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Journal Articles

Repeatable photoinduced insulator-to-metal transition in yttrium oxyhydride epitaxial thin films

Komatsu, Yuya*; Shimizu, Ryota*; Sato, Ryuhei*; Wilde, M.*; Nishio, Kazunori*; Katase, Takayoshi*; Matsumura, Daiju; Saito, Hiroyuki*; Miyauchi, Masahiro*; Adelman, J. R.*; et al.

Chemistry of Materials, 34(8), p.3616 - 3623, 2022/04

 Times Cited Count:6 Percentile:73.76(Chemistry, Physical)

Journal Articles

Stress corrosion cracking of copper in swollen bentonite simulating nuclear waste disposal environment

Fujimoto, Shinji*; Tsuchiya, Hiroaki*; Ogawa, Soma*; Iida, Yoshihisa; Taniguchi, Naoki

Materials and Corrosion, 72(1-2), p.333 - 338, 2021/01

 Times Cited Count:2 Percentile:13.1(Materials Science, Multidisciplinary)

The stress corrosion cracking (SCC) of pure copper in bentonite was examined by a slow strain rate test (SSRT). The bentonite was swollen with pure water or aqueous solutions containing NH$$_{3}$$ of 0.05 M and 0.1 M. The thick corrosion films and particulate deposits were formed on copper surface after SSRT. Typical tarnish rupture type SCC occurred on pure copper in swollen bentonite with and without NH$$_{3}$$. Crack propagation rate was enhanced by NH$$_{3}$$. It is confirmed thick oxide layer is formed on copper during plastic deformation which resulting in the tarnish crack type SCC. The many particulate deposits observed on the surface might be formed as a results of rapid dissolution of Cu$$^{2+}$$ to form porous CuO at locallized deformed sites.

JAEA Reports

Investigation of the long term corrosion resistance of the overpack FY2006 (Contract research)

Tachikawa, Hirokazu*; Kawakubo, Fumie*; Shimizu, Akihiko*; Shibata, Toshio*; Azumi, Kazuhisa*; Inoue, Hiroyuki*; Sugimoto, Katsuhisa*; Tsuru, Toru*; Fujimoto, Shinji*

JAEA-Research 2007-086, 74 Pages, 2008/02

JAEA-Research-2007-086.pdf:5.96MB

The corrosion life time of the overpack has been investigated on the basis of experimental data and past research, assuming the ranging geological environment of Japan. However, some subject for the realization of the overpack design, such as the behavior of the overpack under high pH conditions, the behavior of the overpack with change of near-field environmental condition and the corrosion behavior of the welds have still been left. To take into account these conditions, expert committee composed of metal corrosion science experts were established in the Nuclear Safety Research Association and past research outcomes and the theory of safety assessment for long term corrosion resistance were investigated from the view points of metal corrosion science.

Journal Articles

Beam cooling experiment at ion storage ring, S-LSR

Shirai, Toshiyuki*; Tanabe, Mikio*; Soda, Hikaru*; Ikegami, Masahiro*; Fujimoto, Shinji*; Tongu, Hiromu*; Noda, Akira*; Noda, Koji*; Shibuya, Shinji*; Fujimoto, Tetsuya*; et al.

Proceedings of 9th Symposium on Accelerator and Related Technology for Application, p.19 - 22, 2007/06

JAEA Reports

Investigation of the long term corrosion resistance of the overpack (Contract research)

Tachikawa, Hirokazu*; Kawakubo, Fumie*; Shimizu, Akihiko*; Shibata, Toshio*; Sugimoto, Katsuhisa*; Seo, Masahiro*; Tsuru, Toru*; Fujimoto, Shinji*; Inoue, Hiroyuki*

JAEA-Research 2006-058, 80 Pages, 2006/10

JAEA-Research-2006-058.pdf:10.86MB

The Japan Nuclear Cycle Development Institute submitted "Second Progress Report on Research and Development for the Geological Disposal of HLW in Japan" to the Japanese government. This report contains investigations of the corrosion life time of the overpack on the basis of experimental data and past research, assuming the ranging geological environment of Japan. However some subjects, such as the behavior of the overpack under high pH conditions and the behavior of the engineering barrier with change of near-field environmental condition with time for promoting reliability have still been left. To take into account these conditions, expert committee composed of metal corrosion science experts were established in the Nuclear Safety Research Association and past research outcomes and the theory of safety assessment were investigated from the view points of long term stability and corrosion resistance of engineering barrier.

JAEA Reports

Oral presentation

Stress corrosion cracking of Cu via turnish rupture in wet bentonite

Nishioka, Tsuyoshi*; Ogawa, Soma*; Tsuchiya, Hiroaki*; Fujimoto, Shinji*; Taniguchi, Naoki; Dobashi, Ryuta*

no journal, , 

no abstracts in English

Oral presentation

Effect of corrosion products on stress corrosion cracking of Cu in wet bentonite

Nishioka, Tsuyoshi*; Tsuchiya, Hiroaki*; Fujimoto, Shinji*; Tachikawa, Hirokazu*; Taniguchi, Naoki

no journal, , 

no abstracts in English

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