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Journal Articles

Reduction and unusual recovery in the reversible hydrogen storage capacity of V$$_{1-x}$$Ti$$_x$$ during hydrogen cycling

Kim, H.*; Sakaki, Koji*; Saita, Itoko*; Enoki, Hirotoshi*; Noguchi, Kazuo*; Machida, Akihiko; Watanuki, Tetsu; Nakamura, Yumiko*

International Journal of Hydrogen Energy, 39(20), p.10546 - 10551, 2014/07

 Times Cited Count:13 Percentile:32.57(Chemistry, Physical)

The effect of the vanadium content on the cyclic stability of V-Ti binary alloys was investigated. V$$_{1-x}$$Ti$$_x$$, $$x=$$ 0.2 and 0.5 samples were hydrogenated and dehydrogenated at 410 K and 553 K respectively, for more than 100 times. During hydrogen cycling, reduction in the reversible hydrogen storage capacity was clearly observed from both samples. In addition, the shape of the pressure-composition-isotherm curves was significantly altered over the testing cycle period; the absorption and desorption plateaus got markedly inclined and the hysteresis became evidently smaller. We found that even after the hydrogen storage capacity of V$$_{1-x}$$Ti$$_x$$ was significantly reduced, at low enough temperature V$$_{1-x}$$Ti$$_x$$ was able to absorb hydrogen as much as it did at the first cycle.

Journal Articles

In situ synchrotron $$^{57}$$Fe M$"o$ssbauer spectroscopy of RFe$$_{2}$$ (R = Y, Gd) hydrides synthesized under ultra-high-pressure hydrogen

Mitsui, Takaya; Masuda, Ryo*; Seto, Makoto; Hirao, Naohisa*; Matsuoka, Takehiro*; Nakamura, Yumiko*; Sakaki, Koji*; Enoki, Hirotoshi*

Journal of Alloys and Compounds, 580(Suppl.1), p.S264 - S267, 2013/12

 Times Cited Count:8 Percentile:42.91(Chemistry, Physical)

Journal Articles

An in situ M$"{o}$ssbauer study using synchrotron radiation

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Sakaki, Koji*; Enoki, Hirotoshi*; Nakamura, Yumiko*; Seto, Makoto

Hyperfine Interactions, 204(1-3), p.139 - 142, 2012/03

 Times Cited Count:2 Percentile:76.82

We have been developing a system for in situ M$"{o}$ssbauer studies using synchrotron radiation (SR) to elucidate the mechanism of hydrogenation processes. In the system, samples reacts in an atmosphere chamber and SR-based M$"{o}$ssbauer spectra using variable-frequency nuclear monochromator and energy spectra of inelastic nuclear resonant scattering (NRS) of SR are measured. As a feasibility study, the temperature dependence of the M$"{o}$ssbauer and inelastic NRS spectra of $$^{57}$$Fe in $$c$$-GdFe$$_2$$H$$_3$$ under vacuum were measured. In both spectra, clear differences were observed between 373 K and 573 K. These differences can be interpreted by the change of microscopic environment around Fe at the dehydrogenation. Thus, it is confirmed that this system works well enough to perform the in-situ M$"{o}$ssbauer study on the dehydrogenation of $$c$$-GdFe$$_2$$H$$_3$$.

Oral presentation

M$"{o}$ssbauer study on the hydrides of C15 RFe$$_2$$ (R=Sm,Gd) compounds

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Sakaki, Koji*; Enoki, Hirotoshi*; Nakamura, Yumiko*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Seto, Makoto

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