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Journal Articles

In situ neutron reflectometry analysis of interfacial structure formation between phenolic resin and silica during curing

Izumi, Atsushi*; Shudo, Yasuyuki*; Shibayama, Mitsuhiro*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Langmuir, 37(47), p.13867 - 13872, 2021/11

 Times Cited Count:2 Percentile:14.19(Chemistry, Multidisciplinary)

Journal Articles

Interfacial cross-link inhomogeneity of a phenolic resin on a silica surface as revealed by X-ray and neutron reflection measurements

Izumi, Atsushi*; Shudo, Yasuyuki*; Shibayama, Mitsuhiro*; Yoshida, Tessei*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Macromolecules, 53(10), p.4082 - 4089, 2020/05

 Times Cited Count:7 Percentile:31.66(Polymer Science)

Journal Articles

Diffusion behavior of methanol molecules confined in cross-linked phenolic resins studied using neutron scattering and molecular dynamics simulations

Shudo, Yasuyuki*; Izumi, Atsushi*; Hagita, Katsumi*; Yamada, Takeshi*; Shibata, Kaoru; Shibayama, Mitsuhiro*

Macromolecules, 51(16), p.6334 - 6343, 2018/08

 Times Cited Count:11 Percentile:40.31(Polymer Science)

Journal Articles

Removal of fission products in the spent electrolyte using iron phosphate glass as a sorbent

Amamoto, Ippei; Mitamura, Naoki*; Tsuzuki, Tatsuya*; Takasaki, Yasushi*; Shibayama, Atsushi*; Yano, Tetsuji*; Nakada, Masami; Okamoto, Yoshihiro

Proceedings of 13th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2010) (CD-ROM), p.503 - 508, 2010/10

The main objective of this development is to recycle the purified eutectic medium of the pyroreprocessing, delaying its disposal for as long as possible. We have introduced the simple filtration method to remove the rare earth element (REE) particles which were formed due to the conversion of REE chlorides to phosphates. Here, the iron phosphate glass is used as a filtration medium for the removal of FP particles. However, some soluble FP such as compounds of alkali-metals, alkaline-earth metals, etc. still remain in the eutectic medium. This time around, on an experimental basis, the iron phosphate glass has been used as a sorbent instead, to remove the soluble FP. We have obtained some positive results and have intention to incorporate it into the spent electrolyte recycle process as a part of the FP separation and immobilization system.

JAEA Reports

Transmission system in JT-60U electron cyclotron heating system

Yokokura, Kenji; Hiranai, Shinichi; Shibayama, Minoru*; Ikeda, Yoshitaka; Moriyama, Shinichi; Shinozaki, Shinichi; Sato, Fumiaki*; Kasugai, Atsushi

JAERI-Tech 2003-047, 58 Pages, 2003/06

JAERI-Tech-2003-047.pdf:9.52MB

This report represents a MW-class RF transmission system at 110 GHz in JT-60U electron cyclotron heating system. Its basic design, performances, features, construction experiences, and improvements fed-back from the operation experiences are described. The transmission system has successfully demonstrated high power long pulse operation, e.g., 1MW for 4s with 20 $$sim$$ 25% of low transmission loss which agrees with the designed value.

Oral presentation

Fundamental study on phosphate conversion behaviours of FP chlorides

Takasaki, Yasushi*; Amamoto, Ippei; Myochin, Munetaka; Shibayama, Atsushi*

no journal, , 

no abstracts in English

Oral presentation

Fundamental study on electrolyte recycle process by phosphate conversion technique, 9; Study on sorption mechanism of iron phosphate-glass as sorbent

Amamoto, Ippei; Kofuji, Hirohide; Tsuzuki, Tatsuya*; Mitamura, Naoki*; Takasaki, Yasushi*; Shibayama, Atsushi*; Yano, Tetsuji*; Terai, Takayuki*

no journal, , 

no abstracts in English

Oral presentation

Fundamental study on electrolyte recycle process by phosphate conversion technique, 12; Study on stable iron-phosphate glass system for use as a sorbent in molten salt

Amamoto, Ippei; Kofuji, Hirohide; Mitamura, Naoki*; Tsuzuki, Tatsuya*; Motohashi, Takumi*; Takasaki, Yasushi*; Shibayama, Atsushi*; Yano, Tetsuji*

no journal, , 

no abstracts in English

Oral presentation

Evaluation of $$beta$$-phase based titanium alloys

Wakai, Eiichi; Ishida, Taku*; Kano, Sho*; Shibayama, Tamaki*; Sato, Koichi*; Noto, Hiroyuki*; Makimura, Shunsuke*; Furuya, Kazuyuki*; Yabuuchi, Atsushi*; Yoshiie, Toshimasa*; et al.

no journal, , 

Titanium materials have been applied to beam window materials and beam dumps in large accelerator systems because of their low specific gravity, high corrosion resistance, strength, and other advantages. As the beam power becomes higher, further improvement of irradiation resistance is required. We have investigated further the properties of titanium alloys based on the $$beta$$-phase, and it was found that Ti-15-3-3-3 alloys have excellent irradiation resistance when subjected to ion irradiation. In order to investigate the cause of this, microstructures and point defects in this and related materials were evaluated by TEM, positron lifetime measurement, electrical resistivity, and stress-induced changes, among others. In addition, we have recently begun to develop a prototype of a titanium-based high-entropy alloy based on $$beta$$-titanium, which is attracting worldwide attention and is being developed, and have also begun to evaluate the emotional properties of this alloy. We have examined the various properties of this material and found that it has considerably higher strength than conventional iron- and titanium-based materials.

Oral presentation

Characterization of Fe-, Ti-, and W-based high-entropy alloys that mainly have bcc crystal structure (including irradiation effects)

Wakai, Eiichi; Noto, Hiroyuki*; Shibayama, Tamaki*; Iwamoto, Yosuke; Ishida, Taku*; Sato, Koichi*; Yabuuchi, Atsushi*; Yoshiie, Toshimasa*; Takahashi, Toshiharu*; Kobayashi, Yasuhiro*; et al.

no journal, , 

In recent years, it has been reported that high-entropy alloys (HEA) have high strength but good ductility, and they are being researched and developed by cutting-edge research institutions around the world with the aim of finding various applications in progress. In this study, we considered several Fe-based, W-based, and Ti-based HEAs, excluding Co and Ni elements, in order to aim for use in high radiation fields and considering low-activation properties. These materials mainly have a bcc crystal structure and were fabricated using a melting method and their material properties were evaluated. As a result, it was found that Fe-based HEA has properties that exceed the hardness of pure W and has excellent irradiation resistance. In addition, a Ti-based HEA that can be subjected to high-temperature forging and high-temperature rolling has been found, and evaluation of the optimal heat treatment temperature is progressing. The hardness of W-based HEA increased through Hot Isostatic Pressing (HIP) treatment, and it was found to have the world's highest hardness among HEA materials.

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