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JAEA Reports

XAFS measurement of simulated waste glass samples (Borosilicate glass including vanadium)

Nagai, Takayuki; Kobayashi, Hidekazu; Sasage, Kenichi; Ayame, Yasuo; Okamoto, Yoshihiro; Shiwaku, Hideaki; Matsuura, Haruaki*; Uchiyama, Takafumi*; Okada, Yukiko*; Nezu, Atsushi*; et al.

JAEA-Research 2016-015, 52 Pages, 2016/11

JAEA-Research-2016-015.pdf:37.48MB

The local structure of waste elements in simulated waste glasses including V was estimated by using synchrotron XAFS measurement in this study. The results are as follows. (1) V has a high possibility which exists in the glass phase in the case of frit, and V can regard both samples as stable 4 coordination structure. (2) Zn, Ce, Nd, Zr, and Mo exist in the glass phase, and the difference is admitted by the percentage of Ce(III) and Ce(IV) by the composition. (3) Ru is separated from the glass phase as RuO$$_{2}$$ crystalline, both of metal and oxide exist in Rh, and Pd is separated out as metal. (4) It was confirmed that the regularity of the local structure of Zr and Mo in the molten glasses retreats as a result of the XAFS measurement at high temperature. (5) The XAFS measurement of molten glasses were performed at 1200$$^{circ}$$C, so it would be possible to acquire excellent data by improving the shapes of the sample cell.

Journal Articles

Determination of arsenic and antimony in "Tatara" steel making sample by neutron activation analysis combined with multiple $$gamma$$-ray detection

Inoshita, Shinya*; Suzuki, Shogo*; Okada, Yukiko*; Kato, Masahiko*; Hirai, Shoji*; Kimura, Atsushi; Hatsukawa, Yuichi; Toh, Yosuke; Koizumi, Mitsuo; Oshima, Masumi

Tetsu To Hagane, 94(9), p.345 - 350, 2008/09

"Tatara" is Japanese original steel making method. Steel made by "Tatara" is famous as low alloy and suited to "Kaji" process. By authors' study, it turned out that we could estimate the source region of raw material of Tatara by As and Sb concentration ratio in Tatara sample. But the concentration of these element in Tatara sample is very low (ppm or sub-ppm order), therefore, quantitative analysis is very difficult. In this study, we adopted Neutron Activation Analysis combined with Multiple $$gamma$$-ray detection (NAAMG) to analyze As and Sb in "Tatara" sample (iron lump and sand iron, slag). NAAMG is high sensitive and non-destructive analysis method which combined NAA (Neutron Activation Analysis) and multiple $$gamma$$-ray detectors. Each "Tatara" sample (iron lump, sand iron, slag) were irradiated for 1-2 h (for As measurement), 8-17 h (for Sb measurement) in JRR-3M HR irradiation field (thermal neutron flux was about 9.0$$times$$10$$^{17}$$ n/m $$^{2}$$s$$^{1}$$). And cooling time was 4-5 days (As), and 19-36 days (Sb). Coincidence $$gamma$$-rays were measured by $$gamma$$-ray detector array, GEMINI-II. Counting time was 1-8 hours (As), and 2-41 hours (Sb). Quantification was made by comparison method. As a result of measurement, the concentration of As and Sb in all "Tatara" samples were determined by NAAMG and these were sub-ppm order. Lower Limit of Determination (LLD) of As was 0.1 ppm order and Sb is 0.01ppm order. From the above-mentioned point, the effectiveness of NAAMG to analyze trace element in "Tatara" sample was confirmed.

Oral presentation

Determination of arsenic and antimony in iron sample from simulation "Tatara" of iron making furnace by neutron activation analysis combined with multiple $$gamma$$-ray detection

Inoshita, Shinya*; Hirai, Shoji*; Okada, Yukiko*; Suzuki, Shogo*; Kimura, Atsushi; Oshima, Masumi

no journal, , 

no abstracts in English

Oral presentation

Development of true coincidence summing correction for cascade $$gamma$$-ray emitters including $$^{134}$$Cs, 1; Collaborative experiment by the committee on preparation of reference materials for radioactivity analysis of JSAC

Yonezawa, Chushiro*; Kakita, Kazutoshi*; Takahashi, Takanori*; Aono, Tatsuo*; Maeda, Satoshi; Abe, Takaaki*; Arakawa, Fumihiro*; Kiho, Nobuharu*; Akiyama, Masakazu*; Muramatsu, Isamu*; et al.

no journal, , 

no abstracts in English

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