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Mochiku, Takashi*; Hata, Yoshiaki*; Wuernisha, T.*; Igawa, Naoki; Hoshikawa, Akinori*; Ishigaki, Toru*; Yasuoka, Hiroshi*; Hirata, Kazuto*
Physica C, 470(Suppl.1), p.S158 - S159, 2010/12
Times Cited Count:2 Percentile:12.12(Physics, Applied)We have performed neutron powder diffraction of the superconducting FeSrYCuO and the nonsuperconducting FeSrY(CuZn)O samples at low temperature and room temperature to investigate the relation between the crystal structure ant the physical properties. Neutron diffraction study indicates that the magnetic order in this compound is not long-range order because we observed no extra reflection due to the magnetic superstructure. We have observed structural anomaly related to Cu in the superconducting sample around 30 K although we could not observe it in the nonsuperconducting sample. There is possibility of the change of the charge distribution around 30 K in the superconducting sample.
Hwang, J. I.*; Ishida, Yukiaki*; Kobayashi, Masaki*; Hirata, Gen*; Takubo, Ko*; Mizokawa, Takashi*; Fujimori, Atsushi; Okamoto, Jun; Mamiya, Kazutoshi*; Saito, Yuji; et al.
Physical Review B, 72(8), p.085216_1 - 085216_6, 2005/08
Times Cited Count:64 Percentile:87.86(Materials Science, Multidisciplinary)no abstracts in English
Mochiku, Takashi*; Hata, Yoshiaki*; Tuerxun, W.*; Igawa, Naoki; Hoshikawa, Akinori*; Ishigaki, Toru*; Yasuoka, Hiroshi*; Hirata, Kazuto*
no journal, ,
FeSrYCuO is known as the BaYCuO related super conducting compound with the substitution of the Fe for Cu, only when it is annealed in reduced atmosphere and subsequently in oxidized atmosphere. In this study, we have performed neutron powder diffraction of FeSrYCuO to investigate the magnetic disorder-ordering mechanism. No magnetic reflection was observed even below the magnetic transition temperature. This result indicated that the material has not long-range magnetic-ordering.
Mochiku, Takashi*; Hata, Yoshiaki*; Tsuchiya, Yoshinori*; Igawa, Naoki; Hoshikawa, Akinori*; Ishigaki, Toru*; Yasuoka, Hiroshi*; Hirata, Kazuto*
no journal, ,
FeSrYCuO structure exhibits superconductivity around 60 K, when it is properly annealed in N and subsequently in O. In this study, oxygen arrangement in FeSrYCuO system is investigated by the neutron diffraction method. Cu and Fe in the crystal were ordered by annealing around 700C in N due to structure phase transition from the tetragonal to monoclinic phase with a superlattice structure. It was revealed that the FeO tetrahedron was formed and ordered in the crystal while disordered in the original structure without N-annealing. It was observed that the FeO tetrahedron changed to the octahedron by the subsequently annealing in O.
Mochiku, Takashi*; Hata, Yoshiaki*; Tsuchiya, Yoshinori*; Igawa, Naoki; Hoshikawa, Akinori*; Ishigaki, Toru*; Yasuoka, Hiroshi*; Ozawa, Kiyoshi*; Hirata, Kazuto*
no journal, ,
It is well known that the superconductive phase is related with the ordering of Cu and Fe, and with the oxygen deficiency in FeSrYCuO. We investigated the oxygen deficiency of FeSrYCuO by neutron diffraction method. It was shown that non superconductor phase was stable around the oxygen content 6+ = 7 and that the superconductive phase was appeared at 7.6 of the oxygen content 6+.
Mochiku, Takashi*; Hata, Yoshiaki*; Hoshikawa, Akinori*; Iwase, Kenji*; Sulistyanintyas, D.*; Oguro, Hidetoshi*; Ishigaki, Toru*; Igawa, Naoki; Tsuchiya, Yoshinori*; Iwai, Hideo*; et al.
no journal, ,
FeSrYCuO is expected to coexhibit superconductivity and magnetism, which has a tetragonal structure with the oxygen defect and the substitution between Cu and Fe. We have performed neutron powder diffraction of the FeSrYCuO system to investigate the relation between the crystal structure and the physical properties.