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Yamaguchi, Akiko; Kurihara, Yuichi*; Nagata, Kojiro*; Tanaka, Kazuya; Higaki, Shogo*; Kobayashi, Toru; Tanida, Hajime; Ohara, Yoshiyuki*; Yokoyama, Keiichi; Yaita, Tsuyoshi; et al.
Journal of Colloid and Interface Science, 661, p.317 - 332, 2024/05
Times Cited Count：0no abstracts in English
-, SeO
-, and SeO
-coprecipitated barite after treatment with phosphateTokunaga, Kohei; Tanaka, Kazuya; Takahashi, Yoshio*; Kozai, Naofumi
Environmental Science & Technology, 57(8), p.3166 - 3175, 2023/02
Times Cited Count：1 Percentile：52.26(Engineering, Environmental)Coprecipitation of radionuclides with barite has been studied to remove radionuclides from radioactive liquid waste because of its excellent removal efficiency; however, little information exists concerning the stability of the ions coprecipitated with barite. This study systematically investigated the stability of iodate, selenite, and selenate coprecipitated with barite via leaching tests. These oxyanions were gradually leached from the oxyanion-bearing barite into ultrapure water over time. Leaching of the oxyanions significantly increased in leaching solutions containing NaCl (pH5.3), NaNO (pH5.9), and Na
SO (pH5.7). Conversely, leaching of the oxyanions was suppressed in KHPO solution (pH8.5), indicating that phosphate stabilized the oxyanion-bearing barite. The effect of phosphate treatment on oxyanion-bearing barite was further investigated. The results showed that the barite surface was modified with phosphate, and a thin surface layer of a barium phosphate-like structure was formed. The amount of oxyanions leached from the phosphate-treated samples into leaching solutions containing NaCl or NaNO was much lower than the amounts leached from the untreated barite samples into ultrapure water. The barite coprecipitation combined with subsequent phosphate treatment may be a promising method to efficiently remove iodate, selenite, and selenate from wastewater and stabilize them as barite coprecipitates.
molecular dynamics simulations reveal the hydration structure of the radium(II) ionYamaguchi, Akiko; Nagata, Kojiro*; Kobayashi, Keita; Tanaka, Kazuya; Kobayashi, Toru; Tanida, Hajime; Shimojo, Kojiro; Sekiguchi, Tetsuhiro; Kaneta, Yui; Matsuda, Shohei; et al.
iScience (Internet), 25(8), p.104763_1 - 104763_12, 2022/08
Times Cited Count：9 Percentile：68.46(Multidisciplinary Sciences)no abstracts in English
Shiraishi, Fumito*; Chihara, Ryoji*; Tanimoto, Risa*; Tanaka, Kazuya; Takahashi, Yoshio*
Island Arc, 31(1), p.e12448_1 - e12448_9, 2022/05
Times Cited Count：0 Percentile：0(Geosciences, Multidisciplinary)At Yunotaki Fall in north Japan, manganese-oxidizing bacteria were previously assumed to have oxidized manganese to precipitate birnessite, which relied on oxygen released from algae. However, it remained unclear whether larger-scale manganese oxide precipitation was actually occurring under light conditions. This study evaluated the contribution of indirect oxidation using microelectrodes to analyze local water chemistry, in addition to bulk water chemistry and DNA analyses. The results of this study demonstrate that low bulk pH values in the hot spring water hindered indirect oxidation despite the occurrence of active oxygenic photosynthesis and that direct oxidation by manganese-oxidizing bacteria is considered to dominate in the investigated sample.
Yamaguchi, Akiko; Nagata, Kojiro*; Tanaka, Kazuya; Kobayashi, Keita; Kobayashi, Toru; Shimojo, Kojiro; Tanida, Hajime; Sekiguchi, Tetsuhiro; Kaneta, Yui; Matsuda, Shohei; et al.
Hosha Kagaku, (45), p.28 - 30, 2022/03
no abstracts in English
Nishimura, Shoichiro*; Torii, Hiroyuki*; Fukao, Yoshinori*; Ito, Takashi; Iwasaki, Masahiko*; Kanda, Sotaro*; Kawagoe, Kiyotomo*; Kawall, D.*; Kawamura, Naritoshi*; Kurosawa, Noriyuki*; et al.
Physical Review A, 104(2), p.L020801_1 - L020801_6, 2021/08
Times Cited Count：13 Percentile：83.13(Optics)Tokunaga, Kohei; Takahashi, Yoshio*; Tanaka, Kazuya; Kozai, Naofumi
Chemosphere, 266, p.129104_1 - 129104_10, 2021/03
Times Cited Count：10 Percentile：52.13(Environmental Sciences)Radioactive iodine (
I) is of great concern owing to its high mobility in the environment and long-term radiotoxicity, but there is a lack of effective techniques for removing iodate (IO) from aqueous solution. The aim of this study is to develop a new technique for removing radioactive iodate from contaminated solution by using barite (BaSO). In the present study, we examined the coprecipitation mechanism of iodate by barite at the molecular level for determining optimum conditions for iodate removal. The results showed that iodate was effectively removed from aqueous solution by coprecipitation, even in the presence of competitive anions in solution. Comparing our method with previous studies, iodate removal efficiency by barite was determined to be about two orders of magnitude greater than that by hydrotalcite-like layered double hydroxide at Cl concentration of 10 mmol L
. Extended X-ray absorption fine structure (EXAFS) analysis indicated that incorporated iodate was strongly bound in the crystal lattice of barite by substituting the sulfate site in the structure when the iodine concentration was low. The charge compensation problem from the IO substitution in SO site is achieved by the substitution of Na
-IO pairs at the nearest Ba
site. Therefore, considering high removal efficiency and strong binding of iodate in barite, coprecipitation with barite is a promising material for removing radioactive iodate from various aqueous solutions contaminated with iodate.
Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Takagi, Yasuhiko*; Nakamura, Tomoki*; Hiroi, Takahiro*; Matsuoka, Moe*; et al.
Nature Astronomy (Internet), 5(3), p.246 - 250, 2021/03
Times Cited Count：43 Percentile：96.93(Astronomy & Astrophysics)Here we report observations of Ryugu's subsurface material by the Near-Infrared Spectrometer (NIRS3) on the Hayabusa2 spacecraft. Reflectance spectra of excavated material exhibit a hydroxyl (OH) absorption feature that is slightly stronger and peak-shifted compared with that observed for the surface, indicating that space weathering and/or radiative heating have caused subtle spectral changes in the uppermost surface. However, the strength and shape of the OH feature still suggests that the subsurface material experienced heating above 300 
C, similar to the surface. In contrast, thermophysical modeling indicates that radiative heating does not increase the temperature above 200 C at the estimated excavation depth of 1 m, even if the semimajor axis is reduced to 0.344 au. This supports the hypothesis that primary thermal alteration occurred due to radiogenic and/or impact heating on Ryugu's parent body.
Tanaka, Kazuya; Kanasashi, Tsutomu*; Takenaka, Chisato*; Takahashi, Yoshio*
Science of the Total Environment, 755(Part 2), p.142598_1 - 142598_8, 2021/02
Times Cited Count：5 Percentile：35.21(Environmental Sciences)In this study, we investigated coordination structures of Cs in 
Cs-doped bark, sapwood, heartwood, needle, and branch samples of trees collected in Fukushima by extended X-ray absorption fine structure (EXAFS) spectroscopy. We examined four representative tree species in Fukushima, 
, 
, 
, and 
. EXAFS spectra suggested that Cs was adsorbed as an outer-sphere complex on all parts of the four species, with electrostatic binding to negatively charged functional groups in components of tree tissues. These results were supported by extraction experiments where most of the sorbed Cs was desorbed from all parts of each tree species using 1 M CHCOONH.
Takahashi, Yoshio*; Sakaguchi, Aya*; Fan, Q.*; Tanaka, Kazuya; Miura, Hikaru*; Kurihara, Yuichi*
Behavior of Radionuclides in the Environment I; Function of Particles in Aquatic System, p.115 - 150, 2020/00
Times Cited Count：0 Percentile：0.59(Environmental Sciences)Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Arai, Takehiko*; Nakauchi, Yusuke*; Nakamura, Tomoki*; Matsuoka, Moe*; et al.
Science, 364(6437), p.272 - 275, 2019/04
Times Cited Count：259 Percentile：99.73(Multidisciplinary Sciences)The near-Earth asteroid 162173 Ryugu, the target of Hayabusa2 sample return mission, is believed to be a primitive carbonaceous object. The Near Infrared Spectrometer (NIRS3) on Hayabusa2 acquired reflectance spectra of Ryugu's surface to provide direct measurements of the surface composition and geological context for the returned samples. A weak, narrow absorption feature centered at 2.72 micron was detected across the entire observed surface, indicating that hydroxyl (OH)-bearing minerals are ubiquitous there. The intensity of the OH feature and low albedo are similar to thermally- and/or shock-metamorphosed carbonaceous chondrite meteorites. There are few variations in the OH-band position, consistent with Ryugu being a compositionally homogeneous rubble-pile object generated from impact fragments of an undifferentiated aqueously altered parent body.
Strasser, P.*; Abe, Mitsushi*; Aoki, Masaharu*; Choi, S.*; Fukao, Yoshinori*; Higashi, Yoshitaka*; Higuchi, Takashi*; Iinuma, Hiromi*; Ikedo, Yutaka*; Ishida, Katsuhiko*; et al.
EPJ Web of Conferences, 198, p.00003_1 - 00003_8, 2019/01
Times Cited Count：13 Percentile：99.06(Quantum Science & Technology)
-edge XANES to determination of U oxidation state in zirconTanaka, Kazuya; Takahashi, Yoshio*
Geochemical Journal, 53(5), p.329 - 331, 2019/00
Times Cited Count：0 Percentile：0.01(Geochemistry & Geophysics)We examined three natural zircon samples with different amounts of radiation doses using M-edge and L
-edge U X-ray absorption near-edge structure (XANES). Analysis of XANES spectra at both M-edge and L-edge suggested that the oxidation state of U in the zircon sample with the highest radiation dose is tetravalent. The XANES spectra of the two other samples with lower radiation doses suggested a mixture of U(IV) and U(VI), while the possibility of U(V) was not excluded. This is the first work on the application of M-edge U XANES to the oxidation state of U in natural zircon.
Tanaka, Kazuya; Watanabe, Naoko*; Yamasaki, Shinya*; Sakaguchi, Aya*; Fan, Q.*; Takahashi, Yoshio*
Geochemical Journal, 52(2), p.173 - 185, 2018/00
Times Cited Count：9 Percentile：43.3(Geochemistry & Geophysics)We analyzed riverbed sediments collected at two sites, Yamakiya and Kuroiwa, in Fukushima after the Fukushima accident. The size distributions of K, Rb, and Csreflected the mineralogy of sediments, where primary host minerals for these alkali elements would be biotite, K-feldspar, and clay minerals. Silt-size fractions contained high Cs and 
Cs concentrations possibly due to adsorption on clay minerals. Their concentrations decreased with particle size at the Yamakiya site. In contrast, coarse and very coarse sand fractions from the Kuroiwa site showed higher Cs and Cs concentrations in comparison to fine - medium sand fractions. The coarse sand fractions contained many weathered biotite grains. Overall, the size distributions of Cs and Cs were similar in the sediments, suggesting that the Fukushima-derived radiocesium was distributed into each particle size fraction in response to the distribution of the stable Cs that was controlled by mineralogical composition.
Sakaguchi, Aya*; Chiga, Haruka*; Tanaka, Kazuya; Tsuruta, Haruo*; Takahashi, Yoshio*
Geochemical Journal, 52(2), p.187 - 199, 2018/00
Times Cited Count：7 Percentile：35.55(Geochemistry & Geophysics)An aerosol sample collected on the 15th of March 2011 at Kawasaki City (Kanagawa) was sequentially leached with seawater for 30 days. As a result, about 60% of the total Cs was extracted. In addition, a surface soil sample collected from Kawamata Town (Fukushima) two months after the Fukushima accident, was leached for 223 days with a natural seawater, a 1:1 mixture of ultrapure water and seawater, and ultrapure water. Eventually, more than 15% of the total Cs in the surface soil sample was efficiently desorbed by seawater leaching. In comparison, about 9% of the total Cs was leached with 1:1 diluted seawater and less than 1% of the total Cs was leached with ultrapure water over the 223 days. Overall, Cs and Cs showed similar leaching behaviour.
) of radiocesium in the Kuchibuto River in FukushimaMiura, Hikaru*; Kurihara, Yuichi*; Sakaguchi, Aya*; Tanaka, Kazuya; Yamaguchi, Noriko*; Higaki, Shogo*; Takahashi, Yoshio*
Geochemical Journal, 52(2), p.145 - 154, 2018/00
Times Cited Count：48 Percentile：93.68(Geochemistry & Geophysics)Solid-water distribution coefficient () of radiocesium in rivers is apparently increased due to the possible presence of highly radioactive radiocesium-bearing microparticles (CsMPs) in the solid phase. In this study, we evaluated the contribution of CsMPs to apparent Kd values. The ratio of the radioactivity of the separated CsMPs to the total radiocesium on fluvial suspended particles ranged from 0 to 46%. This means that the existence of CsMPs in fluvial suspended partcles did not change apparent Kd values in order magnitude.
Yamaguchi, Akiko*; Honda, Tasuku*; Tanaka, Masato*; Tanaka, Kazuya; Takahashi, Yoshio*
Geochemical Journal, 52(5), p.415 - 425, 2018/00
Times Cited Count：18 Percentile：61.41(Geochemistry & Geophysics)Ion-adsorption type REE deposits in weathered granite are main sources of REE essential for high-technology industries. However, these type deposits have not been searched in Japan. In this study, Bulk REE abundances (= REE
), ion-exchangeable REE (= REE
) by ammonium chloride solution, and percentage of REE relative to REE (= REE
) in fresh and weathered granite samples in Southwest Japan (i.e., Hiroshima and Shimane Prefectures) were determined. The REE and REE were comparable to those of ion-adsorption type REE deposits in China. Extended X-ray adsorption fine structure (EXAFS) spectra of REE in original samples and samples after the extraction of ion-exchangeable REE showed that (i) REE in samples with high REE mainly forms outer-sphere complexes and (ii) the remaining REE in the rocks after the extraction forms inter-sphere complexes.
Takahashi, Yoshio*; Fan, Q.*; Suga, Hiroki*; Tanaka, Kazuya; Sakaguchi, Aya*; Takeichi, Yasuo*; Ono, Kanta*; Mase, Kazuhiko*; Kato, Kenji*; Kanivets, V. V.*
Scientific Reports (Internet), 7(1), p.12407_1 - 12407_11, 2017/09
Times Cited Count：28 Percentile：67.08(Multidisciplinary Sciences)We focused on factors controlling partition of radiocesium on particulate matters and sediments in rivers of Fukushima and Chernobyl. Radiocesium is more soluble in the Pripyat River (Chernobyl) due to weaker interaction of radiocesium with clay minerals caused by the inhibition effect of the adsorbed humic substances. In contrast, particulate matters and sediments in the Kuchibuto River (Fukushima) display high adsorption affinity with lesser inhibition effect of adsorbed humic substances. This difference is possibly governed by the geology and soil type of provenances surrounding both catchments.
-MnO in NaCl solutionTanaka, Kazuya; Tanaka, Masato*; Watanabe, Naoko*; Tokunaga, Kohei*; Takahashi, Yoshio*
Chemical Geology, 460, p.130 - 137, 2017/06
Times Cited Count：8 Percentile：34.27(Geochemistry & Geophysics)Pd is highly accumulated in ferromanganese nodules and crusts relative to its concentration in seawater but the mechanism by which Pd(II) is incorporated remains poorly understood. We investigated the local coordination structure of Pd(II) adsorbed on -MnO, using X-ray absorption fine structure spectroscopy. X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) analyses indicated that Pd was adsorbed on -MnO through ligand exchange, from Cl coordination to O coordination. Furthermore, curve fitting of EXAFS spectra demonstrated the formation of two different inner-sphere complexes, bidentate-mononuclear and bidentate-binuclear complexes, and this finding was supported by density functional theory calculations. The formation of inner-sphere complexes is reasonable given the relatively large distribution coefficients obtained from adsorption experiments.
Ohashi, Yusuke; Tanaka, Yoshio; Tsunashima, Yasumichi; Ikeda, Yasuhisa*
Journal of Nuclear Science and Technology, 54(3), p.382 - 390, 2017/03
Times Cited Count：9 Percentile：61.27(Nuclear Science & Technology)Sludge-like uranium wastes (SUWs) have been generated with neutralization of acidic aqueous solutions used for decontamination of metal wastes containing a large amount of iron. We have examined the method for recovering uranium from such SUWs using 
-2-pyrrolidone (NCP) as a precipitate. As a result, it was found that precipitation ratios (PRs) of uranium in the solutions prepared by dissolving SUWs in HNO is 97.7% at [NCP]/[U(VI)] = 20, and that the PRs of iron, aluminum, fluorine, and sulfate species are less than 1%. This indicates that uranium species are precipitated selectively. The content ratios of U, Fe, Ca, F, and S in the materials after calcining precipitates obtained at [NCP]/[U(VI)] = 20 were in accordance with the conditions of uranium ore concentrate. From these results, it is expected that highly purified uranium can be efficiently recovered from SUWs by using NCP as the precipitant.
