Hydroxyl group/fluorine disorder in deuterated magnesium hydroxyfluoride and behaviors of hydrogen bonds under high pressure

He, X.*; Kagi, Hiroyuki*; Komatsu, Kazuki*; Iizuka, Riko*; Okajima, Hajime*; Hattori, Takanori; Sano, Asami; Machida, Shinichi*; Abe, Jun*; Goto, Hirotada*; et al.

Journal of Molecular Structure, 1310, p.138271_1 - 138271_8, 2024/08

https://doi.org/10.1016/j.molstruc.2024.138271

High-pressure responses of the O-DF hydrogen bonds in deuterated magnesium hydroxyfluoride were investigated using neutron powder diffraction and Raman spectroscopy. The Rietveld analysis at ambient conditions revealed a chemical formula of Mg(OD)F and hydroxyl group/fluorine disorder (OD/F disorder) in the crystal structure, which gave rise to two hydrogen-bonding configurations. The Rietveld analysis showed the hydrogen-bonding geometries remains up to 9.8 GPa, indicating no pressure-induced strengthening of hydrogen bonds. The Raman spectra at ambient conditions showed three hydroxyl stretching bands at 2613, 2694, and 2718 cm. The high frequencies of the O-D stretching modes indicated that the hydroxyls should be involved in weak or none hydrogen-bonding interactions. Up to 20.2 GPa, the mode initially centered at 2694 cm displayed a pressure-induced blue shift, revealing no strengthening of hydrogen bonds under compression. We discuss the existence of hydrogen bonds and the causes of the blue-shifting hydroxyls at ambient and at high pressures.

Study of the applicability of SrI(Eu) scintillation detector to in-situ gamma-ray spectrometry

Takeyasu, Masanori; Mikami, Satoshi; Ando, Masaki; Hokama, Tomonori

JAEA-Testing 2023-005, 17 Pages, 2024/03

JAEA-Testing-2023-005.pdf:1.16MB

As part of the research aimed at developing a detector to easily perform in-situ gamma-ray spectrometry, the applicability of a SrI(Eu) scintillation detector to in-situ gamma-ray spectrometry was investigated. In this study, the characteristics of the SrI(Eu) detector were evaluated for in-situ gamma-ray spectrometry. Intercomparison measurements of in-situ gamma-ray spectrometry using the SrI(Eu) detector and Ge semiconductor detectors were conducted, and the applicability of the SrI(Eu) detector was examined. To characterize the SrI(Eu) detector, the peak efficiency of the SrI(Eu) detector was measured with respect to the change of incident gamma-ray energy. The angular dependence of the peak efficiency of the SrI(Eu) detector was also measured. As the result of the intercomparison measurement of in-situ gamma-ray spectrometry, the radionuclides quantified by Ge detectors were Cs-134, Cs-137, Pb-214, Bi-214, Tl-208, Ac-228 and K-40. On the other hand, those by SrI(Eu) detector were only Cs-137 and K-40 which had relatively high radioactive intensity. The deposition density of Cs-137 and the concentration of K-40 in soil measured by the SrI(Eu) detector showed relatively good agreements with those by Ge detectors. From these results, it was suggested that the in-situ measurement using a SrI(Eu) detector was available for radionuclides which had high radioactive intensity and whose gamma-ray peaks were not interfered by those of other radionuclides in gamma-ray spectrum. During an accident at nuclear power plant, various radionuclides are released into the environment, but radionuclides with short half-life decayed and radionuclides with long half-life only exist at mid-to-long term environmental monitoring situations, when in-situ gamma-ray spectrometry using a SrI(Eu) detector is applicable.

Background radiation monitoring via manned helicopter and development of technology for radiation monitoring via unmanned airplane for application of nuclear emergency response technique in the fiscal year 2022 (Contract research)

Futemma, Akira; Sanada, Yukihisa; Sasaki, Miyuki; Kawasaki, Yoshiharu*; Iwai, Takeyuki*; Hiraga, Shogo*; Haginoya, Masashi*; Matsunaga, Yuki*; Akutsu, Yuichiro*; Arai, Yoshinori*; et al.

JAEA-Technology 2023-026, 161 Pages, 2024/03

JAEA-Technology-2023-026.pdf:14.66MB

By the accident at Tokyo Electric Power Company's (TEPCO's) Fukushima Daiichi Nuclear Power Station (FDNPS), caused by tsunami triggered by the 2011 off the Pacific coast of Tohoku Earthquake, a large amount of radioactive material was released into the surrounding environment. After the accident, Airborne Radiation Monitoring (ARM) via manned helicopter has been utilized as a method to quickly and extensively measure radiation distribution surrounding FDNPS. In order to utilize ARM and to promptly provide the results during a nuclear emergency, information on background radiation levels, topographical features, and controlled airspace surrounding nationwide nuclear facilities have been prepared in advance. In the fiscal year 2022, we conducted ARM around the Mihama Nuclear Power Station of Kansai Electric Power Company (KEPCO), the Tsuruga Power Station of Japan Atomic Power Company (JAPC), and the Ikata Power Station of Shikoku Electric Power Company (YONDEN), and prepared information on background radiation doses and controlled airspace. In addition, we have developed an aerial radiation detection system via unmanned airplane, which is expected to be an alternative to ARM, during a nuclear emergency. This report summarizes the results and technical issues identified.

Inelastic neutron scattering study of magnon excitation by ultrasound injection in yttrium iron garnet

Shamoto, Shinichi; Akatsu, Mitsuhiro*; Chang, L.-J.*; Nemoto, Yuichi*; Ieda, Junichi

Applied Physics Letters, 124(11), p.112402_1 - 112402_5, 2024/03

https://doi.org/10.1063/5.0189768

The magnon excitation by ultrasound injection in YFeO is studied by inelastic neutron scattering. Both longitudinal and transverse ultrasound injections enhanced the inelastic neutron scattering intensity.

An Analytical model to decompose mass transfer and chemical process contributions to molecular iodine release from aqueous phase under severe accident conditions

Zablackaite, G.; Shiotsu, Hiroyuki; Kido, Kentaro; Sugiyama, Tomoyuki

Nuclear Engineering and Technology, 56(2), p.536 - 545, 2024/02

https://doi.org/10.1016/j.net.2023.10.030

Dynamic deformation properties of medium-Mn multi-phase steels containing retained austenite

Okitsu, Takayuki*; Hojo, Tomohiko*; Morooka, Satoshi; Miyamoto, Goro*

Tetsu To Hagane, 110(3), p.260 - 267, 2024/02

https://doi.org/10.2355/tetsutohagane.TETSU-2023-065

Development of an RPV cooling system for HTGRs

Takamatsu, Kuniyoshi

Kakushinteki Reikyaku Gijutsu; Mekanizumu Kara Soshi, Shisutemu Kaihatsu Made, p.179 - 183, 2024/01

The HTGR has excellent safety, and even in the event of an accident where the reactor coolant is lost, the decay heat and residual heat in the core can be dissipated from the outer surface of the RPV, so the fuel temperature never exceeds the limit value, and the core stabilizes. On the other hand, regarding the cooling system that transports the heat emitted from the RPV to the final heat sink, an active cooling system using forced circulation of water by a pump, etc., and a passive cooling system using natural circulation of the atmosphere have been proposed. However, there is a problem that the cooling performance is affected by the operation of dynamic equipment and weather conditions. This paper presents an overview of a new cooling system concept using radiative cooling, which has been proposed to solve the above problem, and introduces the results of analysis and experiments aimed at confirming the feasibility of this concept.

Petrophysical properties of representative geological rocks encountered in carbon storage and utilization

Hu, Q.*; Wang, Q. M.*; Zhang, T.*; Zhao, C.*; Iltaf, K. H.*; Liu, S. Q.*; Fukatsu, Yuta

Energy Reports (Internet), 9, p.3661 - 3682, 2023/12

https://doi.org/10.1016/j.egyr.2023.02.020

Slightly hydrogen-ordered state of ice IV evidenced by neutron diffraction

Kobayashi, Hiroki*; Komatsu, Kazuki*; Ito, Hayate*; Machida, Shinichi*; Hattori, Takanori; Kagi, Hiroyuki*

Journal of Physical Chemistry Letters (Internet), 14(47), p.10664 - 10669, 2023/11

https://doi.org/10.1021/acs.jpclett.3c02563

Ice IV is a metastable high-pressure phase of ice in which the water molecules exhibit orientational disorder. Although orientational ordering is commonly observed for other ice phases, it has not been reported for ice IV. We conducted powder neutron diffraction experiments for DCl-doped DO ice IV to investigate hydrogen ordering in ice IV. We found abrupt changes in the temperature derivative of unit cell volume, dV/dT, at about 120 K, and revealed their slightly ordered structure at low temperatures based on the Rietveld method. The occupancy of the D1 site deviates from 0.5; it increased when samples were cooled at higher pressures and reached 0.282(5) at 2.38 GPa, 58 K. Our results evidence the presence of a low-symmetry hydrogen-ordered state corresponding to ice IV. It seems, however, difficult to experimentally access the completely ordered phase corresponding to ice IV by slow cooling at high pressure.

Predictive and inverse modeling of a radionuclide diffusion experiment in crystalline rock at ONKALO (Finland)

Soler, J. M.*; Keklinen, P.*; Pulkkanen, V.-M.*; Moreno, L.*; Iraola, A.*; Trinchero, P.*; Hokr, M.*; ha, J.*; Havlov, V.*; Trpkoov, D.*; et al.

Nuclear Technology, 209(11), p.1765 - 1784, 2023/11

https://doi.org/10.1080/00295450.2023.2209234