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Okubo, Takahiro*; Takei, Akihiro*; Tachi, Yukio; Fukatsu, Yuta; Deguchi, Kenzo*; Oki, Shinobu*; Shimizu, Tadashi*
Journal of Physical Chemistry A, 127(4), p.973 - 986, 2023/02
Times Cited Count:1 Percentile:50.66(Chemistry, Physical)The identification of adsorption sites of Cs on clay minerals has been studied in the fields of environmental chemistry. The nuclear magnetic resonance (NMR) experiments allow direct observations of the local structures of adsorbed Cs. The NMR parameters of Cs, derived from solid-state NMR experiments, are sensitive to the local neighboring structures of adsorbed Cs. However, determining the Cs positions from NMR data alone is difficult. This paper describes an approach for identifying the expected atomic positions of Cs adsorbed on clay minerals by combining machine learning (ML) with experimentally observed chemical shifts. A linear ridge regression model for ML is constructed from the smooth overlap of atomic positions descriptor and gauge-including projector augmented wave (GIPAW) ab initio data. The Cs chemical shifts can be instantaneously calculated from the Cs positions on any clay layers using ML. The inverse analysis from the ML model can derive the atomic positions from experimentally observed chemical shifts.
Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Takagi, Yasuhiko*; Nakamura, Tomoki*; Hiroi, Takahiro*; Matsuoka, Moe*; et al.
Nature Astronomy (Internet), 5(3), p.246 - 250, 2021/03
Times Cited Count:44 Percentile:97.1(Astronomy & Astrophysics)Here we report observations of Ryugu's subsurface material by the Near-Infrared Spectrometer (NIRS3) on the Hayabusa2 spacecraft. Reflectance spectra of excavated material exhibit a hydroxyl (OH) absorption feature that is slightly stronger and peak-shifted compared with that observed for the surface, indicating that space weathering and/or radiative heating have caused subtle spectral changes in the uppermost surface. However, the strength and shape of the OH feature still suggests that the subsurface material experienced heating above 300 C, similar to the surface. In contrast, thermophysical modeling indicates that radiative heating does not increase the temperature above 200 C at the estimated excavation depth of 1 m, even if the semimajor axis is reduced to 0.344 au. This supports the hypothesis that primary thermal alteration occurred due to radiogenic and/or impact heating on Ryugu's parent body.
Meigo, Shinichiro; Takei, Hayanori; Matsuda, Hiroki; Yuri, Yosuke*; Yuyama, Takahiro*
Proceedings of 16th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.515 - 519, 2019/07
no abstracts in English
Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Arai, Takehiko*; Nakauchi, Yusuke*; Nakamura, Tomoki*; Matsuoka, Moe*; et al.
Science, 364(6437), p.272 - 275, 2019/04
Times Cited Count:262 Percentile:99.73(Multidisciplinary Sciences)The near-Earth asteroid 162173 Ryugu, the target of Hayabusa2 sample return mission, is believed to be a primitive carbonaceous object. The Near Infrared Spectrometer (NIRS3) on Hayabusa2 acquired reflectance spectra of Ryugu's surface to provide direct measurements of the surface composition and geological context for the returned samples. A weak, narrow absorption feature centered at 2.72 micron was detected across the entire observed surface, indicating that hydroxyl (OH)-bearing minerals are ubiquitous there. The intensity of the OH feature and low albedo are similar to thermally- and/or shock-metamorphosed carbonaceous chondrite meteorites. There are few variations in the OH-band position, consistent with Ryugu being a compositionally homogeneous rubble-pile object generated from impact fragments of an undifferentiated aqueously altered parent body.
Meigo, Shinichiro; Takei, Hayanori; Matsuda, Hiroki; Yuri, Yosuke*; Yuyama, Takahiro*
Proceedings of 15th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.1035 - 1039, 2018/08
no abstracts in English
Sawabe, Yuki*; Ishiyama, Tatsuya; Takahashi, Daisuke; Kato, Yuko; Suzuki, Takahiro*; Hirano, Koichiro; Takei, Hayanori; Meigo, Shinichiro; Kikuzawa, Nobuhiro; Hayashi, Naoki
Proceedings of 13th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.647 - 651, 2016/11
In the J-PARC, a 3 MeV linac has been developed for the tests of beam scraper irradiation and charge exchange by high-power laser. To accomplish tests efficiently and safely, the control system for 3 MeV was designed and developed, and this system consists of four subsystems, personal protection system, machine protection system, timing system, and remote control system using the EPICS. In this paper, the details of control system for a 3 MeV linac are presented.
Takei, Satoshi*; Oshima, Akihiro*; Oyama, Tomoko; Ito, Kenta*; Sugahara, Kigen*; Kashiwakura, Miki*; Kozawa, Takahiro*; Tagawa, Seiichi*; Hanabata, Makoto*
Japanese Journal of Applied Physics, 53(11), p.116505_1 - 116505_7, 2014/11
Times Cited Count:10 Percentile:41.2(Physics, Applied)The application of natural linear polysaccharide to green resists was demonstrated for electron beam (EB) and extreme-ultraviolet (EUV) lithography. Because of the water solubility of natural polysaccharides, the water spin-coating and water-developable processes realize an environmentally friendly manufacturing process for next-generation electronic devices. The developed green resist with a weight-average molecular weight of 83,000 and 70 mol % hydroxyl groups was found to have acceptable properties such as spin-coat ability on 200 mm wafers, pillar patterns of 100-400 nm with a high EB sensitivity of 10 C/cm, etch selectivity with a silicon-based middle layer in CF plasma treatment, and high prediction sensitivity to EUV region.
Takei, Satoshi*; Oshima, Akihiro*; Ichikawa, Takumi*; Sekiguchi, Atsushi*; Kashiwakura, Miki*; Kozawa, Takahiro*; Tagawa, Seiichi*; Oyama, Tomoko; Ito, Shoji*; Miyasaka, Hiroshi*
Microelectronic Engineering, 122, p.70 - 76, 2014/06
Times Cited Count:24 Percentile:76.64(Engineering, Electrical & Electronic)Biomass-derived branched sugar resist material was developed for environmentally-friendly electron beam lithography (EBL). The developed resist enables organic solvent-free water-developable process. The resist performance was evaluated using 75 keV EBL system. Lines of 50-200 nm were fabricated with high sensitivity of 7 C/cm. The resist is developable in pure water at 23 C for 60 s, and it has acceptable CF etch selectivity.
Smirnova, O.*; Azuma, Masaki*; Kumada, Nobuhiro*; Kusano, Yoshihiro*; Matsuda, Masaaki; Shimakawa, Yuichi*; Takei, Takahiro*; Yonesaki, Yoshinori*; Kinomura, Nobukazu*
Journal of the American Chemical Society, 131(23), p.8313 - 8317, 2009/05
Times Cited Count:125 Percentile:91.9(Chemistry, Multidisciplinary)Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate BiMnO (NO) prepared by hydrothermal synthesis is of a new structural type including flat NO layers alternating with blocks of two PbSbO-like layers. Mn (=3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of 257K, no long-range ordering was observed down to 0.4K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions.
Takei, Nahoko; Nakamura, Yukiharu; Ushigome, Masahiro*; Suzuki, Takahiro; Aiba, Nobuyuki; Takechi, Manabu; Tobita, Kenji; Takase, Yuichi*; Fukuyama, Atsushi*; Jardin, S. C.*
Plasma Physics and Controlled Fusion, 49(3), p.335 - 345, 2007/03
Times Cited Count:7 Percentile:25.77(Physics, Fluids & Plasmas)Non-disruptive -collapses with a regular intermittency have been observed after a forced turn-off of neutral beam current drive (NBCD) in JT-60U fully non-inductive, reversed shear (RS) discharges. Self-consistent transport simulations with improved core confinement and linear MHD stability analysis have first clarified that redistribution of return current induced after the NBCD turn-off lowers the safety factor of magnetic shear reversal, leading to the n =1 kink-ballooning instability with localized modes around internal transport barrier (ITB). It was also pointed out that an increase of the bootstrap current under continuous NB heating can lead to ITB reconstruction and thus causes subsequent beta-collapses.
Takei, Nahoko; Ushigome, Masahiro*; Suzuki, Takahiro; Nakamura, Yukiharu; Takase, Yuichi*
Europhysics Conference Abstracts (CD-ROM), 30I, 4 Pages, 2006/00
no abstracts in English
Takei, Nahoko; Ushigome, Masahiro*; Suzuki, Takahiro; Takechi, Manabu; Aiba, Nobuyuki; Nakamura, Yukiharu; Takase, Yuichi*
no journal, ,
no abstracts in English
Takei, Koyo*; Okubo, Takahiro*; Tachi, Yukio; Fukatsu, Yuta
no journal, ,
Cs adsorption sites on vermiculite clays were investigated by Cs magic-angle-spinning nuclear magnetic resonance (MAS NMR) and theoretical Cs chemical shift calculations. A partially Cs exchanged vermiculite sample was prepared. Three peaks on Cs MAS NMR spectra were experimentally observed. However, Cs absorption sites were not assigned to these peaks. A molecular model of fully Cs exchanged vermiculite was built to obtain Cs chemical shift theoretically by GIPAW method. Calculated Cs chemical shift ranged 23 to 47 ppm, which corresponds to the peak of the lowest field side. Detailed relationships between structure and Cs chemical shifts were investigated from Cs position and vermiculite layer structure.
Takir, D.*; Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Arai, Takehiko*; Nakauchi, Yusuke*; Nakamura, Tomoki*; et al.
no journal, ,
JAXA spacecraft and sample return mission Hayabusa2 has arrived at the near-Earth asteroid 162173 Ryugu, which is classified a primitive carbonaceous object. Here we report recent results of near-infrared spectrometer (NIRS3) on the Hayabusa2 spacecraft. The observations provide direct measurements of the surface composition of Ryugu and context for the returned samples. NIRS3 has detected a weak and narrow absorption feature centered at 2.72 micrometer across entire observed surface. This absorption feature is attributed to the presence of OH-bearing minerals. The NIRS3 observations also revealed that Ryugu is the darkest object to be observed up-close by a visiting spacecraft. The intensity of the OH feature and low albedo are consistent with thermally-and/or shock-metamorphosed, and/or carbon-rich space-weathered primitive and hydrated carbonaceous chondrites.