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Ostapczuk, A.*; Hakoda, Teruyuki; Shimada, Akihiko; Kojima, Takuji
Plasma Chemistry and Plasma Processing, 28(4), p.483 - 494, 2008/08
Times Cited Count:16 Percentile:53.62(Engineering, Chemical)The application of non-thermal plasma generated by electron beam (EB) was investigated in laboratory scale to study decomposition of polycyclic aromatic hydrocarbons like naphthalene and acenaphthene in flue gas. PAH compounds were treated by EB with the dose up to 8 kGy in dry and humid base gas mixtures. Experimentally established G-values gained 1.66 and 3.72 mol/100 eV for NL and AC at the dose of 1 kGy. NL and AC removal was observed in dry base gas mixtures showing that the reaction with OH radical is not exclusive pathway to initialize PAH decomposition, however in the presence of water remarkably higher decomposition efficiency was observed. As by-products of NL decomposition were identified compounds containing one aromatic ring and oxygen atoms besides CO and CO. It led to the conclusion that PAH decomposition process in humid flue gas can be regarded as multi-step oxidative de-aromatization analogical to its atmospheric chemistry.
Sun, Y.*; Hakoda, Teruyuki; Chmielewski, A. G.*; Hashimoto, Shoji; Zimek, Z.*; Bulka, S.*; Ostapczuk, A.*; Nichipor, H.*
Radiation Physics and Chemistry, 62(4), p.353 - 360, 2001/10
Times Cited Count:22 Percentile:81.38(Chemistry, Physical)no abstracts in English
Sun, Y.*; Hakoda, Teruyuki; Chmielewski, A. G.*; Hashimoto, Shoji; Zimek, Z.*; Bulka, S.*; Ostapczuk, A.*; Nichipor, H.*
Proceedings of 5th International Symposium & Exhibition on Environmental Contamination in Central & Eastern Europe (CD-ROM), 6 Pages, 2000/00
no abstracts in English