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Ishii, Yasuo; Toyoshima, Atsushi; Tsukada, Kazuaki; Asai, Masato; Li, Z.*; Nagame, Yuichiro; Miyashita, Sunao*; Mori, Tomotaka*; Suganuma, Hideo*; Haba, Hiromitsu*; et al.
Bulletin of the Chemical Society of Japan, 84(9), p.903 - 911, 2011/09
Times Cited Count：17 Percentile：49.33(Chemistry, Multidisciplinary)The cation-exchange behavior of element 104, rutherfordium (Rf), was investigated together with its lighter group-4 homologues Zr and Hf, and the tetravalent pseudo-homologue Th in HF/HNO
mixed solution. The results demonstrate that distribution coefficients (
) of Rf in HF/0.10 M HNO decrease with increasing concentration of the fluoride ion [F
], indicating the consecutive formation of fluorido complexes of Rf. We also measured the values of Rf and the homologues as a function of the hydrogen ion concentration [H
]. The log values decrease linearly with an increase of log [H] with slopes between -2.1 and -2.5. This indicates that these elements are likely to form the same chemical compounds: mixture of [MF]
and [MF
]
(M = Rf, Zr, Hf and Th) in the studied solution. It is also ascertained that sequence in the fluoride complex formation is Zr 
Hf 
Rf Th.
Ishii, Yasuo; Toyoshima, Atsushi; Tsukada, Kazuaki; Asai, Masato; Tome, Hayato; Nishinaka, Ichiro; Nagame, Yuichiro; Miyashita, Sunao*; Mori, Tomotaka*; Suganuma, Hideo*; et al.
Chemistry Letters, 37(3), p.288 - 289, 2008/03
Times Cited Count：20 Percentile：55.03(Chemistry, Multidisciplinary)We have investigated cation-exchange behavior of Rf together with the lighter homologues of the group-4 elements Zr and Hf, and the tetravalent pseudo-homologue Th, in HF/HNO solution using Automated Ion exchange separation apparatus coupled with the Detection system for Alpha spectroscopy (AIDA). The 
values of Zr, Hf, Th and Rf in HF/0.1 M HNO were decreased with increasing the concentration of the fluoride ion [F], indicating the formation of the fluoride complexes. The sequence of the fluoride complexation strength is Zr Hf Rf Th.
Okuno, Hiroshi; Akiyama, Hideo*; Mochizuki, Hiroki*
Journal of Nuclear Science and Technology, 40(1), p.57 - 60, 2003/01
Times Cited Count：1 Percentile：10.88(Nuclear Science & Technology)Low-level waste (LLW) drums are required to transport as fissile material if the current IAEA's Regulations for the Safe Transport of Radioactive Material are rigorously applied. This problem is a consequence that water contents of concrete in LLW drums contained deuterium (D) in quantities more than 0.1% of fissile material mass, therefore they are not excepted from packages containing fissile material. Consideration of differences in the absorption cross sections of light hydrogen and D shows that the relative increase in the neutron multiplication factor by a presence of D in natural water for hydrogen (H)-moderated systems is not larger than 0.015%. A numerical calculation confirms that the infinite multiplication factor of a mixture of 
U-metal and water in a U/H mass ratio of 5% increases proportionally to the D/H atomic ratio, and that its relative increase is less than 0.03% for the D/H atomic ratio of 0.015%. The limiting fissile-to-H mass ratio of 5% in the exception rule is concluded to be applicable to H-moderated systems including D in natural water.
Matsuda, Hideo*; Omura, Ichiro*; Sakiyama, Yoko*; Urano, Satoshi*; Iesaka, Susumu*; Ohashi, Hiromichi*; Hirao, Toshio; Abe, Hiroshi; Ito, Hisayoshi; Mori, Hidenobu; et al.
JAERI-Review 2002-035, TIARA Annual Report 2001, p.11 - 13, 2002/11
no abstracts in English
Kumamaru, Hiroshige; ; Murata, Hideo; Kukita, Yutaka; Akiyama, Mamoru*; *; *; *; *; *; et al.
Proc. of ASME
JSME 4th Int. Conf. on Nuclear Engineering 1996 (ICONE-4), 1(PART B), p.669 - 674, 1996/00
no abstracts in English
/HF mixed solution, 2Ishii, Yasuo; Tome, Hayato; Toyoshima, Atsushi; Asai, Masato; Nishinaka, Ichiro; Tsukada, Kazuaki; Nagame, Yuichiro; Miyashita, Sunao*; Mori, Tomotaka*; Suganuma, Hideo*; et al.
no journal, ,
Chemical properties of rutherfordium (Rf, the element 104) in HNO/HF mixed solutions have been investigated using cation-exchange chromatography. Distribution coefficients of Rf on the cation-exchange resin as a function of hydrofluoric-acid and nitric-acid concentrations have been measured precisely, and it was found that the strength of the fluoride complex formation of Rf is much weaker than those of lighter group 4 homologs Zr and Hf. The same result was obtained through the anion-exchange chromatography. These results enabled us to quantitatively account for the fluoride complexation of Rf.
/HF solutionIshii, Yasuo; Tome, Hayato; Toyoshima, Atsushi; Asai, Masato; Nishinaka, Ichiro; Tsukada, Kazuaki; Nagame, Yuichiro; Miyashita, Sunao*; Mori, Tomotaka*; Suganuma, Hideo*; et al.
no journal, ,
The cation-exchange behavior of rutherfordium(Rf) in HNO/HF solution has been studied based on an atom-at-a-time scale. In the symposium, we will discuss the fluoride complexation of rutherfordium in comparison with that of Zr, Hf and Th.
Unno, Motoyoshi; Ebashi, Tsutomu; Kawasaki, Takashi; Tomotsune, Yusuke; Akiyama, Kiyomitsu; Ejiri, Hideo; Kobayashi, Hirohide
no journal, ,
no abstracts in English
