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Journal Articles

Rotation of complex ions with ninefold hydrogen coordination studied by quasielastic neutron scattering and first-principles molecular dynamics calculations

Omasa, Yoshinori*; Takagi, Shigeyuki*; Toshima, Kento*; Yokoyama, Kaito*; Endo, Wataru*; Orimo, Shinichi*; Saito, Hiroyuki*; Yamada, Takeshi*; Kawakita, Yukinobu; Ikeda, Kazutaka*; et al.

Physical Review Research (Internet), 4(3), p.033215_1 - 033215_9, 2022/09

Journal Articles

Materials and Life Science Experimental Facility (MLF) at the Japan Proton Accelerator Research Complex, 2; Neutron scattering instruments

Nakajima, Kenji; Kawakita, Yukinobu; Ito, Shinichi*; Abe, Jun*; Aizawa, Kazuya; Aoki, Hiroyuki; Endo, Hitoshi*; Fujita, Masaki*; Funakoshi, Kenichi*; Gong, W.*; et al.

Quantum Beam Science (Internet), 1(3), p.9_1 - 9_59, 2017/12

The neutron instruments suite, installed at the spallation neutron source of the Materials and Life Science Experimental Facility (MLF) at the Japan Proton Accelerator Research Complex (J-PARC), is reviewed. MLF has 23 neutron beam ports and 21 instruments are in operation for user programs or are under commissioning. A unique and challenging instrumental suite in MLF has been realized via combination of a high-performance neutron source, optimized for neutron scattering, and unique instruments using cutting-edge technologies. All instruments are/will serve in world-leading investigations in a broad range of fields, from fundamental physics to industrial applications. In this review, overviews, characteristic features, and typical applications of the individual instruments are mentioned.

Journal Articles

True Boundary for the formation of homoleptic transition-metal hydride complexes

Takagi, Shigeyuki*; Iijima, Yuki*; Sato, Toyoto*; Saito, Hiroyuki; Ikeda, Kazutaka*; Otomo, Toshiya*; Miwa, Kazutoshi*; Ikeshoji, Tamio*; Aoki, Katsutoshi*; Orimo, Shinichi*

Angewandte Chemie; International Edition, 54(19), p.5650 - 5653, 2015/05

 Times Cited Count:32 Percentile:68.44(Chemistry, Multidisciplinary)

Journal Articles

Design and performance of high-pressure PLANET beamline at pulsed neutron source at J-PARC

Hattori, Takanori; Sano, Asami; Arima, Hiroshi*; Komatsu, Kazuki*; Yamada, Akihiro*; Inamura, Yasuhiro; Nakatani, Takeshi; Seto, Yusuke*; Nagai, Takaya*; Utsumi, Wataru; et al.

Nuclear Instruments and Methods in Physics Research A, 780, p.55 - 67, 2015/04

 Times Cited Count:75 Percentile:99.01(Instruments & Instrumentation)

PLANET is a time-of-flight (ToF) neutron beamline dedicated to high-pressure and high-temperature experiments. The large six-axis multi-anvil high-pressure press designed for ToF neutron diffraction experiments enables routine data collection at high pressures and high temperatures up to 10 GPa and 2000 K, respectively. To obtain clean data, the beamline is equipped with the incident slits and receiving collimators to eliminate parasitic scattering from the high-pressure cell assembly. The high performance of the diffractometer for the resolution ($$Delta$$ $$d$$/$$d$$ $$sim$$ 0.6%) and the accessible $$d$$-spacing range (0.2-8.4 ${AA}$) together with low-parasitic scattering characteristics enables precise structure determination of crystals and liquids under high pressure and temperature conditions.

JAEA Reports

Radioactive airborne effluent discharged from Tokai reprocessing plant; 1998-2007

Nakada, Akira; Miyauchi, Toru; Akiyama, Kiyomitsu; Momose, Takumaro; Kozawa, Tomoyasu*; Yokota, Tomokazu*; Otomo, Hiroyuki*

JAEA-Data/Code 2008-018, 134 Pages, 2008/10

JAEA-Data-Code-2008-018.pdf:3.23MB

This report provides the data set of atmospheric discharges from Tokai reprocessing plant in Tokai-mura, Japan over the period from 1998 to 2007. Daily and weekly data are shown for $$^{85}$$Kr that is continuously monitored and for the other nuclide (Alpha emitters, Beta emitters, $$^{3}$$H, $$^{14}$$C, $$^{129}$$I, $$^{131}$$I) whose activities are evaluated based on weekly batch-samplings, respectively. The data contained in this report are expected to apply for studying the behavior of the radioactive airborne effluent in the environment.

Journal Articles

Bulk damage observed in recent LSI devices

Shindo, Hiroyuki*; Kuboyama, Satoshi*; Ikeda, Naomi*; Otomo, Hiromitsu*; Shimada, Osamu*; Hirao, Toshio; Matsuda, Sumio*

Proceedings of the 6th International Workshop on Radiation Effects on Semiconductor Devices for Space Application (RASEDA-6), p.63 - 66, 2004/10

no abstracts in English

JAEA Reports

The Verification of neutron activation analysis support system (Cooperative research)

Sasajima, Fumio; Sawahata, Hiroyuki*; Onizawa, Koji*; Ichimura, Shigeju; Otomo, Akitoshi; Ito, Yasuo*; Takayanagi, Masaji

JAERI-Tech 2000-073, 49 Pages, 2000/12

JAERI-Tech-2000-073.pdf:4.43MB

no abstracts in English

Oral presentation

User operation at J-PARC and strategy of high pressure research with neutron

Utsumi, Wataru; Abe, Jun; Hattori, Takanori; Fukazawa, Hiroshi; Yamauchi, Hiroki; Igawa, Naoki; Kagi, Hiroyuki; Arima, Hiroshi*; Arakawa, Masashi; Komatsu, Kazuki*; et al.

no journal, , 

no abstracts in English

Oral presentation

Strategy of high pressure research with pulsed neutron at J-PARC

Utsumi, Wataru; Kagi, Hiroyuki*; Hattori, Takanori; Arima, Hiroshi; Komatsu, Kazuki*; Abe, Jun; Nagai, Takaya*; Okuchi, Takuo*; Harjo, S.; Aizawa, Kazuya; et al.

no journal, , 

J-PARC is a new high-intensity proton accelerator research facility in Japan. It has a spallation neutron source that will produce the world highest intensity pulsed neutron. It is expected that high pressure material science and the investigation of the Earth's interior will greatly improve at J-PARC. A Paris-Edinburgh cell and a cubic anvil high pressure apparatus have been brought to an Engineering Materials Diffractometer(BL19) to conduct the first high pressure experiment. As the next stage, we are planning to construct a dedicated high pressure beamline that will open in 2011.

Oral presentation

First HT HP liquid data using a high-pressure neutron diffractometer, PLANET, in J-PARC/MLF

Katayama, Yoshinori; Yagafarov, O.*; Hattori, Takanori; Chiba, Ayano*; Sano, Asami; Saito, Hiroyuki; Suzuya, Kentaro; Otomo, Toshiya*

no journal, , 

As the first high-pressure experiments on structurally disordered materials using a newly-built high-pressure neutron diffractometer, PLANET, installed in J-PARC/MLF, measurements of silica glass, a typical oxide glass, were caried out. We compressed a sample in a ZrO$$_{2}$$ cube using a six-axis press and measured diffraction at pressures of 0.1 MPa, 2.3, 5.5, 7.5 and 9.9 GPa at room temperature. Vanadium sample and empty cell were also measured for the correction of the diffraction intensity. Clean diffraction patterns without diffraction lines from surrounding materials were obtained thanks to the radial collimator system. Measurements on heavy water at room temperature, 100$$^{circ}$$C and 200$$^{circ}$$C at 0.8 GPa were also carried out as the first high-pressure high-temperature liquid measurement using PLANET. Significant temperature dependence of diffraction pattern was observed.

Oral presentation

High-pressure neutron experiments on SiO$$_{2}$$ glass using J-PARC high-pressure neutron diffractometer PLANET

Hattori, Takanori; Yagafarov, O.*; Katayama, Yoshinori; Sano, Asami; Saito, Hiroyuki; Chiba, Ayano*; Inamura, Yasuhiro; Suzuya, Kentaro; Otomo, Toshiya*

no journal, , 

SiO$$_{2}$$ glass consists of SiO$$_{4}$$ tetrahedra. This glass is easily densified by applying pressure, due to its relatively sparse network ring formed by the linkage of tetrahedra. The density increase amounts to 20% by room temperature compression to 8 GPa. This increase is, however, released after decompression because of insufficient structural relaxation. On the other hand, the heating at high pressures promotes the structural relaxation, resulting in permanent densification of 20% at most. The mechanism of this densification has been investigated so far, but the microscopic origin is still to be revealed. So, we performed in-situ high-pressure neutron experiments at newly constructed high-pressure neutron beamline PLANET in J-PARC. We will discuss the origin of the reversibility in the densification.

Oral presentation

X-ray and neutron structural study on water under high pressure and high temperature

Katayama, Yoshinori; Hattori, Takanori; Saito, Hiroyuki; Sano, Asami; Suzuya, Kentaro; Yagafarov, O.*; Chiba, Ayano*; Otomo, Toshiya*

no journal, , 

Liquid water at ambient conditions has an ice-like, characteristic structure due to the hydrogen bonds between molecules. To study pressure and temperature dependence of the structure of water, we have carried out in-situ high-temperature high-pressure measurements on liquid water using synchrotron radiation at the SPring-8 and molecular dynamics simulations. The results revealed transformation from the ice-like structure to a simple-liquid-like structure. To investigate change in hydrogen bonds, neutron is an important probe. We carried out neutron diffraction measurements on heavy water at room temperature, 100$$^{circ}$$C and 200$$^{circ}$$C at 0.8 GPa using newly-built high-pressure diffractometer, PLANET, at J-PARC/MLF. Significant temperature dependence of diffraction pattern was observed.

Oral presentation

High-pressure neutron experiments on SiO$$_{2}$$ glass using high-pressure neutron diffractometer PLANET at J-PARC

Hattori, Takanori; Yagafarov, O.*; Katayama, Yoshinori; Sano, Asami; Saito, Hiroyuki; Chiba, Ayano*; Inamura, Yasuhiro; Suzuya, Kentaro; Otomo, Toshiya*

no journal, , 

SiO$$_2$$ glass consists of SiO$$_4$$ tetrahedra. This glass is easily densified by applying pressure, due to its relatively sparse network formed by the linkage of tetrahedra. The density increase amounts to 20% by room temperature compression to 8 GPa. This increase is, however, released after decompression because of insufficient structural relaxation. On the other hand, the heating at high pressures promotes the structural relaxation, resulting in permanent densification of 20% at most. The mechanism of this densification has been investigated so far, but the microscopic origin is still to be revealed. So, we performed in-situ high-pressure neutron experiments at newly constructed high-pressure neutron beamline PLANET in J-PARC. We will discuss the origin of the reversibility in the densification.

Oral presentation

X-ray and neutron structural study on water under high pressure and high temperature, 2

Katayama, Yoshinori; Hattori, Takanori; Yagafarov, O.*; Saito, Hiroyuki; Sano, Asami; Suzuya, Kentaro; Chiba, Ayano*; Otomo, Toshiya*

no journal, , 

Liquid water at ambient conditions has an ice-like, characteristic structure due to the hydrogen bonds between molecules. To study pressure and temperature dependence of the structure of water, we have carried out in-situ high-temperature high-pressure measurements on liquid water by in-situ synchrtorn X-ray diffraction experiments at the SPring-8 and molecular dynamics simulations. The results revealed transformation from the ice-like structure to a simple-liquid-like structure. To investigate change in hydrogen bonds, neutron is an important probe. We carried out neturon diffraction measurements on heavy water at 100$$^circ$$C and 200$$^circ$$C at 2 GPa using high-pressure diffractometer, PLANET, at J-PARC/MLF. Significant temperature dependence of width of first peak in diffraction pattern, which is similar to that observed in the previous neutron diffraction experiments at 0.8 GPa.

Oral presentation

Fe-silicate and -carbonate formations at C-steel- compacted bentonite interface hinders buffer degradation in high-level radioactive waste disposal

Kikuchi, Ryosuke*; Fujimura, Tatsuya*; Sato, Tsutomu*; Otake, Tsubasa*; Otomo, Yoko*; Goto, Takahiro*; Suzuki, Satoru*; Taniguchi, Naoki; Suzuki, Hiroyuki*

no journal, , 

15 (Records 1-15 displayed on this page)
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