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Suzuki, Tomoya*; Otsubo, Ukyo*; Ogata, Takeshi*; Shiwaku, Hideaki; Kobayashi, Toru; Yaita, Tsuyoshi; Matsuoka, Mitsuaki*; Murayama, Norihiro*; Narita, Hirokazu*
Separation and Purification Technology, 308, p.122943_1 - 122943_7, 2023/03
Times Cited Count：2 Percentile：24.43(Engineering, Chemical)HNO
leaching is used in recycling Pd metal from spent products that primarily contain Ag, and most Pd residues are separated from solutions containing Ag(I). However, a small amount of Pd(II) often remains in these Ag(I) solutions. Therefore, the separation of Pd(II) and Ag(I) in HNO solutions is essential to promote efficient Pd recycling. In this study, the separation of Pd(II) and Ag(I) in HNO solutions was investigated using four N-donor-type adsorbents functionalized with amine (R-Amine), iminodiacetic acid (R-IDA), pyridine (R-Py), or bis-picolylamine (R-BPA). R-Amine, R-IDA, and R-Py selectively adsorbed Pd(II) over Ag(I), Cu(II), Ni(II), and Fe(III) from HNO solutions (0.3-7 M), but R-Amine exhibited a lower Pd adsorption efficiency. In contrast, 
90% of Pd(II), Ag(I), and Cu(II) were adsorbed by R-BPA over the entire range of HNO concentrations. Structural analyses of the adsorbed metal ions using Fourier transform infrared spectroscopy and extended X-ray absorption fine structure spectroscopy revealed the separation mechanisms of the N-donor-type adsorbents. Pd(II) adsorption on R-IDA, R-Py, and R-BPA occurred via Pd(II) coordination of the functional groups (iminodiacetic acid, pyridine, and bis-picolylamine, respectively), whereas that on R-Amine occurred via anion exchange of NO
with [Pd(NO)
]
. The coordinative adsorption mechanisms resulted in the higher Pd(II) adsorption behaviors of R-IDA, R-Py, and R-BPA. HCl (5.0 M) and thiourea (0.1 M) eluents desorbed 83% of Pd(II) from R-IDA and 95% from R-Py, respectively. R-Py was the most effective Pd(II) adsorbent based on adsorption selectivity and desorption efficiency.
Ohshima, Hiroyuki; Morishita, Masaki*; Aizawa, Kosuke; Ando, Masanori; Ashida, Takashi; Chikazawa, Yoshitaka; Doda, Norihiro; Enuma, Yasuhiro; Ezure, Toshiki; Fukano, Yoshitaka; et al.
Sodium-cooled Fast Reactors; JSME Series in Thermal and Nuclear Power Generation, Vol.3, 631 Pages, 2022/07
This book is a collection of the past experience of design, construction, and operation of two reactors, the latest knowledge and technology for SFR designs, and the future prospects of SFR development in Japan. It is intended to provide the perspective and the relevant knowledge to enable readers to become more familiar with SFR technology.
Suzuki, Tomoya*; Otsubo, Ukyo*; Ogata, Takeshi*; Shiwaku, Hideaki; Kobayashi, Toru; Yaita, Tsuyoshi; Matsuoka, Mitsuaki*; Murayama, Norihiro*; Narita, Hirokazu*
Dalton Transactions (Internet), 50(33), p.11390 - 11397, 2021/09
Times Cited Count：2 Percentile：21.56(Chemistry, Inorganic & Nuclear)no abstracts in English
Ono, Ayako; Kamide, Hideki; Kobayashi, Jun; Doda, Norihiro; Watanabe, Osamu*
Journal of Nuclear Science and Technology, 53(9), p.1385 - 1396, 2016/09
Times Cited Count：11 Percentile：71.62(Nuclear Science & Technology)Decay heat removal by natural circulation is a significant passive safety measure of a fast reactor against station blackout. The decay heat removal system (DHRS) of the loop type sodium fast reactor being designed in Japan comprises a direct reactor auxiliary cooling system and primary reactor auxiliary cooling system (PRACS). The thermal hydraulic phenomena in the plant under natural circulation conditions need to be understood for establishing a reliable natural circulation driven DHRS. In this study, sodium experiments were conducted using a plant dynamic test loop to understand the thermal-hydraulic phenomena considering natural circulation in the plant. The experiments simulating the scram transient confirmed that PRACS started up smoothly under natural circulation, and the simulated core was stably cooled after the scram. Moreover, the experiments varying the pressure loss coefficients of the loop as the experimental parameters showed robustness of the PRACS.
Saito, Toru; Okubo, Toshikazu*; Izumi, Keisuke*; Okawa, Yoshinao*; Kobayashi, Norihiro*; Yamazaki, Toru; Kawano, Katsumi; Isono, Takaaki
Teion Kogaku, 50(8), p.400 - 408, 2015/08
Aramid fiber-reinforced plastic (AFRP) has been developed as a structural material that has the advantages of light weight and high strength. In this study, tensile tests were carried out to measure the tensile properties of AFRP rod on the market for reinforcement of concrete at room temperature, 77 K and 4.2 K. Especially at cryogenic temperatures, it is difficult to perform a tensile test of the bar because the specimen slips through the jig grip. To prevent the rod from slipping, tensile tests were carried out with some filling conditions. The applicable and appropriate tensile test conditions were established by modifying the jig grip, treating the surface of the rod and using cryogenic epoxy infill to grip the rod. They were more than 1100 MPa. Additionally, the AFRP rod included a temperature dependence in which the Young's modulus increased as the test temperature decreased. It was confirmed that the Young's modulus increased because aramid fiber was more dominant than epoxy.
Tsuda, Shuichi; Yoshida, Tadayoshi; Nakahara, Yukio; Sato, Tetsuro; Seki, Akiyuki; Matsuda, Norihiro; Ando, Masaki; Takemiya, Hiroshi; Tanigaki, Minoru*; Takamiya, Koichi*; et al.
JAEA-Technology 2013-037, 54 Pages, 2013/10
JAEA-Technology-2013-037.pdf:4.94MB
JAEA has been performing dose rate mapping in air using a car-borne survey system KURAMA-II. The KURAMA system is a GPS-aided mobile radiation monitoring system that has been newly developed by Kyoto University Research Reactor Institute in response to the nuclear disaster. The KURAMA system is composed of an energy-compensated scintillation survey meter for measuring dose rate, electric device for controlling both the dose rates and the position data from a GPS module, a computer server for processing and analyzing data from KURAMA, and client PCs for providing for end users. The KURAMA-II has been improved in small-packaging, durability, and automated data transmission. In consequence, dose rate mapping in wide area has become possible in shorter period of time. This report describes the construction of KURAMA-II, its application and a suggestion of how to manage a large number of KURAMA-II.
