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Journal Articles

Magnetization, specific heat, $$^{17}$$O NMR, and $$^{237}$$Np M$"o$ssbauer study of U$$_{0.15}$$Np$$_{0.85}$$O$$_2$$

Martel, L.*; Hen, A.*; Tokunaga, Yo; Kinnart, F.*; Magnani, N.*; Colineau, E.*; Griveau, J.-C.*; Caciuffo, R.*

Physical Review B, 98(1), p.014410_1 - 014410_8, 2018/07

 Times Cited Count:5 Percentile:25.82(Materials Science, Multidisciplinary)

We report a study of the magnetic and electronic properties of the U$$_{0.15}$$Np$$_{0.85}$$O$$_2$$ solid solution, based on dc- and ac- magnetisation, $$^{237}$$Np M$"o$ssbauer spectroscopy, $$^{17}$$O Nuclear Magnetic Resonance (NMR), and specific heat measurements. The compound orders antiferromagnetically at T$$_N$$ = 17 K. The different techniques reveal the complexity of this system with:(1) a spatial distribution of ordered moments, (2) a small Np ordered moment, and (3) an additional specific heat anomaly at 7.4 K, with a residual value at very low temperature and a reduced magnetic entropy. The results are compared to the end-members of the series, UO$$_2$$ and NpO$$_2$$, as well as to the other solid solutions previously reported in this system. We discuss how the properties of U$$_{0.15}$$Np$$_{0.85}$$O$$_2$$ add new input to the trend previously reported for the series, in view of the models that have been previously proposed.

Journal Articles

Energy scale of the electron-boson spectral function and superconductivity in NpPd$$_5$$Al$$_2$$

Ummarino, G. A.*; Caciuffo, R.*; Chudo, Hiroyuki; Kambe, Shinsaku

Physical Review B, 82(10), p.104510_1 - 104510_7, 2010/09

 Times Cited Count:4 Percentile:21.96(Materials Science, Multidisciplinary)

The energy scale $$Omega_{0}$$ of the electron-boson spectral function in the heavy-fermion, $$d$$-wave superconductor NpPd$$_5$$Al$$_2$$ is predicted on the basis of Eliashberg theory calculations. Assuming a spectral function shape typical for antiferromagnetic spin fluctuations, and imposing constraints provided by the experimental values for the critical temperature and the low-temperature energy gap, one obtains values of $$Omega_{0}$$ of about 2-2.5 meV, slightly dependent from the strength of the Coulomb pseudopotential. These values are in excellent agreement with the characteristic magnetic fluctuations energy estimated from NMR measurements of the nuclear-spin-lattice relaxation time at the Al site. The calculated temperature dependence of the upper critical field, the local spin susceptibility, and the nuclear spin-lattice relaxation rate is also in good agreement with available experimental data.

Journal Articles

Resonant X-ray scattering study of NpRhGa$$_5$$ and NpCoGa$$_5$$

Detlefs, B.*; Wilkins, S. B.*; Caciuffo, R.*; Paix$~a$o, J. A.*; Kaneko, Koji; Honda, Fuminori*; Metoki, Naoto; Bernhoeft, N.*; Rebizant, J.*; Lander, G. H.*

Physical Review B, 77(2), p.024425_1 - 024425_10, 2008/01

 Times Cited Count:17 Percentile:58.3(Materials Science, Multidisciplinary)

We report a resonant X-ray scattering study of the antiferromagnetic neptunium compounds NpCoGa$$_5$$ and NpRhGa$$_5$$. Large resonant signals of magnetic dipole character are observed below the N$'e$el temperatures. The signals at the Np edges confirm the behavior determined previously from neutron diffraction. On application of a magnetic field of 9 T along the [010] direction in NpRhGa$$_5$$, we observe a change in the population of different [110]-type domains. We also observe a magnetic dipole signal at the Ga $$K$$ edge, similarly to the reported UGa$$_3$$ case, that can be interpreted within a semilocalized model as an orbital polarization of the Ga 4$$p$$ states induced via strong hybridization with the Np 5$$f$$ valence band. Quantitative analysis of the signal shows that the Ga dipole on the two different Ga sites follows closely the Np magnetic moment reorientation in NpRhGa$$_5$$. The ratios of the signals on the two inequivalent Ga sites are not the same for the different compounds.

Oral presentation

Resonant X-ray scattering in NpTGa$$_5$$ (T=Co and Rh); Experiment and theory

Janousova, B.*; Di Matteo, S.*; Wilkins, S. B.*; Caciuffo, R.*; Paix$~a$o, J. A.*; Honda, Fuminori; Metoki, Naoto; Colineau, E.*; Lander, G. H.

no journal, , 

no abstracts in English

Oral presentation

Towards f-electron single-molecule magnets; Physical properties of a Tm-based "double decker" complex

Magnani, N.*; Caciuffo, R.*; Colineau, E.*; Wastin, F.*; Amoretti, G.*; Carretta, S.*; Santini, P.*; Baraldi, A.*; Capelletti, R.*; Adroja, D. T.*; et al.

no journal, , 

no abstracts in English

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