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Kondo, Takafumi*; Asano, Akira*; Yang, J.*; Norizawa, Kimihiro*; Takahashi, Kenji*; Taguchi, Mitsumasa; Nagaishi, Ryuji; Kato, Ryuji*; Yoshida, Yoichi*
Radiation Physics and Chemistry, 78(12), p.1157 - 1160, 2009/12
Times Cited Count:28 Percentile:85.84(Chemistry, Physical)Spectrum and kinetic behavior of solvated electrons (e) in alkyl ammonium ionic liquids (ILs), DEMMA-TFSI, DEMMA-BF4, TMPA-TFSI, PP13-TFSI, P13-TFSI and P14-TFSI were investigated by pulse radiolysis method. The e in the ILs have same absorption peak at 1100 nm with a molar absorption coefficient of 1.5-2.310 dmmolcm. The reaction rate constant of e with Pyrene (Py) was 1.5-3.510 dmmols. These values were about one order of magnitude higher than that of diffusion controlled limit, which was calculated from measured viscosity. The dry electron (e) reacts with Py, and its rate constant in DEMMA-TFSI was 7.910 dmmols, three orders of magnitude higher than that of the e reactions.
Asano, Akira*; Yang, J.*; Kondo, Takafumi*; Norizawa, Kimihiro*; Nagaishi, Ryuji; Takahashi, Kenji*; Yoshida, Yoichi*
Radiation Physics and Chemistry, 77(10-12), p.1244 - 1247, 2008/10
Times Cited Count:25 Percentile:82.53(Chemistry, Physical)The molar extinction coefficient and the radiolytic yield of solvated electrons in ionic liquid of DEMMA-TFSI were estimated respectively to be 2.310 L mol cm and 0.810 mol J by observing the reaction and kinetics of solvated electron and dry electron in the ionic liquid. The solvated electron in DEMMA-TFSI has a very broad absorption spectrum peaking at 1100 nm and reacts slowly with pyrene with a rate constant of 3.510 L mol s, while the dry electron is captured rapidly by pyrene with C value of 0.065 mol L.
Yang, J.*; Kondo, Takafumi*; Norizawa, Kimihiro*; Nagaishi, Ryuji; Taguchi, Mitsumasa; Takahashi, Kenji*; Kato, Ryuji*; Anishchik, S. V.*; Yoshida, Yoichi*; Tagawa, Seiichi*
Radiation Physics and Chemistry, 77(10-12), p.1233 - 1238, 2008/10
Times Cited Count:25 Percentile:82.53(Chemistry, Physical)First observation of picosecond dynamics in ionic liquid of DEMMA-TFSI in radiation chemistry was reported. It is found that the electron produced by ionization is solvated to full solvation in ionic liquid with a rate constant of 3.910 s. The yield of solvated electrons in picosecond time region is 1.210 mol J. The dry electron in ionic liquid reacts rapidly with biphenyl and pyrene with a rate constant of 3.8 to 7.910 L mol s. The geminate ion recombination in n-dodecane and n-hexane was also observed by monitoring the transient absorptions at 523 nm.
Kondo, Takafumi*; Yang, J.*; Kan, Koichi*; Norizawa, Kimihiro*; Shibata, Hiromi*; Taguchi, Mitsumasa; Kurashima, Satoshi; Hirota, Koichi
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