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Sato, Tetsuya; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko*; Haba, Hiromitsu*; Toyoshima, Atsushi; Ono, Sawako*; Hirai, Toshiyuki*; Goto, Shinichi*; Ichikawa, Shinichi; et al.
Journal of Nuclear and Radiochemical Sciences, 6(2), p.N1 - N3, 2005/12
Zr, Hf, and Rf were produced simultaneously from Ge(, n), Gd(O, n), and Cm(O, 5n) reactions, respectively, and the volatility of their chlorides was examined using an isothermal gas chromatographic system. The observed gas chromatogram indicated that ZrCl, HfCl, and RfCl had almost similar volatility.
Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Akiyama, Kazuhiko; Nishinaka, Ichiro; Hirata, Masaru; Yaita, Tsuyoshi; Ichikawa, Shinichi; Nagame, Yuichiro; et al.
Journal of the American Chemical Society, 126(16), p.5219 - 5224, 2004/04
Times Cited Count:43 Percentile:72.51(Chemistry, Multidisciplinary)Fluoride complexation of element 104, rutherfordium (Rf), produced in the Cm(O,5n)Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchangechromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effect on the fluoride complexation of Rf.
Kaneko, Tetsuya*; Ono, Sawako*; Goto, Shinichi*; Haba, Hiromitsu; Asai, Masato; Tsukada, Kazuaki; Nagame, Yuichiro; Kudo, Hisaaki*
Journal of Radioanalytical and Nuclear Chemistry, 255(2), p.381 - 384, 2003/02
Times Cited Count:0 Percentile:0.01(Chemistry, Analytical)no abstracts in English
Haba, Hiromitsu; Tsukada, Kazuaki; Asai, Masato; Goto, Shinichi*; Toyoshima, Atsushi; Nishinaka, Ichiro; Akiyama, Kazuhiko; Hirata, Masaru; Ichikawa, Shinichi; Nagame, Yuichiro; et al.
Journal of Nuclear and Radiochemical Sciences, 3(1), p.143 - 146, 2002/06
We have investigated the sorption behavior of element 104 rutherfordium (Rf) on an anion exchange resin from HCl and HNO solutions. In the HCl experiments, the distribution coefficients of Rf increase with an increase of HCl concentration from 7.0 M to 11.5 M, indicating that anionic species such as [Rf(OH)Cl] or [RfCl] are formed. This sorption behavior of Rf is typical of the group-4 elements Zr and Hf, and is quite different from that of the pseudo-homologue Th. It is also noted that the distribution coefficients decrease in the order Rf, Zr, Hf at 9.0 M HCl, which is consistent with the expected order of ionic radii. On the other hand, Rf appears to behave like Zr and Hf in 8 M HNO not like Pu and Th.