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Journal Articles

Local structure analysis of light elements included in simulated radioactive waste glasses by soft X-ray absorption fine structure

Okamoto, Yoshihiro; Nagai, Takayuki; Kaneko, Koji; Motokawa, Ryuhei; Haga, Yoshinori; Yamanaka, Keisuke*; Ota, Toshiaki*

2017-Nendo Seika Kokaigata Riyo Seika Hokokusho (Ritsumeikan Daigaku SR Senta), p.33 - 36, 2018/00

The high-level radioactive waste solution which generated from a spent nuclear fuel reprocessing process are mixed with a borosilicate glass frit in a vitrification process, and a chemical stable glass solidified body is produced. To understand local structure of light elements included in a glass solidified body, we carried out a B K-edge XANES measurement of raw glass frits and simulated radioactive waste glasses. As a result of this estimation of boron local structure in glass samples, it was found that the sp$$^{3}$$ type boron (BO$$_{4}$$) percentage increases and the sp$$^{2}$$ type (BO$$_{3}$$) percentage by increasing the sodium content in glass frits.

Journal Articles

${it Ex-situ}$ and ${it in-situ}$ X-ray diffractions of corrosion products freshly formed on the surface of an iron-silicon alloy

Suzuki, Shigeru*; Matsubara, Eiichiro*; Komatsu, Takuya*; Okamoto, Yoshinori*; Kanie, Kiyoshi*; Muramatsu, Atsushi*; Konishi, Hiroyuki; Mizuki, Junichiro; Waseda, Yoshio*

Corrosion Science, 49(3), p.1081 - 1096, 2007/03

 Times Cited Count:32 Percentile:80.42(Materials Science, Multidisciplinary)

${it Ex-situ}$ X-ray diffraction measurements of a small amount of samples extracted from wet corrosion products freshly formed on a pure iron and iron-2 mass% silicon surfaces have been conducted using synchrotron radiation. The results showed that $$gamma$$-FeOOH was formed on the outer side of wet corrosion products formed on the pure iron by sodium chloride solution, while $$gamma$$-FeOOH, $$alpha$$-FeOOH, Fe$$_{3}$$O$$_{4}$$, and green rusts were formed on the inner side. In comparison to the case of the pure iron, a significant formation of $$beta$$-FeOOH was observed in the iron-silicon alloy. Furthermore, in-situ diffraction measurements by a conventional X-ray source were conducted for analyzing corrosion products formed on the pure iron and iron-silicon alloy surfaces by cyclic exposure to wet and dry atmospheres. The results obtained by the ${it in-situ}$ diffraction and ${it ex-situ}$ diffraction measurements on the corrosion products were consistent.

Journal Articles

Soft X-ray magnetic circular dichroism study of ferromagnetic uranium compounds

Okane, Tetsuo; Takeda, Yukiharu; Fujimori, Shinichi; Saito, Yuji; Okamoto, Jun*; Mamiya, Kazutoshi*; Muramatsu, Yasuji*; Fujimori, Atsushi; Ochiai, Akira*; Haga, Yoshinori; et al.

Journal of the Physical Society of Japan, 75(Suppl.), p.105 - 106, 2006/08

no abstracts in English

Journal Articles

Soft X-ray absorption magnetic circular dichroism study of ferromagnetic superconductor UGe$$_2$$

Okane, Tetsuo; Okamoto, Jun*; Mamiya, Kazutoshi*; Fujimori, Shinichi; Takeda, Yukiharu; Saito, Yuji; Muramatsu, Yasuji*; Fujimori, Atsushi*; Haga, Yoshinori; Yamamoto, Etsuji; et al.

Journal of the Physical Society of Japan, 75(2), p.024704_1 - 024704_5, 2006/02

 Times Cited Count:12 Percentile:58.26(Physics, Multidisciplinary)

no abstracts in English

Journal Articles

Nearly localized nature of $$f$$ electrons in Ce$$T$$In$$_5$$ ($$T$$=Rh, Ir)

Fujimori, Shinichi; Okane, Tetsuo; Okamoto, Jun; Mamiya, Kazutoshi; Muramatsu, Yasuji; Fujimori, Atsushi*; Harima, Hisatomo*; Aoki, Dai*; Ikeda, Shugo*; Shishido, Hiroaki*; et al.

Physical Review B, 67(14), p.144507_1 - 144507_5, 2003/04

 Times Cited Count:35 Percentile:79.9(Materials Science, Multidisciplinary)

We have performed angle-resolved photoemission spectroscopy ($$hnu=21.2, 40.8$$~eV) and 3$$d$$-4$$f$$ resonant photoemission spectroscopy ($$hnu sim 881$$~eV) studies on the layered cerium compounds Ce$$T$$In$$_5$$ ($$T$$=Rh and Ir), which show competition between superconductivity and antiferromagnetism. The results suggest that the Ce~4$$f$$ electrons in both compounds are nearly localized. We have found that although the Ce~4$$f$$ electrons in the superconducting CeIrIn$$_5$$ are more delocalized than those in the antiferromagnetic CeRhIn$$_5$$, their electronic structures are very similar to each other.

Journal Articles

Effect of higher-harmonic flux in exponential experiment for subcriticality measurement

Yamamoto, Toshihiro; Miyoshi, Yoshinori; Tonoike, Kotaro; Okamoto, Hajime*; Ida, Toshikazu*; Aoki, Shigeaki*

Journal of Nuclear Science and Technology, 40(2), p.77 - 83, 2003/02

 Times Cited Count:8 Percentile:49.89(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Nuclear Material Research in Cross-Over Research Project

Okamoto, Makoto*; Kitajima, Masahiro*; Kobayashi, Yoshinori*; Kiuchi, Kiyoshi*; Kano, Shigeki

Nihon Genshiryoku Gakkai-Shi, 37(9), p.796 - 806, 1995/00

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

None

Oral presentation

Aiming to Fukushima environmental recovery; Elucidation of the Cs desorption mechanism and development of the Cs desorption method for waste volume reduction

Shiwaku, Hideaki; Yaita, Tsuyoshi; Suzuki, Shinichi; Kobayashi, Toru; Miyazaki, Yuji; Awual, M. R.; Motokawa, Ryuhei; Okamoto, Yoshihiro; Matsumura, Daiju; Yoshii, Kenji; et al.

no journal, , 

no abstracts in English

Oral presentation

Change in cyclic voltammogram of molten glass by glass composition

Nagai, Takayuki; Kaneko, Koji; Motokawa, Ryuhei; Okamoto, Yoshihiro; Haga, Yoshinori; Kobayashi, Hiromi*; Homma, Masanobu*; Hatakeyama, Kiyoshi*; Hirono, Kazuya*

no journal, , 

no abstracts in English

Oral presentation

Redox behavior of iron in molten borosilicate glass

Nagai, Takayuki; Kaneko, Koji; Motokawa, Ryuhei; Okamoto, Yoshihiro; Haga, Yoshinori

no journal, , 

no abstracts in English

Oral presentation

Change in B-O coordination structure by chemical composition of borosilicate glass

Nagai, Takayuki; Okamoto, Yoshihiro; Kaneko, Koji; Motokawa, Ryuhei; Haga, Yoshinori; Yamagishi, Hirona*; Yamanaka, Keisuke*; Ota, Toshiaki*

no journal, , 

no abstracts in English

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