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Katabuchi, Tatsuya*; Iwamoto, Osamu; Hori, Junichi*; Kimura, Atsushi; Iwamoto, Nobuyuki; Nakamura, Shoji; Rovira Leveroni, G.; Endo, Shunsuke; Shibahara, Yuji*; Terada, Kazushi*; et al.
EPJ Web of Conferences, 281, p.00014_1 - 00014_4, 2023/03
Rovira Leveroni, G.; Katabuchi, Tatsuya*; Tosaka, Kenichi*; Matsuura, Shota*; Kodama, Yu*; Nakano, Hideto*; Iwamoto, Osamu; Kimura, Atsushi; Nakamura, Shoji; Iwamoto, Nobuyuki
Journal of Nuclear Science and Technology, 59(1), p.110 - 122, 2022/01
Times Cited Count:3 Percentile:44.61(Nuclear Science & Technology)Nakano, Shota*; Konno, Soken*; Tomita, Naoto*; Matsuba, Go*; Tominaga, Taiki*; Takata, Shinichi
Microsystem Technologies, 22(1), p.57 - 63, 2016/01
Times Cited Count:3 Percentile:20.89(Engineering, Electrical & Electronic)We studied the structural formation process of polyacrylonitrile (PAN) gelation in a wide-spatial scale with the small and wide angle neutron scattering in MLF, J-PARC. In micron-scale structure, light transmittance and gelation time were evaluated. The presence of water in the mixed solvent accelerated the phase separation and gelation. In the opaque-gel case, we observed the nanometer-scaled correlation of crystalline cross-linking points and smooth boundary of two micron-scaled phases due to liquid-liquid phase separation. The correlation length is independent of the annealing time, then the cross-linking point exists locally and micro-gelation occurs during phase separation. By contrast, in the transparent-gel case, the correlation length was found to increase throughout the gelation process, and the entanglements of the polymer chains play a role similar to that of cross-linking points.