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Journal Articles

Nitrogen $$K$$-edge soft X-ray natural circular dichroism of histidine thin film

Izumi, Yudai; Tanaka, Masahito*; Tanigawa, Yoshiaki*; Tanabe, Maiko*; Momoki, Yohei*; Iwai, Miki*; Takenaka, Shun*; Ishiyama, Kimihiro*; Kuroki, Misa*; Muro, Takayuki*; et al.

Journal of Physics; Conference Series, 502(1), p.012038_1 - 012038_4, 2014/04

 Times Cited Count:2 Percentile:72.87

Oral presentation

Nitrogen K-edge soft X-ray natural circular dichroism of histidine thin film

Izumi, Yudai; Tanaka, Masahito*; Tanigawa, Yoshiaki*; Momoki, Yohei*; Iwai, Miki*; Takenaka, Shun*; Ishiyama, Kimihiro*; Kuroki, Misa*; Muro, Takayuki*; Nakagawa, Kazumichi*

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It is unclear whether natural circular dichroism (NCD) originating from core-absorption of atoms located at various sites, as well as next to the asymmetric carbon, in the molecules can be observed selectively. In this study, we measured NCD spectra of an amino acid, histidine (His) which has three nitrogen atoms, thin film in the nitrogen K-edge energy region and confirmed whether we can pick up the NCD signals originating from each nitrogen atom throughout the molecules. NCD peaks assigned to the 1s $$rightarrow$$ $$pi$$$$^{*}$$ of the nitrogen atoms in imidazole ring and the 1s $$rightarrow$$ $$sigma$$$$^{*}$$ transition of the nitrogen atoms in imidazole ring and amino group. Imidazole ring and amino group are positioned at the side chain distant from and next to the asymmetric carbon, respectively. This result suggests that NCD spectroscopy in the soft X-ray region can selectively pick up the information on local structure around specific atoms, regardless of the position of atoms in molecules.

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