Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Yasuda, Satoshi; Tamura, Kazuhisa; Terasawa, Tomoo; Yano, Masahiro; Nakajima, Hideaki*; Morimoto, Takahiro*; Okazaki, Toshiya*; Agari, Ryushi*; Takahashi, Yasufumi*; Kato, Masaru*; et al.
Journal of Physical Chemistry C, 124(9), p.5300 - 5307, 2020/03
Times Cited Count:14 Percentile:60.14(Chemistry, Physical)Confinement of hydrogen molecules at graphene-substrate interface has presented significant importance from the viewpoints of development of fundamental understanding of two-dimensional material interface and energy storage system. In this study, we investigate H confinement at a graphene-Au interface by combining selective proton permeability of graphene and the electrochemical hydrogen evolution reaction (electrochemical HER) method. After HER on a graphene/Au electrode in protonic acidic solution, scanning tunneling microscopy finds that H nanobubble structures can be produced between graphene and the Au surface. Strain analysis by Raman spectroscopy also shows that atomic size roughness on the graphene/Au surface originating from the HER-induced strain relaxation of graphene plays significant role in formation of the nucleation site and H storage capacity.
Tanabe, Tetsuro*; Fujine, Michihiko*; Noguchi, Hiroshi*; Yagi, Yasufumi*; Hirano, Yoichi*; Shimizu, Hajime*; Akiba, Masato; Araki, Masanori; Kubota, Yusuke*; Miyahara, Akira*
Journal of Nuclear Materials, 200(1), p.120 - 127, 1993/03
Times Cited Count:9 Percentile:66.93(Materials Science, Multidisciplinary)no abstracts in English