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Journal Articles

The Effect of alkyl substituents on actinide and lanthanide extraction by diglycolamide compounds

Sasaki, Yuji; Sugo, Yumi; Morita, Keisuke; Nash, K.*; Nash, K. L.*

Solvent Extraction and Ion Exchange, 33(7), p.625 - 641, 2015/10

 Times Cited Count:85 Percentile:91.28(Chemistry, Multidisciplinary)

The effect of alkyl substituents at amidic N atoms in diglycolamide (DGA) compounds on solvent extraction was investigated. The solubility in water and n-dodecane, loading capacity, and distribution ratio (D) of lanthanides and actinides for various DGA compounds were monitored. DGA derivatives with short alkyl chains, for example methyl and ethyl groups, are highly water soluble, while DGA derivatives with long alkyl chains are highly soluble in n-dodecane. The loading capacity correlats with their alkyl chain lengths. The results of masking effect and solubility tests indicate that TEDGA(tetraethyl-diglycolamide) is the best actinide masking agent among the water-soluble DGA derivatives. Actinide extractions were performed using ten DGA compounds in six diluents (nitrobenzene, 1,2-dichloroethane, 1-octanol, chloroform, toluene, and n-dodecane), in which it was observed that DGA derivatives with shorter alkyl chains show higher D values.

Journal Articles

Studies on the uptake and column chromatographyic separation of Eu, Th, U, and Am by tetramethylmalonamide resin

Shimada, Asako; Sulakova, J.*; Yang, Y.*; Alexandratos, S.*; Nash, K. L.*

Solvent Extraction and Ion Exchange, 32(1), p.27 - 43, 2014/01

 Times Cited Count:4 Percentile:16.87(Chemistry, Multidisciplinary)

A tetramethylmalonamide-functionalized resin (TMMA resin) has been developed and investigated for its ability to separate trivalent, tetravalent, and hexavalent actinide elements. As a fundamental study of the extraction mechanism and to design a chromatographic separation scheme, distribution coefficients ($$K$$$$_{d}$$) for partitioning of Eu(III), Th(IV), U(VI), and Am(III) onto the resin from HNO$$_{3}$$, NaNO$$_{3}$$, HCl and NaCl solutions with and without organic acids and potential consistents of low-level radioactve waste have been determined. The competition between metal extraction and HNO$$_{3}$$ extraction was confirmed by the extraction data and FT-IR spectra. Based on these fundamental experimental results, an extractive chromatographic scheme for actinide isolation was designed and demonstrated.

Oral presentation

Extraction properties of tetramethylmalonamide resin for actinide ions

Shimada, Asako; Nash, K.*; Alexandratos, S.*; Yang, Y.*

no journal, , 

Oral presentation

Fundamental investigation of extraction properties of actinides elements with tetramethylmalonamide resin

Shimada, Asako; Nash, K.*; Alexandratos, S.*; Yang, Y.*

no journal, , 

Oral presentation

Elucidation of the extraction mechanism of Tetramethylmalonamide resin and its application to chromatography

Shimada, Asako; Nash, K.*; Kameo, Yutaka; Takahashi, Kuniaki

no journal, , 

no abstracts in English

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