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Journal Articles

XAFS study on RbC$$_{60}$$

Kubozono, Yoshihiro*; Mimura, Kazue*; Takabayashi, Yasuhiro*; Maeda, Hironobu*; Kashino, Setsuo*; Emura, Shuichi*; Nishihata, Yasuo; Uruga, Tomoya*; Tanaka, Tsunehiro*; Takahashi, Masao*

Journal of Synchrotron Radiation, 6(Part3), p.564 - 566, 1999/05

The Rb K-edge XAFS spectra for the stable phase of RbC60 which is a quasi one-dimensional polymer were measured in the temperature range from 14.6 to 210 K in order to clarify the origin of the metal-insulator transition around 50 K. The distances and mean-square relative displacements between the Rb atom and the neighboring C atoms determined by XAFS exhibited no change around 50 K, implying that the metal-insulator transition originates from the SDW instablity.

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