Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Sekine, Yurina; Nankawa, Takuya; Yamada, Teppei*; Matsumura, Daiju; Nemoto, Yoshihiro*; Takeguchi, Masaki*; Sugita, Tsuyoshi; Shimoyama, Iwao; Kozai, Naofumi; Morooka, Satoshi
Journal of Environmental Chemical Engineering, 9(2), p.105114_1 - 105114_12, 2021/04
Times Cited Count：10 Percentile：49.28(Engineering, Environmental)Remediating toxic ion contamination is crucial for protecting human health and the environment. This study aimed to provide a powerful strategy for effectively utilizing bone waste from the food production and preparation industries for removal of toxic ions. Here, we show that immersing pig bone in NaHCO
solution produced a carbonated nanohydroxyapatites (C-NHAP). The C-NHAP exhibited high adsorptivity for Sr
, Cd, Pb, and Cu. The strontium adsorptivity was about 250 and 4,500 times higher than that of normal bone and synthetic HAP, respectively. The C-NHAP is an eco-friendly, high-performance material that is simple to prepare and should be useful for tackling problems of food waste disposal and environmental pollution.
Cs solid-state NMR and density functional theory calculationsOkubo, Takahiro*; Okamoto, Takuya*; Kawamura, Katsuyuki*; Gu
gan, R.*; Deguchi, Kenzo*; Oki, Shinobu*; Shimizu, Tadashi*; Tachi, Yukio; Iwadate, Yasuhiko*
Journal of Physical Chemistry A, 122(48), p.9326 - 9337, 2018/12
Times Cited Count：13 Percentile：60.51(Chemistry, Physical)The structures of Cs adsorption on montmorillonite were investigated by the nuclear magnetic resonance (NMR) spectroscopy. The NMR spectra of Cs adsorbed on montmorillonite samples were measured under different Cs contents and relative humidity levels. NMR parameters were evaluated by the first principle calculations in order to identify the relationship between adsorbed Cs structures and NMR parameters. The comparisons between experimental and theoretical NMR spectra revealed that Cs is preferentially adsorbed at sites near Al for low Cs substituted montmorillonites, and that non-hydrated Cs present in partially Cs substituted samples, even after being hydrated under high relative humidity.
Deguchi, Yoshihiro*; Muranaka, Ryota*; Kamimoto, Takahiro*; Takagi, Taku*; Kikuchi, Shin; Kurihara, Akikazu
Applied Thermal Engineering, 114, p.1319 - 1324, 2017/03
Times Cited Count：2 Percentile：12.87(Thermodynamics)The purpose of this study aims to clarify the gas phase sodium-water reaction path and reaction products quantitatively. The counter-flow diffusion experiment device was employed to analyze the reaction path and reaction products using laser diagnostics. The main product of sodium-water reaction was determined to be NaOH and the sodium oxide was not notably measured compared with NaOH.
Deguchi, Yoshihiro*; Muranaka, Ryota*; Kamimoto, Takahiro*; Takagi, Taku*; Kikuchi, Shin; Kurihara, Akikazu
Proceedings of 3rd International Workshop on Heat Transfer Advances for Energy Conservation and Pollution Control (IWHT 2015) (CD-ROM), 6 Pages, 2015/10
The purpose of this study aims to clarify the gas phase sodium-water reaction path and reaction products quantitatively. The counter-flow diffusion experiment device was employed to analyze the reaction path and reaction products using laser diagnostics. The main product of sodium-water reaction was determined to be NaOH and the sodium oxide was not notably measured compared with NaOH.
Kariya, Tsuyoshi*; Minami, Ryutaro*; Imai, Tsuyoshi*; Eguchi, Taku*; Sakamoto, Keishi; Mitsunaka, Yoshika*; Numakura, Tomoharu*; Endo, Yoichi*
Plasma and Fusion Research (Internet), 8, p.1205107_1 - 1205107_2, 2013/10
Minami, Ryutaro*; Kariya, Tsuyoshi*; Imai, Tsuyoshi*; Numakura, Tomoharu*; Endo, Yoichi*; Nakabayashi, Hidetaka*; Eguchi, Taku*; Shimozuma, Takashi*; Kubo, Shin*; Yoshimura, Yasuo*; et al.
Nuclear Fusion, 53(6), p.063003_1 - 063003_7, 2013/06
Minami, Ryutaro*; Kariya, Tsuyoshi*; Imai, Tsuyoshi*; Numakura, Tomoharu*; Endo, Yoichi*; Nakabayashi, Hidetaka*; Eguchi, Taku*; Shimozuma, Takashi*; Kubo, Shin*; Yoshimura, Yasuo*; et al.
Nuclear Fusion, 53(6), p.063003_1 - 063003_7, 2013/06
Times Cited Count：12 Percentile：47.42(Physics, Fluids & Plasmas)Hosoi, Takuji*; Kirino, Takashi*; Uenishi, Yusuke*; Ikeguchi, Daisuke*; Chanthaphan, A.*; Yoshigoe, Akitaka; Teraoka, Yuden; Mitani, Shuhei*; Nakano, Yuki*; Nakamura, Takashi*; et al.
Workshop digest of 2012 Asia-Pacific Workshop on Fundamentals and Applications of Advanced Semiconductor Devices (AWAD 2012), p.22 - 25, 2012/06
/4H-SiC interfaceHosoi, Takuji*; Kirino, Takashi*; Chanthaphan, A.*; Uenishi, Yusuke*; Ikeguchi, Daisuke*; Yoshigoe, Akitaka; Teraoka, Yuden; Mitani, Shuhei*; Nakano, Yuki*; Nakamura, Takashi*; et al.
Materials Science Forum, 717-720, p.721 - 724, 2012/05
Times Cited Count：5 Percentile：91.62(Materials Science, Multidisciplinary)Watanabe, Heiji*; Hosoi, Takuji*; Kirino, Takashi*; Uenishi, Yusuke*; Chanthaphan, A.*; Ikeguchi, Daisuke*; Yoshigoe, Akitaka; Teraoka, Yuden; Mitani, Shuhei*; Nakano, Yuki*; et al.
ECS Transactions, 41(3), p.77 - 90, 2011/00
Times Cited Count：5 Percentile：90.81(Electrochemistry)Yura, Kei; Shionyu, Masafumi*; Hagino, Kei*; Hijikata, Atsushi*; Hirashima, Yoshinori*; Nakahara, Taku*; Eguchi, Tatsuya*; Shinoda, Kazuki*; Yamaguchi, Akihiro*; Takahashi, Kenichi*; et al.
Gene, 380(2), p.63 - 71, 2006/10
Times Cited Count：55 Percentile：72.3(Genetics & Heredity)Alternative splicing is a molecular mechanism that produces multiple proteins from a single gene, and is thought to produce variety in proteins translated from a limited number of genes. Here we analyzed how alternative splicing produced variety in protein structure and function, by using human full-length cDNAs, on the assumption that all of the alternatively spliced mRNAs were translated to proteins. We found that the length of alternatively spliced amino acid sequences, in most cases, fell into a size shorter than that of average protein domain. We evaluated comprehensively the presumptive three-dimensional structures of the alternatively spliced products to assess the impact of alternative splicing on gene function. We found that more than half of the products encoded proteins which were involved in signal transduction, transcription and translation, and more than half of alternatively spliced regions comprised interaction sites between proteins and their binding partners, including substrates, DNA/RNA, and other proteins. Intriguingly, 67% of the alternatively spliced isoforms showed significant alterations to regions of the protein structural core, which likely resulted in large conformational change. Based on those findings, we speculate that there are a large number of cases that alternative splicing modulates protein networks through significant alteration in protein conformation.
Kojima, Takuji; Tanaka, Ryuichi; Morita, Yosuke; Seguchi, Tadao; Yoshida, Kenzo
JAERI-M 86-137, 21 Pages, 1986/09
no abstracts in English
/SiC interface structure and conduction band offsetKirino, Takashi*; Chanthaphan, A.*; Ikeguchi, Daisuke*; Yoshigoe, Akitaka; Teraoka, Yuden; Mitani, Shuhei*; Nakano, Yuki*; Nakamura, Takashi*; Hosoi, Takuji*; Shimura, Takayoshi*; et al.
no journal, ,
In order to investigate correlation between a conduction band offset and the interface characteristics of SiO/SiC structure, synchrotron radiation XPS have been conducted for the SiO/SiC structure formed by sputtering and thermal oxidation. In the SiO/SiC interface formed by sputtering, higher oxidation number components decreased and the total amount of suboxides was small comparing with thermal oxidation. Furthermore, an SiO photoemission peak of the sputtering sample was shifted to higher binding energy side by 0.24 eV, and a conduction band offset was smaller comparing with the thermal oxide sample. The SiO band gap was evaluated from an O1s energy loss spectrum, and the valence band offset was also obtained from a valence band photoemission spectrum. The conduction band offset for the sputtering sample was smaller by 0.35 eV comparing with the thermal oxide sample.
/4H-SiC interface passivalon on energy band alignment between SiO and 4H-SiCHosoi, Takuji*; Kirino, Takashi*; Chanthaphan, A.*; Ikeguchi, Daisuke*; Yoshigoe, Akitaka; Teraoka, Yuden; Mitani, Shuhei*; Nakano, Yuki*; Nakamura, Takashi*; Shimura, Takayoshi*; et al.
no journal, ,
A balence band off-set of SiO/SiC interface, which affects the reliability of SiC-MOS devises, was evaluated by synchrotron radiation photoemission spectroscopy. An SiO film formed by sputtering deposition showed smaller off-set than that of thermal oxide film. Interface defects, originate in carbon impurities, and balence band off-set of thermal SiO/SiC interface were decreased by annealing in the high temperature hydrogen gas.
Hosoi, Takuji*; Kirino, Takashi*; Chanthaphan, A.*; Ikeguchi, Daisuke*; Yoshigoe, Akitaka; Teraoka, Yuden; Mitani, Shuhei*; Nakano, Yuki*; Nakamura, Takashi*; Shimura, Takayoshi*; et al.
no journal, ,
no abstracts in English
Cs solid state NMR, 2; Cs MAS and 3Q MAS NMROkamoto, Takuya*; Okubo, Takahiro*; Iwadate, Yasuhiko*; Deguchi, Kenzo*; Shimizu, Tadashi*; Oki, Shinobu*; Tachi, Yukio
no journal, ,
The structures of Cs adsorption on montmorillonite were investigated by the nuclear magnetic resonance (NMR) spectroscopy. The NMR spectra of Cs adsorbed montmorillonite samples with different Cs contents were collected by Cs Magic Angle Spinning (MAS) NMR and Cs Triple Quantum (3Q) MAS NMR. The adsorbed Cs structures were evaluated based on the correlations between the structural characteristics and the values of the NMR parameters predicted by the first principal calculations.
Okamoto, Takuya*; Okubo, Takahiro*; Iwadate, Yasuhiko*; Deguchi, Kenzo*; Shimizu, Tadashi*; Oki, Shinobu*; Tachi, Yukio
no journal, ,
The structures of Cs adsorbed on montmorillonite were investigated by Cs Magic Angle Spinning (MAS) NMR spectroscopy. The NMR spectra of Cs adsorbed on montmorillonite samples were measured under different relative humidity levels and were analyzed to evaluate the change in the structure of hydrated Cs sorbed on montmorillonite.
Kasatsugi, Takumi*; Eguchi, Yuto*; Fujitani, Jun*; Takesue, Naohisa*; Saito, Junichi
no journal, ,
no abstracts in English
Eguchi, Yuto*; Kasatsugi, Takumi*; Fujitani, Jun*; Takesue, Naohisa*; Saito, Junichi
no journal, ,
no abstracts in English
Wakaida, Ikuo; Oba, Hironori; Akaoka, Katsuaki; Karino, Takahiro; Sakamoto, Kan*; Nakanishi, Ryuzo*; Kashiwakura, Shunsuke*; Taira, Takunori*; Ikeda, Yuji*; Deguchi, Yoshihiro*
no journal, ,
We are developing remote in-situ analysis by laser induced breakdown spectroscopy (LIBS) for simple in-situ screening analysis of fuel debris in the decommissioning of the Fukushima Daiichi Nuclear Power Station. For various application scenarios, microchip laser based LIBS for ultra-long distance analysis, microwave assisted LIBS for signal enhancement, and long/short double pulse laser LIBS for water-containing samples are developing as the fiber-optic LIBS system. To have the reliability, valuation with nuclear fuel materials and spent fuel, and radiation resistance test by 
Co irradiation will be planed. As a challenging trial, a development of Machine learning technique has introduced for automatically analysis of LIBS spectra.
