298 K from both single-crystal and powder neutron diffraction techniques. We reveal the three-dimensional atomic distributions from the maximum entropy method and unexpectedly find a ring-like distribution of hydrogen in contrast to the commonly-accepted discrete sites. In addition, total scattering analysis at 274 K clarified the difference in the intermolecular structure from ice VIII, the ordered counterpart of ice VII, despite an identical molecular geometry. Our complementary structure analyses robustly demonstrate the unique disordered structure of ice VII. Furthermore, these noble findings are related to the proton dynamics which drastically vary with pressure, and will contribute to an understanding of the structural origin of anomalous physical properties of ice VII under pressures.
Katsube, Daiki*; Ono, Shinya*; Takayanagi, Shuhei*; Ojima, Shoki*; Maeda, Motoyasu*; Origuchi, Naoki*; Ogawa, Arata*; Ikeda, Natsuki*; Aoyagi, Yoshihide*; Kabutoya, Yuito*; et al.
Langmuir, 37(42), p.12313 - 12317, 2021/10
Times Cited Count:1 Percentile:6.39(Chemistry, Multidisciplinary)We investigated the oxidation of oxygen vacancies at the surface of anatase TiO(001) using supersonic seeded molecular beam (SSMB) of oxygen. The oxygen vacancies at the top-surface and sub-surface could be eliminated by the supply of oxygen using an SSMB. These results indicate that the interstitial vacancies can be mostly assigned to oxygen vacancies, which can be effectively eliminated by using an oxygen SSMB. Oxygen vacancies are present on the surface of anatase TiO(001) when it is untreated before transfer to a vacuum chamber. These vacancies, which are stable in the as-grown condition, could also be effectively eliminated using the oxygen SSMB.
Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Takagi, Yasuhiko*; Nakamura, Tomoki*; Hiroi, Takahiro*; Matsuoka, Moe*; et al.
Nature Astronomy (Internet), 5(3), p.246 - 250, 2021/03
Times Cited Count:44 Percentile:97.1(Astronomy & Astrophysics)Here we report observations of Ryugu's subsurface material by the Near-Infrared Spectrometer (NIRS3) on the Hayabusa2 spacecraft. Reflectance spectra of excavated material exhibit a hydroxyl (OH) absorption feature that is slightly stronger and peak-shifted compared with that observed for the surface, indicating that space weathering and/or radiative heating have caused subtle spectral changes in the uppermost surface. However, the strength and shape of the OH feature still suggests that the subsurface material experienced heating above 300 C, similar to the surface. In contrast, thermophysical modeling indicates that radiative heating does not increase the temperature above 200 C at the estimated excavation depth of 1 m, even if the semimajor axis is reduced to 0.344 au. This supports the hypothesis that primary thermal alteration occurred due to radiogenic and/or impact heating on Ryugu's parent body.
Abe, Toru*; Hirano, Fumio; Mihara, Morihiro; Honda, Akira
Genshiryoku Bakkuendo Kenkyu (CD-ROM), 27(1), p.3 - 11, 2020/06
Degradation of TRU waste in a geological disposal facility may cause the formation of a nitrate plume. A Nitrate Evolution model due to mineral reactions, microbial activity, and metal corrosiON (NEON) has therefore been developed to evaluate the safety case for geological disposal of TRU waste. Small scale laboratory experiments can be reproduced satisfactorily, however, it is necessary to demonstrate the applicability of the NEON model on scales relevant to the geological disposal of TRU waste. In the current study, an industrial analogue of a nitrate plume from the pollution of groundwater from nitrate fertilizers used on Ikuchi Island, Japan was selected to test the applicability of the NEON model. Concentration profiles of nitrate ions in the groundwater were successfully reproduced over the hundreds of meters scale demonstrating the applicability of the NEON model in evaluating the chemical behavior of a nitrate plume derived from the geological disposal of TRU waste.
Myagmarjav, O.; Iwatsuki, Jin; Tanaka, Nobuyuki; Noguchi, Hiroki; Kamiji, Yu; Ioka, Ikuo; Kubo, Shinji; Nomura, Mikihiro*; Yamaki, Tetsuya*; Sawada, Shinichi*; et al.
International Journal of Hydrogen Energy, 44(35), p.19141 - 19152, 2019/07
Times Cited Count:16 Percentile:48.9(Chemistry, Physical)Nakajima, Kenji; Kawakita, Yukinobu; Ito, Shinichi*; Abe, Jun*; Aizawa, Kazuya; Aoki, Hiroyuki; Endo, Hitoshi*; Fujita, Masaki*; Funakoshi, Kenichi*; Gong, W.*; et al.
Quantum Beam Science (Internet), 1(3), p.9_1 - 9_59, 2017/12
The neutron instruments suite, installed at the spallation neutron source of the Materials and Life Science Experimental Facility (MLF) at the Japan Proton Accelerator Research Complex (J-PARC), is reviewed. MLF has 23 neutron beam ports and 21 instruments are in operation for user programs or are under commissioning. A unique and challenging instrumental suite in MLF has been realized via combination of a high-performance neutron source, optimized for neutron scattering, and unique instruments using cutting-edge technologies. All instruments are/will serve in world-leading investigations in a broad range of fields, from fundamental physics to industrial applications. In this review, overviews, characteristic features, and typical applications of the individual instruments are mentioned.
Oshima, Takeshi; Yokoseki, Takashi; Murata, Koichi; Matsuda, Takuma; Mitomo, Satoshi; Abe, Hiroshi; Makino, Takahiro; Onoda, Shinobu; Hijikata, Yasuto*; Tanaka, Yuki*; et al.
Japanese Journal of Applied Physics, 55(1S), p.01AD01_1 - 01AD01_4, 2016/01
Times Cited Count:14 Percentile:54.58(Physics, Applied)Yokoseki, Takashi; Abe, Hiroshi; Makino, Takahiro; Onoda, Shinobu; Tanaka, Yuki*; Kandori, Mikio*; Yoshie, Toru*; Hijikata, Yasuto*; Oshima, Takeshi
Materials Science Forum, 821-823, p.705 - 708, 2015/07
Yamaki, Tetsuya; Ito, Hisayoshi; Matsubara, Masakazu*; Abe, Hiroaki*; Asai, Keisuke*
Transactions of the Materials Research Society of Japan, 28(3), p.879 - 882, 2003/10
Titanium oxide nanoparticles were formed by pulsed laser ablation of a TiO rutile pellet with a KrF excimer laser ( = 248 nm). The ablation was performed in atmospheres of Ar and O at total pressures ranging from 0.2 and 10 Torr. At a higher pressure than 1 Torr, Ti in the nanoparticles had an oxidation state of 4+ to form TiO. According to the X-ray diffraction analyses, the nanopartiles were found to contain both the anatase and rutile phases, which crystallized through extremely energetic, non-equilibrium reactions in an ablation plume. In contrast, at pressures of 0.2 and 0.5 Torr, the nanoparticles were composed of dominant TiO with a small amount of a less oxidized phase such as TiO. The important result is that the XRD patterns of the samples prepared at 1 and 5 Torr showed the different anatase-to-rutile ratio of the peak intensities. This indicates that the weight fraction of the rutile/anatase crystalline phases can be controlled by the ambient gas pressure.
Matsubara, Masakazu*; Yamaki, Tetsuya; Ito, Hisayoshi; Abe, Hiroaki*; Asai, Keisuke*
Japanese Journal of Applied Physics, Part 2, 42(5A), p.L479 - L481, 2003/05
Pulsed laser ablation with a KrF excimer laser was used to prepare fine particles of titanium dioxide (TiO). The ablation in an atmosphere of Ar and O (5:5) at total pressures of 1 Torr led to the formation of TiO nanoparticles composed of anatase and rutile structures without any suboxides. The weight fraction of the rutile/anatase crystalline phases was controlled by the pressure of the Ar/O gas. The TiO nanoparticles had a spherical shape and their size, ranging from 10 and 14 nm, also appeared to be dependent on the ambient pressure.
; ; ; Nakamura, H.; ; ; ; ; ; *; et al.
JAERI-M 82-174, 309 Pages, 1982/11
no abstracts in English
; ; ; ; ; *; *; *; *
Shinku, 20(4), p.136 - 141, 1977/04
no abstracts in English
Sumi, Mika; Takamatsu, Mai*; Ebisawa, Noriyuki; Abe, Katsuo; Kageyama, Tomio; Chiba, Masahiko; Nakazawa, Hiroaki; Suzuki, Toru; Katchi, Tomokazu*; Kushigeta, Yoshiyuki*; et al.
no journal, ,
Standard material which called Large Size Dried (LSD) spikes is required for Plutonium and Uranium measurement by Isotope Dilution Mass Spectrometry (IDMS). Collaboration work between JAEA and JNFL is performed to validate efficient use of standard material (primary) and to evaluate the effectivity of the Pu which separated and purified from MOX stored at JAEA. According to the presentation "Preparation and evaluation of reference materials (LSD spikes) (1) Preparation and testing", uncertainty of the actual sample measurements at Rokkasho Reprocessing plant are evaluated with GUM. Also, the effectivity of the half sized LSD spikes from generally used at JAEA and LSD spikes which prepared from Pu purified from MOX at JAEA are statistically evaluated and validated.
Horikawa, Daiki*; Kunieda, Takekazu*; Abe, Wataru*; Koshikawa, Shigeyuki*; Nakahara, Yuichi*; Watanabe, Masahiko*; Iwata, Kenichi*; Sakashita, Tetsuya; Hamada, Nobuyuki*; Higashi, Seigo*; et al.
no journal, ,
We report the first successful rearing of the herbivorous tardigrade, , by supplying a green alga as a food. The reared individuals of this species had an anhydrobiotic capacity throughout their life cycle, from eggs, to juveniles, and to adults. Reared adults, while in an anhydrobiotic state, were tolerant to temperatures -196C and 100C. Furthermore, they were shown to be tolerant to the exposure to 99.8% acetonitrile, 1 GPa of hydrostatic pressure, or 5000 Gy of He ion radiation. We will report the details of these results, along with the description of their life history. Due to the observed tolerance to such extreme environmental conditions, we propose R. varieornatus to be included as a suitable model for astrobiological studies of multicellular organisms.
Katchi, Tomokazu*; Kushigeta, Yoshiyuki*; Murakami, Yoshiki*; Hishi, Tomoyuki*; Ai, Hironobu*; Takamatsu, Mai*; Ebisawa, Noriyuki; Sumi, Mika; Abe, Katsuo; Kageyama, Tomio; et al.
no journal, ,
Standard material which called Large Size Dried (LSD) spikes is required for Plutonium and Uranium measurement by Isotope Dilution Mass Spectrometry (IDMS). Collaboration work between JAEA and JNFL is performed to validate efficient use of standard material (primary) and to evaluate the effectivity of the Pu which separated and purified from MOX stored at JAEA. Preparation of the LSD spikes at JAEA and evaluation with actual samples with remote operation systems at JNFL will be presented.
Toda, Yoshiaki*; Hara, Toru*; Abe, Fujio*; Kimura, Akihiko*; Kasada, Ryuta*; Inoue, Masaki; Okuda, Takanari*; Onuki, Somei*; Ukai, Shigeharu*; Fujisawa, Toshiharu*
no journal, ,
no abstracts in English
Hattori, Takanori; Arima, Hiroshi; Abe, Jun; Sano, Asami; Utsumi, Wataru; Nagai, Takaya*; Kagi, Hiroyuki*; Iitaka, Toshiaki*; Katayama, Yoshinori; Inoue, Toru*; et al.
no journal, ,
The new beamline dedicated to high-pressure studies, PLANET is now being constructed at BL11 in MLF/J-PARC. The design concept and the current construction state are introduced. The most characteristic feature of this beamline is a huge press with the maximum load of 1500 ton. The coupling this with the state of the art neutron techniques reveals hydrogen positions and its effects on the physical properties of materials and minerals at tens of gigapascals and a few thousand Kelvins. This opens the door to explore deep interior of the hydrous Earth and Planets.
Kagi, Hiroyuki*; Hattori, Takanori; Arima, Hiroshi; Abe, Jun; Sano, Asami; Katayama, Yoshinori; Utsumi, Wataru; Nagai, Takaya*; Inoue, Toru*; Iitaka, Toshiaki*; et al.
no journal, ,
Material and Life Science experimental Facility (MLF) of Japan Proton Accelerator Research Complex (J-PARC) will be one of the most powerful spallation neutron facilities in the world. We are constructing the powder diffractometer dedicated to high-pressure experiments (PLANET) on BL-11. PLANET aims to study structures of hydrogen-bearing materials including dense hydrous minerals of the Earth's deep interior, magmas and light element liquids. The instrument will realize diffraction and radiography experiments for powder and liquid/glass samples at high pressures up to 20 GPa and 2000 K using a large sized multi-anvil hydraulic press.
Hattori, Takanori; Arima, Hiroshi; Sano, Asami; Abe, Jun; Utsumi, Wataru; Nagai, Takaya*; Kagi, Hiroyuki*; Iitaka, Toshiaki*; Katayama, Yoshinori; Inoue, Toru*; et al.
no journal, ,
The high-pressure neutron diffractometer PLANET is the new spectrometer dedicated for high-pressure experiments, which is now being constructed in MLF at J-PARC. The main purpose is to investigate the effect of the water on the Earth's dynamics with the help of the neutron. One of the most characteristic features is the huge 6ram 6axes press with the maximum centric load to 3000 tonf, which enables us to investigate the structure of crystals, liquids and amorphous solids under high-pressure and high-temperature conditions of 30GPa and 2000K. We have installed several optical devices, such as choppers, supermirror guides, 4-dimensional slit, and data acquisition system. On the last March, we received FIRST NEUTRON BEAM. In the talk, we overview the spectrometer and introduce the current construction state.
Arima, Hiroshi; Inoue, Toru*; Abe, Jun; Hattori, Takanori
no journal, ,
Water is one of the important volatile components of the Earth. In low pressure condition, the silicate component bearing liquid and water bearing fluid can be distinguished by the existence of the immiscible region, and hydrous solidus can define clearly. In higher pressure, however, the immiscible region should be disappeared to form miscible region. Main obstacle to observing such a phenomenon is weak contrast difference between magma and fluid. The main advantage of neutron imaging technique is that light elements can be detected in silicate melt such as magma. In this presentation, we report preliminary results of neutron imaging method at BL11 of MLF/J-PARC, which is a neutron beamline dedicated for neutron science under high pressure and high temperature conditions.