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Suzuki, Tomoya*; Otsubo, Ukyo*; Ogata, Takeshi*; Shiwaku, Hideaki; Kobayashi, Toru; Yaita, Tsuyoshi; Matsuoka, Mitsuaki*; Murayama, Norihiro*; Narita, Hirokazu*
Separation and Purification Technology, 308, p.122943_1 - 122943_7, 2023/03
Times Cited Count：2 Percentile：24.43(Engineering, Chemical)HNO
leaching is used in recycling Pd metal from spent products that primarily contain Ag, and most Pd residues are separated from solutions containing Ag(I). However, a small amount of Pd(II) often remains in these Ag(I) solutions. Therefore, the separation of Pd(II) and Ag(I) in HNO solutions is essential to promote efficient Pd recycling. In this study, the separation of Pd(II) and Ag(I) in HNO solutions was investigated using four N-donor-type adsorbents functionalized with amine (R-Amine), iminodiacetic acid (R-IDA), pyridine (R-Py), or bis-picolylamine (R-BPA). R-Amine, R-IDA, and R-Py selectively adsorbed Pd(II) over Ag(I), Cu(II), Ni(II), and Fe(III) from HNO solutions (0.3-7 M), but R-Amine exhibited a lower Pd adsorption efficiency. In contrast, 
90% of Pd(II), Ag(I), and Cu(II) were adsorbed by R-BPA over the entire range of HNO concentrations. Structural analyses of the adsorbed metal ions using Fourier transform infrared spectroscopy and extended X-ray absorption fine structure spectroscopy revealed the separation mechanisms of the N-donor-type adsorbents. Pd(II) adsorption on R-IDA, R-Py, and R-BPA occurred via Pd(II) coordination of the functional groups (iminodiacetic acid, pyridine, and bis-picolylamine, respectively), whereas that on R-Amine occurred via anion exchange of NO
with [Pd(NO)
]
. The coordinative adsorption mechanisms resulted in the higher Pd(II) adsorption behaviors of R-IDA, R-Py, and R-BPA. HCl (5.0 M) and thiourea (0.1 M) eluents desorbed 83% of Pd(II) from R-IDA and 95% from R-Py, respectively. R-Py was the most effective Pd(II) adsorbent based on adsorption selectivity and desorption efficiency.
Suzuki, Tomoya*; Otsubo, Ukyo*; Ogata, Takeshi*; Shiwaku, Hideaki; Kobayashi, Toru; Yaita, Tsuyoshi; Matsuoka, Mitsuaki*; Murayama, Norihiro*; Narita, Hirokazu*
Dalton Transactions (Internet), 50(33), p.11390 - 11397, 2021/09
Times Cited Count：2 Percentile：21.56(Chemistry, Inorganic & Nuclear)no abstracts in English
La
B
studied by resonant X-ray diffractionMatsumura, Takeshi*; Michimura, Shinji*; Inami, Toshiya; Otsubo, Toru*; Tanida, Hiroshi*; Iga, Fumitoshi*; Sera, Masafumi*
JPS Conference Proceedings (Internet), 3, p.014008_1 - 014008_6, 2014/06
We study the 
-type antiferro-octupole (AFO) ordered state of CeLaB below 1.5 K by resonant X-ray diffraction in magnetic fields. Multipole moments induced by the field in the AFO phase are identified. In a mean-field model for the AFO order within the 
quartet crystal-field ground state, the 
and 
antiferroquadrupoles (AFQ) are expected as mostly induced AFQ. However, in contrast to this expectation, the main induced moment is found to be the 
-type AFQ.
LaB from resonant X-ray diffraction in magnetic fieldsMatsumura, Takeshi*; Michimura, Shinji*; Inami, Toshiya; Otsubo, Toru*; Tanida, Hiroshi*; Iga, Fumitoshi*; Sera, Masafumi*
Physical Review B, 89(1), p.014422_1 - 014422_13, 2014/01
Times Cited Count：14 Percentile：52.23(Materials Science, Multidisciplinary)The multipole ordered phase in CeLaB (phase IV) has been studied by resonant X-ray diffraction in magnetic fields. By utilizing diamond X-ray phase plates to rotate the incident linear polarization and a conventional crystal analyzer system, full linear polarization analysis has been performed to identify the order parameters. The analysis shows that the 
quadrupoles are more induced by the field than the 
quadrupoles in phase IV, in disagreement with mean-field calculations, in which the quadrupole is the main induced moment. Hence, we consider that large fluctuations of the quadrupole is hidden behind the primary ordering of the octupole.
Yamasaki, Chisato*; Murakami, Katsuhiko*; Fujii, Yasuyuki*; Sato, Yoshiharu*; Harada, Erimi*; Takeda, Junichi*; Taniya, Takayuki*; Sakate, Ryuichi*; Kikugawa, Shingo*; Shimada, Makoto*; et al.
Nucleic Acids Research, 36(Database), p.D793 - D799, 2008/01
Times Cited Count：51 Percentile：71.25(Biochemistry & Molecular Biology)Here we report the new features and improvements in our latest release of the H-Invitational Database, a comprehensive annotation resource for human genes and transcripts. H-InvDB, originally developed as an integrated database of the human transcriptome based on extensive annotation of large sets of fulllength cDNA (FLcDNA) clones, now provides annotation for 120 558 human mRNAs extracted from the International Nucleotide Sequence Databases (INSD), in addition to 54 978 human FLcDNAs, in the latest release H-InvDB. We mapped those human transcripts onto the human genome sequences (NCBI build 36.1) and determined 34 699 human gene clusters, which could define 34 057 protein-coding and 642 non-protein-coding loci; 858 transcribed loci overlapped with predicted pseudogenes.
S
Michimura, Shinji; Inami, Toshiya; Otsubo, Toru*; Matsumura, Takeshi*; Tanida, Hiroshi*; Sera, Masafumi*; Matsuoka, Eiichi*; Watahiki, Masanori*; Tanigaki, Katsumi*; Onodera, Hideya*
no journal, ,
LaB
in magnetic fieldMichimura, Shinji; Inami, Toshiya; Otsubo, Toru*; Matsumura, Takeshi*; Tanida, Hiroshi*; Sera, Masafumi*; Iga, Fumitoshi*
no journal, ,
no abstracts in English
S by a resonant X-ray diffractionMichimura, Shinji; Inami, Toshiya; Otsubo, Toru*; Matsumura, Takeshi*; Tanida, Hiroshi*; Sera, Masafumi*; Matsuoka, Eiichi*; Watahiki, Masanori*; Tanigaki, Katsumi*; Onodera, Hideya*
no journal, ,
no abstracts in English
