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Journal Articles

Effect of pressure on hopping conduction in amorphous Ge alloys

Toda, Naohiro*; Katayama, Yoshinori; Tsuji, Kazuhiko*

Review of High Pressure Science and Technology, 7, p.647 - 649, 1998/03

The electrical conductivity $$sigma$$ has been measured at pressures $$P$$ to 8 GPa and temperatures $$T$$ of 77-300K in evaporated amorphous Ge (a-Ge), a-Ge-Cu alloys and a-Ge-Al alloys. The $$T$$ dependence of $$sigma$$ is well described by a power lw at low temperatures below 150 K, which is expemcted from a multi-phonon tunneling transition process model with weak electron-lattice coupling, rather than the Mott's variable range hopping conduction model. The exponent $$n$$ in the power law changes with increasing pressure. For both a-Ge$$_{1-x}$$Cu$$_{x}$$ and a-Ge$$_{1-x}$$Al$$_{x}$$ alloys, d(ln $$n$$)/d$$P$$ show positive values in the low pressure region and negative values in the high pressure region. Results are discussed from several hopping conduction models.

Journal Articles

Structure of liquid rubidium and liquid sodium under pressure

Morimoto, Yoshiki*; Kato, Sayuri*; Toda, Naohiro*; Katayama, Yoshinori; Tsuji, Kazuhiko*; Yaoita, Kenichi*; Shimomura, Osamu

Review of High Pressure Science and Technology, 7, p.245 - 247, 1998/03

X-ray diffraction for liquid Rb and liquid Na has been measured under pressure up to 6 GPa using synchrotron radiation. Volume dependences of static structure factor $$S(Q)$$ and pair distribution function $$g(r)$$ were obtained to the volume range $$nu(=V/V_{0})$$ of 0.52 for liquid Rb and $$nu$$ of 0.73 for liquid Na to investigate the effect of the electronic change on the structure of liquid metals. With increasing pressure, the peaks of $$S(Q)$$ of both liquid Rb and liquid Na shift towards higher $$Q$$, and the heights of the first peak increase. Theses volume dependences of the structural data are compared with those for other metals under pressure and expanded fluids.

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