Rapid analysis of Sr in cattle bone and tooth samples by inductively coupled plasma mass spectrometry

Koarai, Kazuma; Matsueda, Makoto; Aoki, Jo; Yanagisawa, Kayo*; Terashima, Motoki; Fujiwara, Kenso; Kino, Yasushi*; Oka, Toshitaka; Takahashi, Atsushi*; Suzuki, Toshihiko*; et al.

Journal of Analytical Atomic Spectrometry, 36(8), p.1678 - 1682, 2021/08

https://doi.org/10.1039/D1JA00086A

Rapid analysis of Sr in bone and tooth samples of cattle were achieved by an inductively coupled plasma mass spectrometry (ICP-MS) coupled with mass shift and solid phase extraction techniques. Limit of detection (LOD) in the ICP-MS measurement of 0.1 g samples was lower than that of the radioactivity measurement. Analytical time of the ICP-MS method was reduced from 20 days to 11 hours, compared with the radiometric method. Therefore, the ICP-MS method can be rapid and useful procedure of Sr in small bone and tooth samples derived from terrestrial animals.

Development of solid-phase extraction technique for ICP-MS analysis of iodine-129 in environmental samples; Comparative study of anion-exchange and silver ion-supported resins on isolation of Iodine-129 from interference elements

Aoki, Jo; Matsueda, Makoto; Koarai, Kazuma; Terashima, Motoki; Fujiwara, Kenso; Abe, Hironobu

JAEA-Research 2021-002, 20 Pages, 2021/05

JAEA-Research-2021-002.pdf:2.75MB

In order to analyze extremely low concentrations of I in environmental samples by ICP-MS with high sensitivity and rapidity, it is necessary to remove interfering elements (Na, Mg, K, Ca, Mo, Cd and In) using a pretreatment method with Solid-phase Extraction Resin. Anion Exchange Resins with amino groups have been widely used as Solid-phase Extraction Resins, while Ag+ Supported Resins have also been widely used in recent years. It is necessary to optimize the pretreatment technique based on characteristics of the resins. In this study, we compared in terms of separation of I from matrix elements (Na, Mg, K, Ca, Mo, Cd and In) for DOWEX1-X8, AG 1-X8 and CL Resin, and investigated their suitability for ICP-MS analysis of I in environmental samples. The results of adsorption and elution experiments showed that all resins examined uptake and elute I quantitatively. CL Resin showed the highest removal performance of interfering elements, with 3.1% of Mo remaining, but other interfering elements were removed below the detection limit of ICP-MS. However, the Mo remained after the CL Resin treatment could interfere the ICP-MS measurement of I, based on the consideration of ratio of I and Mo. The eluate from CL Resin was treated with a Cation exchange resin (DOWEX 50WX8). As a result, Mo in the eluate was removed by up to 98% and the interference from Mo was reduced to measurable level. Therefore, the pretreatment method using CL Resin in combination with DOWEX 50WX8 is effective for ICP-MS analysis of I at extremely low concentrations (background level).

A Study for a fire gas behavior by using a vertical shaft model (Contract research)

Abe, Hironobu; Hatakeyama, Nobuya; Yamazaki, Masanao; Okuzono, Akihiko*; Sakai, Tetsuo*; Inoue, Masahiro*

JAEA-Research 2009-019, 192 Pages, 2020/02

JAEA-Research-2009-019.pdf:8.07MB

Construction of the underground facility is on going at the Horonobe Underground Research Center, a division of the Japan Atomic Energy Agency. The facility is consisted of three shafts and horizontal drifts at the completion of construction and it is excavated in geological environment with methane gas, so it is important to secure the workers and visitors security in case of fire in the underground. However, it is known that the fire gas such as methane shows a complicated behavior by drift effect and so on and very difficult to predict its behavior, even if under enforced ventilation. In order to construct new prediction method of the fire gas behavior, the model scaled experiments were conducted by using the basic model which consists of shafts and drifts. As a results, fundamental data of the fire gas behavior was grasped and complicated behavior of the fire gas such as three-dimensional backflow and main flow inversion phenomena at the underground structure were ascertained. A new fire gas behavior analysis system has been designed and a prototype system has been programmed which is able to simulate the phenomena noted above. Coupling analysis method is adapted to the system, which consists of mainly one-dimensional ventilation network analysis and simplified computational fluid dynamics program named M-CFD. To minimize calculation time, M-CFD was designed as two-dimensional calculation with simulators multi area analysis system. Using the prototype system, several experimented models representing typical behavior of fire gas have been simulated for model scaled experiments. The system qualitatively reappeared the phenomena such as back flow or main flow inversion, and most of calculations completed in expected time. This indicates appropriateness of the prototype system, but some upgrade such as heat conductivity analysis in the wall rock mass transfer calculation, user friendly interface system and others will be required.

New measurement of the Li(,n)B reaction in a lower-energy region below the Coulomb barrier

Das, S. K.*; Fukuda, Tomokazu*; Mizoi, Yutaka*; Ishiyama, Hironobu*; Miyatake, Hiroari*; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Jeong, S. C.*; Ikezoe, Hiroshi*; Matsuda, Makoto; et al.

Physical Review C, 95(5), p.055805_1 - 055805_4, 2017/05

https://doi.org/10.1103/PhysRevC.95.055805

The Transfer of radiocesium from the bark to the stemflow of chestnut trees () contaminated by radionuclides from the Fukushima Dai-ichi Nuclear Power Plant accident

Sasaki, Yoshito; Abe, Hironobu; Mitachi, Katsuaki; Watanabe, Takayoshi; Ishii, Yasuo; Niizato, Tadafumi

Journal of Environmental Radioactivity, 161, p.58 - 65, 2016/09

AA2015-0311.pdf:1.93MB

https://doi.org/10.1016/j.jenvrad.2015.12.001

We report the behavior of radiocesium on the tree bark and its transfer into the stemflow of chestnut in a forest in Fukushima. The radiocesium concentration is greatest in 2-cm stem, less in 5-mm stem, and least in the leaves. In the 2-cm stem, the radiocesium concentration of the bark was approximately 10 times that of wood. The average Cs-137 concentration of the dissolved fraction of stem flow was about 10 Bq/L; the pH was nearly constant at 5.8. A strong positive correlation was observed between the radiocesium concentration and the electrical conductivity of the dissolved fraction of stemflow; this result suggests that radiocesium and electrolytes have the same elution mechanism from the tree. Some of the particles in the particulate fraction of the stem flow was strongly adsorbed radiocesium.

Direct measurement of nanoscale lithium diffusion in solid battery materials using radioactive tracer of Li

Ishiyama, Hironobu*; Jeong, S.-C.*; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Jung, H. S.*; Miyatake, Hiroari*; Oyaizu, Mitsuhiro*; Osa, Akihiko; Otokawa, Yoshinori; et al.

Nuclear Instruments and Methods in Physics Research B, 376, p.379 - 381, 2016/06

https://doi.org/10.1016/j.nimb.2015.12.036

Nanoscale diffusion tracing by radioactive Li tracer

Ishiyama, Hironobu*; Jeong, S.-C.*; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Miyatake, Hiroari*; Oyaizu, Mitsuhiro*; Katayama, Ichiro*; Osa, Akihiko; Otokawa, Yoshinori; et al.

Japanese Journal of Applied Physics, 53(11), p.110303_1 - 110303_4, 2014/11

https://doi.org/10.7567/JJAP.53.110303

Development of a resonant laser ionization gas cell for high-energy, short-lived nuclei

Sonoda, Tetsu*; Wada, Michiharu*; Tomita, Hideki*; Sakamoto, Chika*; Takatsuka, Takaaki*; Furukawa, Takeshi*; Iimura, Hideki; Ito, Yuta*; Kubo, Toshiyuki*; Matsuo, Yukari*; et al.

Nuclear Instruments and Methods in Physics Research B, 295, p.1 - 10, 2013/01

https://doi.org/10.1016/j.nimb.2012.10.009

no abstracts in English

GEM-MSTPC; An Active-target type detector in low-pressure He/CO mixed gas

Ishiyama, Hironobu*; Yamaguchi, Kanako*; Mizoi, Yutaka*; Watanabe, Yutaka*; Das, S. K.*; Hashimoto, Takashi*; Miyatake, Hiroari*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Oyaizu, Mitsuhiro*; et al.

Journal of Instrumentation (Internet), 7(3), p.C03036_1 - C03036_14, 2012/03

https://doi.org/10.1088/1748-0221/7/03/C03036

We developed an active-target type gas counter operating with low He/CO (10%) detector gas for application in studying low-energy nuclear reactions using radioactive beams. A 400-m-thick gas electron multiplier (THGEM) was used as the proportional counter for high injection rate capability. We examined the gas gain stability and the influence of ion feedback on particle tracks at high beam injection rates of up to 10 particles per second (pps) using a low-energy C beam. From the result of this examination, we found that the THGEM was found to be applicable for our active target at high injection rates of up to 10 pps.

Horonobe Underground Research Laboratory Project; Research and development plan (H22-H26)

Iwatsuki, Teruki; Sato, Haruo; Nohara, Tsuyoshi; Tanai, Kenji; Sugita, Yutaka; Amano, Kenji; Yabuuchi, Satoshi; Oyama, Takuya; Amano, Yuki; Yokota, Hideharu; et al.

JAEA-Research 2011-009, 73 Pages, 2011/06

JAEA-Research-2011-009.pdf:4.41MB

The research and development plan in Horonobe Underground Research Laboratory are summarized according to the 2nd Midterm Plan till 2014 fiscal year of JAEA. In this midterm, galleries and the infrastructures for the research and development up to the depth of 350 m are constructed by Private Financial Initiative (PFI). Additionally Phase 3: Operation phase at the galleries begins in parallel to Phase 2: Construction phase. In these phases various research and development including collaboration with other institutes are conducted at the galleries. Generallic applicable techniques on the subject of the investigation of geological environment, facility construction in deep underground and the reliability of geological deposal are developed during the phase. The feasibility and reliance of various technologies concerning geological disposal is demonstrated by widely opening the outcome to the public in the society.