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Osaki, Hirotaka; Shimazaki, Yosuke; Sumita, Junya; Shibata, Taiju; Konishi, Takashi; Ishihara, Masahiro
Proceedings of 23rd International Conference on Nuclear Engineering (ICONE-23) (DVD-ROM), 8 Pages, 2015/05
For the design on the VHTR graphite components, it is desirable to employ graphite material with higher strength. IG-430 graphite has been developed as an advanced candidate for VHTR. However, the new developed IG-430 does not have enough databases for the design of HTGR. In this paper, the compressive strength (Cs) of IG-430, one of important strengths for design data, is statistically evaluated. The component reliability is evaluated based on the safety factors defined by the graphite design code, and the applicability as the VHTR graphite material is discussed. It was found that IG-430 has higher strength (about 11%) and lower standard deviation (about 27%) than IG-110 which is one of traditional graphites used for HTGR, because the crack in IG-430 would not easy to propagate rather than IG-110. Since fracture probability for IG-430 is low, the higher reliability of core-component will be achieved using IG-430. It is expected that IG-430 is applicable for VHTR graphite material.
Fujita, Ichiro*; Eto, Motokuni*; Osaki, Hirotaka; Shibata, Taiju; Sumita, Junya; Konishi, Takashi; Yamaji, Masatoshi; Kunimoto, Eiji
JAEA-Research 2013-004, 20 Pages, 2013/07
JAEA-Research-2013-004.pdf:2.4MB
Graphite components in HTGR and VHTR may be oxidized by impurities in coolant helium-gas even at normal operation, as well as by air at air-ingress accident. In this study, by air-oxidation test at 520-900
C, oxidation characteristics of IG-110 and IG-430 graphites, and associated decrease in compressive strength were examined. The following results were obtained. (1) The activation energy of the air-oxidation for IG-430 is 176 kJ/mol being almost same as for IG-110, though the oxidation rate for IG-430 is less than a half of that for IG-110. (2) There are correlations between density change and decrease in compressive strength. Decrease in strength is the largest in case that the oxidation temperature is lower than 600 C where the homogenous oxidation occurs. (3) In the process of oxidation, amorphous binder regions are predominantly oxidized. It suggests that peeling-off of cokes grains is necessary to be considered for oxidation weight loss, as well as gasification.
nanocomposite electrocatalyst; An in situ electrochemical X-ray absorption fine structure studyMasuda, Takuya*; Fukumitsu, Hitoshi*; Fugane, Keisuke*; Togasaki, Hirotaka*; Matsumura, Daiju; Tamura, Kazuhisa; Nishihata, Yasuo; Yoshikawa, Hideki*; Kobayashi, Keisuke*; Mori, Toshiyuki*; et al.
Journal of Physical Chemistry C, 116(18), p.10098 - 10102, 2012/05
Times Cited Count：118 Percentile：93.76(Chemistry, Physical)In situ electrochemical X-ray absorption fine structure (XAFS) measurements were performed at the Pt L
and Ce L edges of the Pt-CeO/C catalyst, which was prepared by a combined process of precipitation and coimpregnation methods, as well as at the Pt L edge of the conventional Pt/C catalyst in oxygen-saturated H
SO
solution to clarify the role of CeO in the reduction of the overpotential for the oxygen reduction reaction (ORR) at the Pt-CeO nanocomposite compared with the conventional Pt/C catalyst. XAFS measurements clearly show that the enhancement of ORR activity is attributed to the inhibition of Pt oxide formation by the CeO layer, of which Ce
was oxidized to Ce
instead of Pt at the Pt oxide formation potential.
Shibata, Taiju; Sumita, Junya; Ueta, Shohei; Osaki, Hirotaka; Kunimoto, Eiji; Eto, Motokuni*; Konishi, Takashi
no journal, ,
no abstracts in English
Osaki, Hirotaka; Konishi, Takashi*; Eto, Motokuni*; Shibata, Taiju; Sumita, Junya
no journal, ,
no abstracts in English
Shimazaki, Yosuke; Shinohara, Masanori; Ono, Masato; Tochio, Daisuke; Osaki, Hirotaka; Sawa, Kazuhiro
no journal, ,
no abstracts in English
