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JAEA Reports

A Study on the reprocessing of spent FBR-fuel by ion exchange - II

*; Arai, Tsuyoshi*; Kumagai, Mikio*

JNC TJ9400 2001-012, 92 Pages, 2001/03

JNC-TJ9400-2001-012.pdf:2.64MB

In order to develop an economically efficient wet separation process other than solvent extraction for reprocessing spent FBR-fuel (MOX fuel), we have investigated the possibility of an advanced ion exchange process. Based on the results of fundamental research and the fruits of this research in last year, the proposed FBR-fuel reprocessing process which consists of anion exchange separation and extraction chromatography separation has been studicd quantitatively from the engineering aspect. The plant concept, construction cost, applicability of this process were investigated and preliminarily evaluated. The proposed process was improved to reduce the amounts of operation solution and waste generation, and to enhance the properties of the impregnation adsorbents for MA separation. The mass balance including waste generation in main processes was evaluated. The operation flow sheets for each process were drawn. The main machines were conceptually designed. Furthermore, conceptual design for the reprocessing plant using ion exchange and extraction chromatography was executed and the installation layouts of the machines, equipment and facilities were examined and designed. Based on the research results, the construction cost for the reprocessing plant was estimated and compared with the existing PUREX plant. Finally, the subjects resulted from the introduction of the ion exchange process were extracted and the considerations for solving these subjects were also indicated.

JAEA Reports

A Study on the reprocessing of spent FBR-fuel by ion exchange

*; Arai, Tsuyoshi*; Kumagai, Mikio*

JNC TJ9400 2000-002, 80 Pages, 2000/02

JNC-TJ9400-2000-002.pdf:4.67MB

In order to develop an economically efficient wet separation process other than solvent extraction for reprocessing spent FBR-fuel (MOX fuel), we have investigated the possibility of an advanced ion exchange process. Based on the fundamental research results, we proposed an advanced ion exchange process considering the characteristics of FBR-fuel cycle. The separation system consists of a main separation process using a novel anion exchanger which has a rapid kinetics and two extraction chromatography processes for minor actinides isolation using novel impregnation adsorbents with high selectivity. The chemical flow sheet, mass balance chart, list of main equipment and installation layout of each equipment were estimated and designed for the process in a reprocessing plant with the capacity of 200 tHM/y FBR-fuel. The process was pfeliminarny evalualed from the aspects of economy performance, recovery of potentially useable resources, minimization of environmental risk and proliferation-resistance by comparing with the advanced PUREX process. Furthermore, the subjects which are important for the practical application of the process are also listed.

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