Valence control of charge and orbital frustrated system YbFeO with electrochemical Li intercalation

Murase, Satoshi*; Yoshikawa, Yumi*; Fujiwara, Kosuke*; Fukada, Yukimasa*; Teranishi, Takashi*; Kano, Jun*; Fujii, Tatsuo*; Inada, Yasuhiro*; Katayama, Misaki*; Yoshii, Kenji; et al.

Journal of Physics and Chemistry of Solids, 162, p.110468_1 - 110468_6, 2022/03

https://doi.org/10.1016/j.jpcs.2021.110468

We report a trial of the valence control for mixed valence iron triangular oxide YbFeO in order to develop an effective technique to control the frustration of charges in strongly correlated electron systems. The electro-chemical doping of Li into YbFeO was examined on the cell type sample similar to the Li-ion secondary battery cell. Systematic change of the lattice constant, Fe-Fe and Fe-Yb distance were observed with Li doping. Maximum value of the doping was over 300 mAh/g. An EXAFS experiment indicated that Li positioned between Yb octahedron layer (U-layer) and Fe-bipyramidal layer (W-layer). However, detailed change of iron valence state of YbFeO was not clearly observed because of the superimpose of the signal from iron metal nano particles in XANES observation. The results indicate that the electrochemical method might be one of the potential technique to control the frustration of charges in YbFeO.

Carbonated nanohydroxyapatite from bone waste and its potential as a super adsorbent for removal of toxic ions

Sekine, Yurina; Nankawa, Takuya; Yamada, Teppei*; Matsumura, Daiju; Nemoto, Yoshihiro*; Takeguchi, Masaki*; Sugita, Tsuyoshi; Shimoyama, Iwao; Kozai, Naofumi; Morooka, Satoshi

Journal of Environmental Chemical Engineering, 9(2), p.105114_1 - 105114_12, 2021/04

https://doi.org/10.1016/j.jece.2021.105114

Remediating toxic ion contamination is crucial for protecting human health and the environment. This study aimed to provide a powerful strategy for effectively utilizing bone waste from the food production and preparation industries for removal of toxic ions. Here, we show that immersing pig bone in NaHCO solution produced a carbonated nanohydroxyapatites (C-NHAP). The C-NHAP exhibited high adsorptivity for Sr, Cd, Pb, and Cu. The strontium adsorptivity was about 250 and 4,500 times higher than that of normal bone and synthetic HAP, respectively. The C-NHAP is an eco-friendly, high-performance material that is simple to prepare and should be useful for tackling problems of food waste disposal and environmental pollution.

Hydrogen absorption and desorption on Rh nanoparticles revealed by dispersive X-ray absorption fine structure spectroscopy

Song, C.*; Seo, O.*; Matsumura, Daiju; Hiroi, Satoshi*; Cui, Y.-T.*; Kim, J.*; Chen, Y.*; Tayal, A.*; Kusada, Kohei*; Kobayashi, Hirokazu*; et al.

RSC Advances (Internet), 10(34), p.19751 - 19758, 2020/05

https://doi.org/10.1039/D0RA03322G

Local structure study of the iron-based systems of BaFeAs and LiFeAs by X-ray PDF and XAFS analyses

Li, S.*; Toyoda, Masayuki*; Kobayashi, Yoshiaki*; Ito, Masayuki*; Ikeuchi, Kazuhiko*; Yoneda, Yasuhiro; Otani, Akira*; Matsumura, Daiju; Asano, Shun*; Mizuki, Junichiro*; et al.

Physica C, 555, p.45 - 53, 2018/12

https://doi.org/10.1016/j.physc.2018.10.003

-dependence of local distortions in BaFeAs and LiFeAs by X-ray PDF and XAFS methods. Although PDF data exhibit anomaly at the structure transition temperature, EXAFS data exhibit no anomaly. Data supporting the local orthorhombicity at 300 K in the tetragonal phase for BaFeAs. Arguments on the origins of the 4-fold symmetry breaking in the ground average structure of the tetragonal phase.

Countercurrent extraction/stripping experiments using TDdDGA solvent extractant in a centrifugal contactors system

Kibe, Satoshi; Fujisaku, Kazuhiko*; Ambai, Hiromu; Sakamoto, Atsushi; Sano, Yuichi; Takeuchi, Masayuki; Suzuki, Hideya; Tsubata, Yasuhiro; Matsumura, Tatsuro

JAEA-Research 2015-021, 40 Pages, 2016/02

JAEA-Research-2015-021.pdf:2.3MB

The flowsheet with TDdDGA extractant has been being developed for recovering MA from PUREX raffinate. In the previous study, the yields of MA and other elements in countercurrent extraction/stripping experiments using mixer-settlers were not enough for the target and it would be due to the insufficient phase (aqueous/organic) separation. In this study, we carried out countercurrent experiments with surrogate PUREX raffinate using centrifugal contactors which had superior phase separation ability, and evaluated the extraction/stripping behavior of each element. During the operation, abnormal fluid behavior, such as overflow and entrainment, was not observed, and sufficient phase separation was achieved by centrifugal contactors. Extraction behavior of lanthanides was similar to that in mixer-settlers, but their stripping efficiencies decreased. This would be due to shorter residence time in mixing zone.

Single-shot observation of growing streamers using an ultrafast camera

Takahashi, Eiichi*; Kato, Susumu*; Furutani, Hirohide*; Sasaki, Akira; Kishimoto, Yasuaki*; Takada, Kenji*; Matsumura, Satoshi*; Sasaki, Hiroyasu*

Journal of Physics D; Applied Physics, 44(30), p.302001_1 - 302001_4, 2011/08

https://doi.org/10.1088/0022-3727/44/30/302001

A recently developed ultrafast camera that can acquire frames per second was used to investigate positive streamer discharge. It enabled single-shot evaluation of streamer evolution without the need to consider shot-to-shot reproducibility. This camera was used to investigate streamers in argon. Growing branches, the transition when a streamer forms a return stroke, and related phenomena were clearly observed.

Crystal growth procedure of HIV-1 protease-inhibitor KNI-272 complex for neutron structural analysis at 1.9 resolution

Shimizu, Noriko*; Sugiyama, Shigeru*; Maruyama, Mihoko*; Takahashi, Yoshinori*; Adachi, Motoyasu; Tamada, Taro; Hidaka, Koshi*; Hayashi, Yoshio*; Kimura, Toru*; Kiso, Yoshiaki*; et al.

Crystal Growth & Design, 10(7), p.2990 - 2994, 2010/06

https://doi.org/10.1021/cg100054s

We report crystal growth of human immunodeficiency virus 1 protease (HIV PR) in a complex with its inhibitor KNI-272 by six different methods. Comparative analysis indicates that top-seeded solution growth (TSSG) and TSSG combined with the floating and stirring technique (TSSG-FAST) are efficient strategies for rapidly obtaining large single crystals and effectively preventing polycrystallization of the seed crystal. Neutron diffraction analysis confirmed that the crystalobtained by TSSG is a high-quality single crystal. Furthermore, crystal shape was observed to be influenced by solution flow, suggesting that the degree of supersaturation significantly affects the crystal growth direction of HIV PR complex. This finding implies that the shape of the HIV PR complex crystal might be controlled by the solution flow rate.

Temperature control of a cyclotron magnet for stabilization of the JAERI AVF cyclotron beam

Okumura, Susumu; Arakawa, Kazuo; Fukuda, Mitsuhiro; Nakamura, Yoshiteru; Yokota, Wataru; Ishimoto, Takayuki*; Kurashima, Satoshi; Ishibori, Ikuo; Nara, Takayuki; Agematsu, Takashi; et al.

AIP Conference Proceedings 600, p.330 - 332, 2001/00

https://doi.org/10.1063/1.1435267

Frequent corrections of the magnetic field of the JAERI AVF cyclotron were required for keeping a beam current constant during long time operation. We observed correlation between the magnetic field and the temperature of the cyclotron magnet yoke by measuring the magnetic field with an NMR probe and the temperature with platinum resistance thermometers. The unstable phenomenon of a cyclotron beam was induced by temperature change in the magnet yoke caused mainly by thermal conduction from the main coil. To restrain the thermal conduction to the yoke, we have inserted temperature controlled copper plates between the yoke and the main coil. In addition, a temperature control system of the cooling water of the trim coils has been installed independent of the total cooling system for controlling the pole tip temperature. An optimum condition of the temperature control systems for stabilizing the magnetic field has been investigated.

Status report on the JAERI AVF cyclotron system

Nakamura, Yoshiteru; Nara, Takayuki; Agematsu, Takashi; Ishibori, Ikuo; Tamura, Hiroyuki; Kurashima, Satoshi; Yokota, Wataru; Okumura, Susumu; Fukuda, Mitsuhiro; Akaiwa, Katsuhiro*; et al.

Proceedings of 13th Symposium on Accelerator Science and Technology, p.193 - 195, 2001/00

The AVF cyclotron system at JAERI Takasaki has been smoothly operated without serious troubles since the first beam extraction in March, 1991. A yearly operation time is about 3200 hours on an average for recent eight years. In last two years, we performed some improvements and developments as followings: stabilization of the cyclotron beam by addition on an exclusive cooling system, designing and investigation of the flat-top system using fifth-harmonic RF, reconstruction of the rotary shutter for radiation shielding and reinforcement of the magnetic channel and its power supply. Furthermore, the renewal of main circulation pump for cooling system, replacement of shunt resistor in the power supplies and re-alignment of the several magnets along the trunk beam transport line were also carried out.

The New laser-irradiating fiberscope system for hemostasis in the treatment of intracranial lesions

Oka, Kiyoshi; Seki, Takeshi; Akatsu, Tomohiro; Akutsu, Hiroyoshi*; Yamamoto, Tetsuya*; Ihara, Satoshi*; Watanabe, Shinya*; Matsumura, Akira*; Kikuta, Kenichiro*

no journal, , 

For the neuroendoscopic surgery, we are developing a new laser-irradiating fiberscope system. In this system, we use a composite-type optical fiberscope (COF) with 1 mm in outer diameter, which can transmit both laser energy and images for observation simultaneously. The diameter of the cautery laser fiber is 0.1 mm, which is located in the center of the imaging fibers. In this animal experimental study, we conducted the laser-irradiation on the femoral artery and vein of a rat using a usual single core fiber of 0.1 mm in outer diameter and the COF in order to assess the availability of this system. As a result, the blood flow decreased to 1/2 or 1/3 after a cauterization with the single core fiber. Furthermore, in the laser irradiation with the COF, the contraction of the artery with minimal heat damage of adjacent tissue was confirmed. Under direct observation with optical fiberscope, the obliteration of arteries was safely and successfully performed.