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Nankawa, Takuya; Sekine, Yurina; Matsumura, Daiju; Hiroi, Kosuke; Takata, Shinichi; Kamiya, Yoshimi*; Honda, Takayuki*
Langmuir, 40(11), p.5725 - 5730, 2024/03
Times Cited Count：0The chemical reaction between Fe and lacquer has been used to create the black color lacquer since ancient times. Here, the chemical state of Fe ions in black lacquer was investigated by using X-ray absorption near edge structure (XANES), extended X-ray absorption fine structure (EXAFS), and Fourier transform-infrared (FT-IR) spectroscopy. Fe(II) or Fe(III) was added to the lacquer paste to prepare black lacquer films by air drying, heating, or UV irradiation. The XANES spectral features of all the film samples were similar, meaning that the Fe ions in the samples existed in the trivalent state regardless of the oxidation state of the initially added Fe. The corresponding Fourier transforms of the EXAFS spectra around the Fe K-edge were used to investigate Fe sites in the lacquer films. The spectra of all the film samples were similar shapes, but the peak intensities decreased in the order air dried 
heated UV irradiated films. This result indicates that heating and UV irradiation made the coordination structure of Fe in the lacquer non-uniform, and that heating caused the greatest non-uniformity. The complementary use of XANES, XAFS, and FT-IR spectroscopy is highly effective for non-destructive analysis of black lacquer in precious cultural artifacts.
O/HO vapor generator for contrast-variation neutron scatteringArima-Osonoi, Hiroshi*; Takata, Shinichi; Kasai, Satoshi*; Ouchi, Keiichi*; Morikawa, Toshiaki*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki; Iwase, Hiroki*; Hiroi, Kosuke; et al.
Journal of Applied Crystallography, 56(6), p.1802 - 1812, 2023/12
Times Cited Count：0 Percentile：0.02(Chemistry, Multidisciplinary)Shibata, Motoki*; Nakanishi, Yohei*; Abe, Jun*; Arima, Hiroshi*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; Motokawa, Ryuhei; Kumada, Takayuki; Takata, Shinichi; Yamamoto, Katsuhiro*; et al.
Polymer Journal, 55(11), p.1165 - 1170, 2023/11
Times Cited Count：1 Percentile：51.7(Polymer Science)Sakaguchi, Yoshifumi*; Takata, Shinichi; Kawakita, Yukinobu; Fujimura, Yuki; Kondo, Keietsu
Journal of Physics; Condensed Matter, 35(41), p.415403_1 - 415403_11, 2023/10
Times Cited Count：0 Percentile：0(Physics, Condensed Matter)Hibino, Masayuki*; Takata, Shinichi; Hiroi, Kosuke; Aoki, Hiroyuki; Terashima, Takaya*
Macromolecules, 56(8), p.2955 - 2964, 2023/04
Times Cited Count：0 Percentile：0(Polymer Science)Miura, Daisuke*; Kumada, Takayuki; Sekine, Yurina; Oku, Takayuki; Takata, Shinichi; Hiroi, Kosuke; Iwata, Takahiro*
J-PARC 22-02; J-PARC MLF Annual Report 2021, p.6 - 7, 2022/03
We carried out spin contrast variation neutron powder diffractometry of glutamic acid crystal. The diffraction peak intensities varied as a function of proton polarization. We extracted the structure factor of hydrogen atoms from the variation of peak intensities.
Ohira, Masashi*; Katashima, Takuya*; Naito, Mitsuru*; Aoki, Daisuke*; Yoshikawa, Yusuke*; Iwase, Hiroki*; Takata, Shinichi; Miyata, Kanjiro*; Chung, U.-I.*; Sakai, Takamasa*; et al.
Advanced Materials, 34(13), p.2108818_1 - 2108818_9, 2022/01
Times Cited Count：13 Percentile：89.09(Chemistry, Multidisciplinary)Abe, Hiroshi*; Nemoto, Fumiya*; Hiroi, Kosuke; Oishi, Kazuki*; Takata, Shinichi
Journal of Molecular Liquids, 346, p.117035_1 - 117035_6, 2022/01
Times Cited Count：4 Percentile：61.27(Chemistry, Physical)Nogami, Satoshi*; Kadota, Kazunori*; Uchiyama, Hiromasa*; Arima-Osonoi, Hiroshi*; Iwase, Hiroki*; Tominaga, Taiki*; Yamada, Takeshi*; Takata, Shinichi; Shibayama, Mitsuhiro*; Tozuka, Yuichi*
International Journal of Biological Macromolecules, 190, p.989 - 998, 2021/11
Times Cited Count：6 Percentile：39.73(Biochemistry & Molecular Biology)Ito, Kanae; Yamada, Takeshi*; Shinohara, Akihiro*; Takata, Shinichi; Kawakita, Yukinobu
Journal of Physical Chemistry C, 125(39), p.21645 - 21652, 2021/10
Times Cited Count：4 Percentile：29.65(Chemistry, Physical)Nagao, Michihiro*; Kelley, E. G.*; Faraone, A.*; Saito, Makina*; Yoda, Yoshitaka*; Kurokuzu, Masayuki*; Takata, Shinichi; Seto, Makoto*; Butler, P. D.*
Physical Review Letters, 127(7), p.078102_1 - 078102_7, 2021/08
Times Cited Count：19 Percentile：88.38(Physics, Multidisciplinary)Harada, Masashi*; Takata, Shinichi; Iwase, Hiroki*; Kajiya, Shuji*; Kadoura, Hiroaki*; Kanaya, Toshiji*
ACS Omega (Internet), 6(23), p.15257 - 15263, 2021/06
Times Cited Count：16 Percentile：78.19(Chemistry, Multidisciplinary)Kumar, S.*; Saha, D.*; Takata, Shinichi; Aswal, V. K.*; Seto, Hideki
Applied Physics Letters, 118(15), p.153701_1 - 153701_7, 2021/04
Times Cited Count：6 Percentile：51.66(Physics, Applied)
He spin filter at a pulsed neutron sourceOkudaira, Takuya; Ueda, Yuki; Hiroi, Kosuke; Motokawa, Ryuhei; Inamura, Yasuhiro; Takata, Shinichi; Oku, Takayuki; Suzuki, Junichi*; Takahashi, Shingo*; Endo, Hitoshi*; et al.
Journal of Applied Crystallography, 54(2), p.548 - 556, 2021/04
Times Cited Count：2 Percentile：33.1(Chemistry, Multidisciplinary)Neutron polarization analysis (NPA) for small-angle neutron scattering (SANS) experiments using a pulsed neutron source was successfully achieved by applying a He spin filter as a spin analyzer for the scattered neutrons. The He spin filter covers a sufficient solid angle for performing SANS experiments, and the relaxation time of the He polarization is sufficient for continuous use over a few days, thus reaching the typical duration required for a complete set of SANS experiments. Although accurate evaluation of the incoherent neutron scattering, which is predominantly attributable to hydrogen atoms in samples, is practically difficult using calculations based on the sample elemental composition, the developed NPA approach with consideration of the influence of multiple neutron scattering enabled reliable decomposition of the SANS intensity distribution into the coherent and incoherent scattering components. To date, NPA has not been well established as a standard technique for SANS experiments at pulsed neutron sources. This work is anticipated to greatly contribute to the accurate determination of the coherent neutron scattering component for scatterers in various types of organic sample systems in SANS experiments at J-PARC.
Miura, Daisuke*; Kumada, Takayuki; Sekine, Yurina; Motokawa, Ryuhei; Nakagawa, Hiroshi; Oba, Yojiro; Ohara, Takashi; Takata, Shinichi; Hiroi, Kosuke; Morikawa, Toshiaki*; et al.
Journal of Applied Crystallography, 54(2), p.454 - 460, 2021/04
Times Cited Count：1 Percentile：17.63(Chemistry, Multidisciplinary)We developed a spin-contrast-variation neutron powder diffractometry technique that extracts the structure factor of hydrogen atoms, namely, the contribution of hydrogen atoms to a crystal structure factor. Crystals of L-glutamic acid were dispersed in a dpolystyrene matrix containing 4-methacryloyloxy-2,2,6,6,-tetramethyl-1-piperidinyloxy (TEMPO methacrylate) to polarize their proton spins dynamically. The intensities of the diffraction peaks of the sample changed according to the proton polarization, and the structure factor of the hydrogen atoms was extracted from the proton-polarization dependent intensities. This technique is expected to enable analyses of the structures of hydrogen-containing materials that are difficult to determine with conventional powder diffractometry.
Pallbo, J.*; Imai, Masayuki*; Gentile, L.*; Takata, Shinichi; Olsson, U.*; Sparr, E.*
Frontiers in Physiology (Internet), 11, p.592117_1 - 592117_13, 2020/12
Times Cited Count：6 Percentile：40.86(Physiology)Singh, H.*; Ray, D.*; Kumar, S.*; Takata, Shinichi; Aswal, V. K.*; Seto, Hideki
Physical Review E, 102(6), p.062601_1 - 062601_11, 2020/12
Times Cited Count：10 Percentile：74.2(Physics, Fluids & Plasmas)Shiino, Keisuke*; Otomo, Toshiya; Yamada, Takeshi*; Arima, Hiroshi*; Hiroi, Kosuke; Takata, Shinichi; Miyake, Jumpei*; Miyatake, Kenji*
ACS Applied Polymer Materials (Internet), 2(12), p.5558 - 5565, 2020/11
Times Cited Count：23 Percentile：78.91(Materials Science, Multidisciplinary)Noda, Takashi*; Doi, Yuya*; Ota, Yutaka*; Takata, Shinichi; Takano, Atsushi*; Matsushita, Yushu*
Journal of Polymer Science, 58(15), p.2098 - 2107, 2020/08
Times Cited Count：8 Percentile：37.53(Polymer Science)Gupit, C. I.*; Li, X.*; Maekawa, Ryosuke*; Hasegawa, Naoki*; Iwase, Hiroki*; Takata, Shinichi; Shibayama, Mitsuhiro*
Macromolecules, 53(4), p.1464 - 1473, 2020/02
Times Cited Count：13 Percentile：54.29(Polymer Science)
